Glycidyl methacrylate copolymers modified with diamines as effective nucleophilic scavengers

• Autorzy: Bukowski W. , Bukowska E.
• Języki publikacji: EN

Abstrakty

EN

Three-components glycidyl methacrylate terpolymers were chemically modified in the reaction with ethylenediamine or trans-1,2-diaminocyclohexane. The reactive resins which contain 1.6 - 2.0 mol N/g were obtained as a result. The latter resins were tested as rapid scavengers of salicylaldehydes, benzoil chloride and 4,4'-diphenylmetane diisocyanate.

Słowa kluczowe

EN

functional polymers; scavenger resins

PL

polimery funkcjonalne; żywice

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2006
• Tom: Vol. 8, nr 3
• Strony: 73--75
• Opis fizyczny: Bibliogr. 6 poz., tab.

Twórcy

autor

Bukowski W.

autor

Bukowska E.

• Faculty of Chemistry, Rzeszów University of Technology al. Powstańców W-wy 6, 35-959 Rzeszów

Bibliografia

• (1) Sherrington D. C.: Polymer-Supported Reagents, Catalysts, and Sorbents: Evolution and Exploitation - A Personalized View, J. Polym. Sci., Part A: Polym. Chem., 2001, 39, 2364.
• (2) Buchmeiser M. R. (Editor): Polymeric Materials in Organic Synthesis and Catalysis, Wiley-VCH, Weinheim 2003.
• (3) Boot R. J., Hodges J. C.: Solid-supported Reagent Strategies for Rapid Purification of Combinatorial Synthesis Products, Acc. Chem. Res., 1999, 32, 18.
• (4) Ley S. V., Baxendale I. R., Bream, R. N., Jackson P. S., Leach A. G., Longbottom D. A., Nesi M., Scott J. S., Storer R. I., Taylor S. J.: Multi-step Organic Synthesis Using Solid-supported Reagents and Scavengers: a New Paradigm in Chemical Library Generation, J. Chem. Soc, Perkin Trans. 1, 2000, 3815.
• (5) Eames J., Watkinson M.: Polymeric Scavenger Reagents in Organic Synthesis, Eur. J. Org. Chem, 2001, 1213.
• (6) Bukowska A., Bukowski W., Noworol J.: Three Components Terpolymers of Glycidyl Methacrylate with Good Swelling Characteristics, submitted to J. Appl. Polym. Sci., 2006.