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Warianty tytułu
Języki publikacji
Abstrakty
The results of 1-butene-3-ol (1B3O) epoxidation over the titanium silicalite catalysts: TS-1, Ti-Beta, Ti-MCM-41 has been presented. The optimal parameters obtained for the individual catalyst were compared. The main functions describing the process were: the selectivity of transformation to 1,2-epoxy-3-butanol (1,2E3B) in relation to 1B3O consumed, the conversions of 1B3O and hydrogen peroxide and the selectivity of the transformation to organic compounds in relation to the H2O2 consumed. The main product of the epoxidation process was 1,2-epoksy-3-butanol, the chemical compounds having a lot of applications.
Czasopismo
Rocznik
Tom
Strony
49--52
Opis fizyczny
Bibliogr. 10 poz., schem., tab.
Twórcy
autor
autor
- Szczecin University of Technology, Institute of Organic Chemical Technology, ul. Pułaskiego 10, 70-322 Szczecin, jwajzberg@ps.pl
Bibliografia
- 1. Jung M. E., Jung Y. H.: Tetrahed. Lett., Rapid synthesis of ß-hydroxy-ß-amino acids, such as L-threonine, ß-hydroxyphenylalanine, and ß-hydroxyleucine, via an application of the Sharpless asymmetric epoxidation, 30, 1989, 6637.
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- 3. Valluri M., Hindupur R. M, Bijoy P., Labadie G., Avery M. A.: Total synthesis of epothilone B, Org. Lett., 2001, 23, 3607.
- 4. Hindupur R. M., Panicker B., Valluri M., Avery M. A.: Total synthesis of epothilone A, Tetrahed. Lett., 2001, 42, 7341.
- 5. Kąkol B., Jezierska-Zięba M., Kamieński J., Bełdowicz M., Szpakiewicz M., Soliński J.: Chlorowodorek (2R, 3S)-fenyloizoseryny jako półprodukt do otrzymywania Paclitaxelu, Przem. Chem., 2002, 81, 780.
- 6. White J. D., Avery M. A., Choudhry S. C., Dhingra O. P., Kang M., White A. J.: Stereocontrolled Synthesis of the C(1)-C(17) Half of Boromycin, J. Am. Chem. Soc., 1983, 105, 6517.
- 7. Thangaraj A., Kumar R., Ratnasamy P.: Direct catalytic hydroxylation of benzene with hydrogen peroxide over titanium-silicalite zeolites, Appl. Catal., 1990, 57, L1-L3.
- 8. Camblor M. A., Corma A., Martinez A., Perez-Pariente J.: Synthesis of a titaniumsilicoaluminate isomorphous to zeolite beta and its application as a catalyst for the selective oxidation of large organic molecules, J. Chem. Soc., 1992, 8, 589.
- 9. Grün M., Unger K. K, Matsumoto A., Tatsumi K.: Novel pathways for the preparation of mesoporous MCM-41 materials: control of porosity and morphology, Micropor. Mesopor. Mater. 27, 1999, 207.
- 10. Brill W. F.: The Origin of Epoxides in the Liquid Phase Oxidation of Olefins with Molecular Oxygen, J. Am. Chem. Soc., 1963, 85, 141.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0045-0040