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Tytuł artykułu

Sedimentation of water dispersed systems of acrylate copolymers in xylene

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Methyl methacrylate - butyl acrylate - methacrylic acid copolymer and butyl methacrylate - methacrylic acid amide copolymer of a different segmental structure were stabilised with non-ionic and anionic surfactants. Gel chromatography, viscosimetry, tensiometry, conductometry and sedimentation methods were applied to define the properties of the synthesized copolymers, surfactants in water solutions and water dispersions. The types and the properties of the phases being in a state of sedimentation balance were also determined. The obtained experimental data were interpreted and justified by using the copolymer and surfactants properties. The existing correlations were pointed out. The obtained results show that the stability of a disperse system considerably depends on the structure of the copolymer. The MMA/BA/MAA copolymer has monomeric units of elastic butyl acrylate. Segments containing these monomeric units adsorb surfactants much better and form more stable water disperse systems. However, the MBA/AMAA copolymer with the polarity of amide group of methacrylamide makes disperse systems less stable.
Rocznik
Strony
29--34
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
  • Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences, ul. Seminaryjna 3, 85-326 Bydgoszcz, makar@utp.edu.pl
Bibliografia
  • 1. Grad, P.J., Oldring, P. & Clarke, J. (1994). The Chemistry of Waterborne Acrylics. P. Oldring & P. Lam (Eds.), Waterborne and solvent based acrylics and their end user application (pp. 105-176). London, UK: SITA Technology Limited.
  • 2. Bouvy, A. & Opstaele, A. (1995). Polymeric Surfactants and Their Application in Resin Emulsification. D.R. Karsa & W.D. Davies (Eds.), Waterborne Coatings and Additives (pp. 190-201). Cambridge, UK: The Royal Society of Chemistry.
  • 3. Hunter, R.J. (1989). Foundation of Colloid Surface (vols. 1 and 2). Oxford, UK: ClarendonPress.
  • 4. Lyklema, J. (1995). Fundamentals of Interface and Colloid Surface (vol. 1). New York, USA: Academic Press.
  • 5. Candan, F. & Ottewill, R.H. (1990). Scientific Methods of Polymer Colloids and their Applications. Dordrecht, NL: Kluwer Academic Publishers.
  • 6. Ahualli, S., Delgado, A.V., Miklavcic, S.J. & White, L.R. (2007). Use of a cell model for the evaluation of the dynamic mobility of spherical silica suspensions. Journal of Colloid And Interface Science. 309, 342-349.
  • 7. Husband, J.C. (1998). Adsorption and rheological studies of sodium carboxymethyl cellulose onto kaolin: effect of degree of substitution. Colloids and Surfaces A., Physicochemical and Engineering Aspect. 134, 349-358.
  • 8. Ho, C.C. & Ottewill, R.H. (1998). Investigation of the charge distribution of ellipsoidal particles. Colloids and Surfaces A., Physicochemical and Engineering Aspects. 141, 29-35.
  • 9. Goodwin, J.W. (2004). Colloids and Interfaces, with Surfactants and Polymers: An Introduction. New York, USA: Wiley.
  • 10. Napper, D.M. (1983). Polymeric Stabilization of Colloidal Dispersions. London, UK: Academic Press.
  • 11. Gurumayum Sharma, S.D., Moreton, D. & Vincent, B. (2003). Adsorption isotherm and atomic force microscopy studies of the interactions between polymers and surfactants on steel surfaces in hydrocarbon media. Journal of Colloid and Interface Science. 263, 343-349.
  • 12. Morisson, I.D. & Ross, S. (2002). Colloidal Dispersions: Suspensions, Emulsions and Foams. New York, USA: Academic Press.
  • 13. Sonntag, H. & Strenge, K. (1972). Coagulation and Stability of Disperse Systems, New York, USA: Halsted Press.
  • 14. Pashley, R.M. (2004). Applied Colloid and Surface Chemistry. New York, USA:Wiley.
  • 15. Brostow, W., Pal, S. & Singh, R.P. (2007). A model of flocculation. Materials Letters. 61, 4381-4384.
  • 16. Makarewicz, E. (1997). An effect of non-ionic lipidhydrophilic surfactants on stability of the water emulsions of acrylate-methacrylate resin. Progress in Organic Coatings. 31, 217-222.
  • 17. Makarewicz, E. & Zalewska, A. (2005). The analysis of phenomena and factors having an effect on the sedimentation stability and rheology of water-based dispersions of MMA/BA/Maa copolymer in xylene. Progress in Organic Coatings. 54, 43-54.
  • 18. Izmailova, V.N., Yampolskaya, G.P. (1998). Concentrated emulsions stabilized by macromolecules and the contributions of Hans Sonntag to this scientific field. Colloids and Surfaces A., Physicochemical and Engineering Aspects. 142, 125-134.
  • 19. Fordedal, H., Schildberg, Y., Sjoblom, J. & Volle, J.L. (1996). Crude oil emulsions in high electric fields as studied by dielectric spectroscopy. Influence of interaction between commercial and indigenous surfactants. Colloids and Surfaces A., Physicochemical and Engineering Aspects. 106, 33-47.
  • 20. Hotrum, N.E., van Vliet, T., Cohen Stuart, M.A. & van Aken, G.A. (2002). Monitoring Entering and Spreading of Emulsion Droplets at an Expanding Air/Water Interface: A Novel Technique. Journal of Colloid and Interface Science. 247, 125-131.
  • 21. Atkins, P.W. (1996). The Elements of Physical Chemistry (second ed.). Oxford, UK: University Press.
  • 22. Van Krevelen, D.W. (1972). Properties of polymers correlations with chemical structure, Amsterdam-London-New York, NL: Elsevier Publishing Co.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0049-0014
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