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Photosensitized decomposition of textile dyes on TiO2-Tytanpol A11 and TiO2-Degussa P25

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The photoassisted decomposition of five organic dyes (Reactive Red 198 (RR198), Reactive Black 5 (RB5), Acid Black 1 (AB1), Direct Green 99 (DG99) and Acid Blue 7 (AB7)) has been investigated in aqueous solution in the presence of two kinds of TiO2 photocatalysts: TiO2-Tytanpol A11 (,,Police" Chemical Factory, Poland) and TiO2-Degussa P25 (,,Degussa" Germany) and under the illumination by the Vis light. The results suggest that the value of the adsorption of the dyes on the photocatalyst surface is the controlling step of the photosensitized degradation of dyes. The A11 photocatalyst demonstrates higher activity than P25. This effect is diffrent from the one obtained under the UV illumination, where P25 shows a much higher activity. Additionally, it was investigated that for both phototocatalysts used the degree of dyes decomposition decreased with the increasing of the maximum absorption of the dyes.
Rocznik
Strony
150--152
Opis fizyczny
Bibliogr. 8 poz., rys.
Twórcy
  • Institute of Chemical and Environment Engineering, Szczecin University of Technology, Pułaskiego 10, 70-322 Szczecin, bzielinska@ps.pl
Bibliografia
  • (1) Alhakimi G., Studnicki L. H., Al-Ghazali M.: Photocatalytic destruction of potassium hydrogen phthalate using TiO2 and sunlight: application for the treatment of industrial wastewater, J. ,Photochem. Photobiol. A, 2003, 154, 219.
  • (2) Docters T., Chovelon J. M., Herrmann J. M., Deloume J. P.: Syntheses of TiO2 photocatalysts by the molten salts method. Aplication to the photocatalytic degradation of Prosulfuron, Appl. Catal. B, 2004, 50, 219.
  • (3) Ding Z., Lu G. Q., Greenfield P. F.: Role of the crystallite phase of TiO2 in heterogeneous photocatalysis for phenol oxidation in water, J. Phys. Chem. B, 2000, 104, 4815.
  • (4) Baran W., Makowski A., Wardas W.: The influence of FeCl3 on the photocatalytic degradation of dissolved azo dyes in aqueous TiO2 suspension, Chemosphere, 2003, 53, 87.
  • (5) Moon J., Yun Ch. Y., Ch K-W.: Photocatalytic activation of TiO2 under visible light using Acid Red 44, Catal. Today, 2003," 87, 77.
  • (6) Vinodgopal K., Wynkoop D. E., Kamat P. V: Environmental photochemistry on semiconductor surfaces: photosensitized degradation of a textile azo dye, Acid Orange 7, on TiO2 particles using visible light, Environ. Sci. Technol., 1996, 30, 1660.
  • (7) Zielińska B., Grzechulska J., Morawski A. W.: Photocatalytic decomposition of textile dyes on TiO2-Tytanpol A11 and TiO2-Degussa P25, J. Photochem. Photobiol. A, 2003, 157, 65.
  • (8) Zielińska B., Grzechulska J., Kaleńczuk R. J., Morawski A.W.: The pH influence on photocatalytic decomposition of organic dyes over A11 and P25 titanium dioxide, Appl. Catal. B, 2003, 45, 293.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0039-0078
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