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The removal of azo dye Acid Red 18 in hybrid photocatalysis/membrane processes systems was investigated. The photocatalytic reactions were conducted in the reactor with photocatalyst suspended in the solution. The reaction solution was recirculated through the ultrafiltration system. A commercially available titanium dioxide (AeroxideŽ P25, Degussa, Germany) was used as a photocatalyst. The solution after the photocatalytic/UF reaction was applied as the feed for the membrane distillation process. The changes of various parameters, including the concentration of the dye, pH and the conductivity of the solution, TOC and TDS content were analyzed during the process. It was found that azo dye Acid Red 18 could be successfully decolourised in the hybrid photocatalysis/UF system. The catalyst particles were retained in the feed solution by means of the ultrafiltration membrane so the obtained permeate was free of TiO2. The application of ultrafiltration together with the photocatalytic process results in the separation of photocatalyst from the treated solution but does not give the complete removal of organic matter from the reaction mixture. Membrane distillation applied with the permeate after the photocatalysis/UF process as a feed gives a complete separation of TOC from the treated solution and the obtained product is practically pure water.
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Tom
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94--98
Opis fizyczny
Bibliogr. 22 poz, rys.
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autor
autor
- Szczecin University of Technology, Institute of Chemical and Environment Engineering, Pułaskiego 10, 70-322 Szczecin, joanna@ps.pl
Bibliografia
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- 8. Fernández A., Lassaletta G., Jiménez V. M., Justo A., González-Elipe A. R., Herrmann J. -M., Tahiri H., Ait-Ichou Y.: Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass, quartz and stainless steel). Comparative studies of photocatalytic activity in water purification, Appl. Catal. B: Environ., 1995, 7(1 - 2), 49 - 63.
- 9. Grzechulska J., Morawski A. W.: Photocatalytic labyrinth flow reactor with immobilized P25 TiO2 bed for removal of phenol from water, Appl. Catal. B: Environ., 2003, 46(2), 415 - 419.
- 10. Balasubramanian G., Dionysiou D. D., Suidan M. T., Baudin I., Laîné J. -M.: Evaluating the activities of immobilized TiO2 powder films for the photocatalytic degradation of organic contaminants in water, Appl. Catal. B: Environ., 2004, 47(2), 73 - 84.
- 11. Venkata Subba Rao K., Subrahmanyam M., Boule P.: Immobilized TiO2 photocatalyst during long-term use: decrease of its activity, Appl. Catal. B: Environ., 2004, 49(4), 239 - 249.
- 12. Wintgens T., Melin T., Schäfer A., Khan S., Muston M., Bixio D., Thoeye C.: The role of membrane processes in municipal wastewater reclamation and reuse, Desalination, 2005, 178(1 - 3), 1 - 11.
- 13. Molinari R., Borgese M., Drioli E., Palmisano L., Schiavello M.: Hybrid processes coupling photocatalysis and membranes for degradation of organic pollutants in water, Catal. Today, 2002, 75, 77 - 85.
- 14. Molinari R., Palmisano L., Drioli E., Schiavello M.: Studies on various reactor configurations for coupling photocatalysis and membrane processes in water purification, J. Membrane Sci. 2002, 206, 399 - 415.
- 15. Sopajaree K., Qasim S. A., Basak S., Rajeshwar K.: An integrated flow reactor-membrane filtration system for heterogeneous photocatalysis. Part I. Experiments and modeling of a batch-recirculated photoreactor, J. Appl. Electrochem., 1999, 29(5), 533 - 539.
- 16. Sopajaree K., Qasim S. A., Basak S., Rajeshwar K.: An integrated flow reactor-membrane filtration system for heterogenous photocatalysis. Part II. Experiments on the ultrafiltration unit and combined operation. J. Appl. Electrochem., 1999, 29(9), 1111 - 1118.
- 17. Molinari R., Mungari M., Drioli E., Di Paola A., Loddo V., Palmisano L., Schiavello M.: Study on a photocatalytic membrane reactor for water purification, Catal. Today, 2000, 55(1 - 2), 71 - 78.
- 18. Molinari R., Grande C., Drioli E., Palmisano L., Schiavello M.: Photocatalytic membrane reactors for degradation of organic pollutants in water, Catal. Today, 2001, 67(1 - 3), 273 - 279.
- 19. Xi W., Geissen S. -U.: Separation of titanium dioxide from photocatalytically treated water by cross-flow microfiltration, Water Res., 2001, 35(5), 1256 - 1262.
- 20. Molinari R., Pirillo F., Falco M., Loddo V., Palmisano L.: Photocatalytic degradation of dye by using a membrane reactor, Chem. Eng. Proc., 2004, 43, 1103 - 1114.
- 21. Mozia S., Tomaszewska M., Morawski A. W.: A new photocatalytic membrane reactor (PMR) for removal of azodye Acid Red 18 from water, Appl. Catal. B: Environmental, 2005, 59(1 - 2), 133 - 139.
- 22. Mozia S., Tomaszewska M., Morawski A.W.: Removal of azo-dye Acid Red 18 in two hybrid membrane systems employing a photodegradation process, Desalination, 2006, 198, 183 - 190.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0045-0051