Correlation of kinetic parameters of sodium acetate thermal decomposition

Olszak-Humienik, M.; Możejko, J.

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Tytuł artykułu

Correlation of kinetic parameters of sodium acetate thermal decomposition

Autorzy

Olszak-Humienik M. , Możejko J.

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http://content.sciendo.com/view/journals/pjct/pjct-overview.xml

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Języki publikacji

Abstrakty

Thermogravimetry and differential thermal analysis were used in the study of the kinetics of non-isothermal sodium acetate's thermal decomposition under an air atmosphere. The diagrams were recorded on a sample mass of 20 mg at temperatures ranging from 20 to 600°C. Five different heating rates were used. The relations of α vs. T were estimated from the mass losses. The values of the kinetic parameters (activation energy and the pre-exponential factor) of the thermal decomposition were calculated from α(T) data in several ways: by using the integral method, applying the Coats-Redfern approximation, the modified isoconversional Coats-Redfern method, the differential method of Friedman and the Kissinger's method. A correlation was found between kinetic parameters estimated by different kinetic methods.

Słowa kluczowe

kinetic parameters kinetics of thermal decomposition sodium acetate

parametry kinetyczne kinetyka termicznego rozkładu octan sodu

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2006

Tom

Vol. 8, nr 2

Strony

22--25

Opis fizyczny

Bibliogr. 22 poz., rys., tab.

Twórcy

autor

Olszak-Humienik M.

autor

Możejko J.

Szczecin University of Technology, Institute of Chemistry and Environmental Protection, al. Piastów 42, 71-065 Szczecin, magol@ps.pl

Bibliografia

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Bibliografia

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