Synthesis and characteristics of salen catalysts supported on hydroxyl functionalized methacrylic copolymers

• Autorzy: Bukowski W. , Bukowska A.
• Języki publikacji: EN

Abstrakty

EN

Salen supported polymer catalysts were obtained as a result of a multi-stage chemical modification of three-components 2-hydroxyethyl and 2-hydroxypropyl metacrylate copolymers. The catalysts were tested in the model reaction of acetic acid with epichlorohydrin.

Słowa kluczowe

EN

salen supported polymer catalysts; 2-hydroxyethyl methacrylate; 2-hydroxypropyl metacrylate; acetic acid; epichorohydrin

PL

katalizatory salenowe; metakrylany; kwas octowy; epichlorohydryna

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2006
• Tom: Vol. 8, nr 3
• Strony: 76--78
• Opis fizyczny: Bibliogr. 6 poz., rys., tab.

Twórcy

autor

Bukowski W.

autor

Bukowska A.

• Faculty of Chemistry, Rzeszów University of Technology,al. Powstańców W-wy 6, 35-959 Rzeszów

Bibliografia

• (1) Canali L., Sherrington D. C: Utilisation of Homogeneous and Supported Chiral Metal(salen)complexes in Asymmetric Catalysis, Chem. Soc. Rev., 1999, 28, 85.
• (2) Leadbeater N. E., Marco M., Preparation of Polymer- Supported Ligands and Metal Complexes for Use in Catalysis, Chem. Rev., 2002, 102, 3217.
• (3) Song C. E., Lee S.: Supported Chiral Catalysts on Inorganic Materials, Chem. Rev., 2002, 102, 3495.
• (4) Canali L., Cowan E., Deleuze H., Gibson C. L., Sherrington D. C: Polystyrene and Polymethacrylate Resin- supported Jacobsen's Alkene Epoxidation Catalyst, J. Chem. Soc, Perkin Trans. 1, 2000, 2055.
• (5) Larrrow J. F., Jacobsen E. N.: A Practical Method for the Large-scale Preparation of [N,N’-bis(3,5-di-tertbutylsalicylidene)l,2-cyclohexanediaminato(2-)]manganese(III) Chloride, a Highly Enantioselective Epoxidation Catalyst, J. Org. Chem., 1994, 59, 1939.
• (6) Bukowska A., Bukowski W., Noworól J.: New 2-Hydroxyethyl Methacrylate Resins with good swelling characteristics, J. Appl. Polym. Sci., 2006 in press