Epoxidation of allylic compounds over Ti-MCM-48 catalyst

• Autorzy: Wróblewska A.
• Języki publikacji: EN

Abstrakty

EN

The results of the epoxidation of allylic compounds (allyl alcohol, methallyl alcohol and methallyl chloride) to corresponding epoxides (glycidol, 2-methylglycidol and 2-methylepichlorohydrin, respectively) with hydrogen peroxide over Ti-MCM-48 catalyst have been presented. The epoxidation was carried out with 30 wt% hydrogen peroxide in methanol used as a solvent in an autoclave. The optimum technological parameters (temperature, the molar ratio allylic compound/H2O2, methanol concentration, Ti-MCM-48 concentration and reaction time) for the epoxidation of each allylic compound were presented.

Słowa kluczowe

EN

epoxidation; glycidol; 2-methylglycidol; 2-methylepichlorohydrin; Ti-MCM-48

PL

epoksydacja; glicydol; 2-metyloglicydol; 2-metyloepichlorohydryna; Ti-MCM-48

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2006
• Tom: Vol. 8, nr 2
• Strony: 80--82
• Opis fizyczny: Bibliogr. 7 poz., tab.

Twórcy

autor

Wróblewska A.

• Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin,

Bibliografia

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