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The extraction of palladium(II) from hydrochloric acid solutions of various concentrations in the presence of different amounts of sodium chloride with phosphonium ionic liquid CyphosŽIL101 in toluene was investigated. The extraction of Pd(II) is very effective. The percentage extraction of Pd(II) from 0.1 mol dm-3 HCl solution amounts to 97% with CyphosŽIL101. Both the increase in HCl concentration and the presence of NaCl have a negative influence on the extraction. The extent of extraction from 0.1 mol dm-3 HCl solution in the presence of 0.5 mol dm-3 NaCl is about 80% and from 3 mol dm-3 HCl is lower and amounts to 56%. The extraction of Pd(II) from aqueous 0.1 mol dm-3 HCl and from 0.1 mol dm-3 HCl in the presence of 0.5 mol dm-3 NaCl with this phosphonium ionic liquid is rapid and the equilibrium is achieved after 1 - 2 minutes. The extraction of Pd(II) from aqueous 3 mol dm -3 HCl is slower and the equilibrium is achieved after 5 - 6 minutes.
Czasopismo
Rocznik
Tom
Strony
99--101
Opis fizyczny
Bibliogr. 23 poz., rys.
Twórcy
autor
autor
autor
- Institute of Chemical Engineering and Technology, Poznan University of Technology, pl. M. Skłodowskiej-Curie 2, 60-965 Poznań, maciej.wisniewski@put.poznan.pl
Bibliografia
- 1. Sadyrbeava T. Z.: Separation of palladium(II) and platinum by bulk liquid membranes during electrodialysis, Sep. Sci. and Technol., 2006, 41, 3213.
- 2. Wisniewski M., Szymanowski J.: Industrial applications of noble metals' extraction. Polish J. Appl. Chem., 1996, 40, 17.
- 3. Cleare M. J., Grant R. A., Charlesworth P.: Separation of platinum group metals by use of selective solvent extraction techniques, Extractive Metallurgy, IMM, London, 1981.
- 4. Preston J. S., du Preez A. C.: Solvent extraction of platinum-group metals from hydrochloric acid solutions by dialkyl sulphoxides, Solvent Extr. Ion Exch, 2002, 20, 359.
- 5. Rovira M., Hurtado L., Cortina J. L., Arnaldos J., Sastre A. M.: Recovery of palladium(II) from hydrochloric acid solutions using impregnated resins containing Alamine 336, React. Funct. Polym., 1998, 38, 279.
- 6. Zhang A., Wanyan G., Kumagai M.: Association behavior of 4-acylpyrazolone derivative and tertiary amine of high molecular weight in antagonistic synergistic extraction of palladium, J. Solut. Chem., 2004, 33, 1017.
- 7. Szczepanska I., Borowiak-Resterna A., Wiśniewski M.: New pyridinecarboxamides for rapid extraction of palladium from acidic chloride media, Hydrometallurgy, 2003, 68, 159 - 170.
- 8. Regel-Rosocka M., Wisniewski M., Borowiak-Resterna A., Cieszynska A., Satre A. M.: Selective extraction of palladium(II) from hydrochloric acid solutions with piridinecarboxamides and ACORGA®CLX50, Sep. Purif. Techn., 2007, 53, 337.
- 9. Dakshinamoorthy A., Venugopal V.: Solvent extraction studies on the complexation of palladium with alpha benzoin oxime, J. Radioanal. Nucl. Ch., 2005, 3, 425.
- 10. Garifzyanov A. R., Zakharov S. V., Kryukov S. V., Galkin V. I., Cherkasov R. A.: Liquid extraction of noble metal ions with α-amino phosphonate, Russ. J. Gen. Chem.+, 2005, 75, 1208.
- 11. Giridhar P., Venkatesan K. A., Srinivasan T. G., Vasudeva Rao P. R.: Extraction of fission palladium by Aliquat 336 and electrchemical studies of direct recovery from ionic liquid phase, Hydrometallurgy, 2006, 81, 30.
- 12. Zhao H., Shuqian X., Peisheng M.: Review of ionic liquids as ‘green’ solvents for extractions, J. Chem. Technol. Biot., 2005, 80, 1089.
- 13. Davis J. H. Jr.: Task-Specific Ionic Liquids, Chem. Lett., 2004, 1072.
- 14. Zhao H., Xia S., Ma R.: Use of ionic liquids as ‘green’ solvents for extractions, J. Chem. Technol. Biotechnol, 2005, 80, 1089.
- 15. Regel-Rosocka M., Cieszynska K.,. Wisniewski M.: Extraction of zinc(II) with selected phosphonium ionic liquids, Przem. Chem., 2006, 85, 651.
- 16. Vidal S. T. M., Neiva Correia M. J., Marques M. M., Ismael M. R., Angelino Reis M. T.: Studies on the ionic liquids as potential extractants of phenolic compounds and metal ions, Sep. Sci. Technol., 2004, 39, 2155.
- 17. Matsumoto M., Mochiduki K., Fukunishi K., Kondo K.: Extraction of organic acid using imidazolium-based ionic liquids and their toxicity to lactobacillus rhamnosus, Sep. Purif. Technol., 2004, 40, 97.
- 18. Branco L. C., Crespo J. G., Afonso C. A. M.: Studies on the selective transport of organic compounds by using ionic liquids as novel supported liquid membranes, Chem. Eur. J., 2002, 8, 3865.
- 19. Fortunato R., Afonso C. A. M., Reis M. A. M., Crespo J. G.: Supported liquid membranes using ionic liquids: study of stability and transport mechanism, J. Membrane Sci., 2004, 242, 197.
- 20. Fortunato R., Branco L. C., Afonso C. A. M., Benavente J., Crespo J. G.: Electrical impedance spectroscopy characterisation of supported ionic liquid membranes, J. Membrane Sci., 2006, 270, 42.
- 21. Fadeev A. G., Meagher M. M.: Opportunities for ionic liquids in recovery of biofuels, Dalton Chem. Commun., 2001, 259.
- 22. Giridhar P., Venkatesan K. A., Srinivasan T. G., Vasudeva Rao P. R.: Extraction of uranium(VI) from nitric acid medium by 1,1 M tri-n-butylophosphate in ionic liquid diluent, J. Radioanal. Nucl. Chem., 2005, 265, 31.
- 23. Marczenko Z., Balcerzak M.: Spektrofotometryczne metody w analizie nieorganicznej, PWN, Warszawa, 1998
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0045-0052