Modeling of the influence of the modifier concentration on the retention process in NP-HPLC

• Autorzy: Zapała W.
• Języki publikacji: EN

Abstrakty

EN

The adsorption model for an accurate prediction of the analyte retention in the normal - phase liquid chromatography with a binary mobile phase has been proposed. This model was derived using a thermodynamically consistent modified competitive Langmuir isotherm. The performance of the proposed equation was compared with two retention models reported in literature. All models were verified for different NP-LC systems by use of three criteria: the sum of squared differences between the experimental and theoretical data, approximation of the standard deviation and the Fisher test.

Słowa kluczowe

EN

NP-HPLC; retention models; mobile phase composition

PL

NP-HPLC; model retencji; faza ruchoma

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2008
• Tom: Vol. 10, nr 1
• Strony: 52--56
• Opis fizyczny: Bibliogr. 12 poz., rys., tab.

Twórcy

autor

Zapała W.

• Department of Chemical and Process Engineering, Chemical Faculty, Rzeszów University of Technology, Al. Powstańców Warszawy 6, 35-959 Rzeszów,

Bibliografia

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