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Extraction of organic impurities using 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6]

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EN
Abstrakty
EN
Extraction of several chloro compounds from water has been examined. As the extracting liquid the 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF6], which is common hydrophobic ionic liquid, was used. Additionally, extraction of selected chlorinated compounds from tert-butylmethylether (MTBE) was investigated. The obtained results show the usefulness of [BMIM][PF6] to remove the organic impurities from water, particularly at the concentration range inappropriate for biological purification plants.
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79--83
Opis fizyczny
Bibliogr. 26 poz., rys., tab.
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Bibliografia
  • 1. Friemantle, M. (2007). New frontiers for ionic liquids. Chem. Eng. News. 85, 23 - 26.
  • 2. Blanchard, L. A., Gu, Z. & Brennecke, J. F. (2001). Highpressure phase behavior of ionic liquid/CO2 systems. J. Phys. Chem B. 105, 2437 - 2444.
  • 3. Scovazzo, P., Kieft, J., Finan, D. A., Koval, C., DuBois, D. & Noble R. (2004). Gas separation using nonhexafluorophosphate [PF6]- anion supported ionic liquid membranes. J. Membrane Sci. 238, 57 - 63.
  • 4. Yokozeki A. & Shiflett M. B. (2007). Hydrogen purification using room-temperature ionic liquids. Appl. Energy. 84, 351 - 361.
  • 5. Lee, B.-C. & Outcalt, S. L. (2006). Solubilities of gases in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. J. Chem. Eng. Data. 51, 892 - 897.
  • 6. Arlt, W., Seiler, M., York, C. & Scheider, T. Ionic liquids as selective additives for the separation of close-boiling or azeotropic mixtures. PTC Int. Appl., 2002, WO 0274718 A2.
  • 7. York, C., Seiler, M., Beste, Y. A. & Arlt, W. (2004). Influence of ionic liquids on the phase behavior of aqueous azeotropic systems. J. Chem. Eng. Data. 49, 852 - 857.
  • 8. Olivier-Bourbigou, H. & Magna, L. (2002). Ionic liquids: perspectives for organic and catalytic reactions. Journal of Molecular Catalysis A: Chem. 182 - 183, 419 - 437.
  • 9. Abraham, A., Zissimos, A. M., Huddleston, J. G., Willauer, H. D., Rogers, R. D. & Acree jr, W. E. (2003). Some novel liquid partitioning systems: water - ionic liquids and aqueous biphasic systems. Ind. Eng. Chem. Res. 42, 413 - 418.
  • 10. Li, C., Xin, B., Xu, W. & Zhang, Q. (2007). Study on the extraction of dyes into a room-temperature ionic liquids and their mechanism. J. Chem. Technol. Biotechnol. 82, 196 - 204.
  • 11. Visser, A. E., Swatlowski, R. P., Reichert, W. M., Griffin, S. T. & Rogers, R. D. (2000). Traditional extractants in nontraditional solvents: groups 1 and 2 extraction by crown ether in room-temperature ionic liquids. Ind. Eng. Chem. Res. 39, 3596 - 3604.
  • 12. Luo, H., Dai, S., Bonnesen, P. V. & Buchannan III, A. C. (2006). Separation of fission products based on ionic liquids: task-specific ionic liquids conatining an aza-crown ether fragment. J. Alloys Comp. 418, 195 - 199.
  • 13. Arce, A., Rodriquez, O. & Soto, A. (2004). Experimental determination of liquid equilibrium using ionic liquids: tert-amyl ethyl ether + ethanol + 1-octyl-3-methylimidazolium chloride system at 298.15 K, J. Chem. Eng. Data. 49, 514 - 517.
  • 14. Lechter, T. M., Deenadayalu, N., Soko, B. & Ramjugernath, D. (2003). Ternary liquid-liquid equilibria for mixtures of 1-methyl-octylimidazolium chloride + and alkanol + an alkane at 298.2 K and 1 bar. J. Chem. Eng. Data. 48, 904 - 907.
  • 15. Arce, A., Rodríguez, O. & Soto, A. (2006). A comaprative study on solvents for separation of tert-amyl ethyl ether and ethanol mixtures. New experimental data for 1-ethyl-3-methyl imidazolium ethyl sulfate ionic liquid. Chem. Eng. Sci. 61, 6929 - 6935.
  • 16. Deenadayalu, N., Ngcongo, K. C., Lechter, T. M. & Ramjugernath, D. (2006). Liquid-liquid equilibria for ternary mixture (an ionic liquid + benzene + heptane or hexadecane) at T=298.2 K and atmospheric pressure. J. Chem. Eng. Data. 51, 988 - 991.
  • 17. Arce A., Earle M. J., Rodriquez H. & Seddon K. R. (2007). Separation of benzene and hexane by solvent extractoion with 1-alkyl-3-3-methylimidazolium bis{[trifluoromethyl)sulfonyl}amide ionic liquids: effect of the alkyl-substituent length. J. Phys. Chem. B. 111, 4732 - 4736.
  • 18. Koel, M. (2000). Physical and chemical properties of ionic liquids based on the dialkylimidazolium cation. Proc. Estonian Acad. Sci., Chem. 49, 145 - 155.
  • 19. Baker, S. N., Baker, G. A., Kane, M. A. & Bright F. V. (2001). The cybotactic region surrounding fluorescent probes dissolved in 1-butyl-3-methylimidazolium hexafluorophosphate: Effects of temperature and added carbon dioxide, J. Phys. Chem. B. 105, 9663 - 9668.
  • 20. Hunddelston, J. G., Willuer, H. D., Swatlowski, R. S., Visser, A. E. & Rogers, R. D. (1998). Room temperature ionic liquids as novel media for ‘clean’ liquid-liquid extraction. Chem. Commun. 1765 - 1766.
  • 21. McEwen, A. B., Ngo, H. L., LeCompte, K. & Goldman, J. L., (1999). Electrochemical properties of imidazolium salt electrolytes for electrochemical capacitor applications, J. Electrochem. Soc. 146, 1687 - 1695.
  • 22. Swatlowski, R. P., Holbrey, J. D. & Rogers, R. D. (2003). Ionic liquids are not always green: hydrolysis of 1-butyl-3-methylimidazolium hexafluorophosphate, Green Chem. 5, 361 - 363.
  • 23. Choua, C.-H., Perng, F.-S., Wong, D. S.H. & Su W. C. 1-Octanol/water partition coefficient of ionic liquids, 15 Symphosium on Thermophysical Properties, Boulder, USA, 22-27.06.2003.
  • 24. http://www.dfmg.com.tw/member/chemical/cas/108-88-3.htm
  • 25. Yang, Q. & Dionysiou, D. D. (2004). Photolytic degradation of chlorinated phenols in room temperature ionic liquids, J. Photochem. Photobiol. A: Chem. 165, 229 - 240.
  • 26. Li, C., Xin, B., Xu, W. & Zhand Q. (2007). Study in the extraction of dyes into a room-temperature ionic liquid and their mechanisms. J. Chem. Technol. Biotechnol. 82, 196 - 204.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0047-0048
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