Tytuł artykułu
Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Języki publikacji
Abstrakty
Trioxane (C6H6O3) is formed during catalytic polymerization of the formaldehyde. Separation is carried out from a gas or liquid mixture including part of the unprocessed stock and the by-products like: methanol, formic acid, methylal, methyl formate and others, by means of: extraction, distillation, melt crystallization or cooling crystallization. In this paper the kinetics of vacuum crystallization from solution, chemical composition of vapour and crystals hardness versus the temperature of the process have been presented, respectively. It has been found that trioxane is a well-crystallized substance with a relatively high effective growth rate and with simultaneously big resistance to attrition. In the light of the presented data the vacuum method of trioxane crystallization seems to be a promising alternative instead of the cooling crystallization, as the cooling solution generates an intensive incrustation on the heat exchangers surfaces and simultaneously is vastly energy consuming. The proposed method eliminates these difficulties. Additionally, the simplicity of operating and the economic indexes like capital costs or energy consumption are propitious in comparison to the cooling method.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
70--72
Opis fizyczny
Bibliogr. 2 poz., rys., tab.
Twórcy
Bibliografia
- (1) Patent application no. P 364 264 (2004)
- (2) Gues R.: et al., J. Chem. Sod. Faraday Trans., 91, (18), 3185 - 3187, (1995)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0039-0018
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.