Synthesis of peroxyesters using polymer-supported phase transfer catalysts

• Autorzy: Baj S. , Siewniak A. , Hefczyc J.
• Języki publikacji: EN

Abstrakty

EN

A synthesis method of peroxyesters from alkyl hydroperoxides and acid chlorides catalyzed by polymer-supported phase transfer catalysts was introduced. This method makes it possible for the catalyst to be easily separated from the reaction product and be used in the continuous process.

Słowa kluczowe

EN

peroxyesters; polymer-supported phase transfer catalyst

PL

nadtlenoestry; kataliza przeniesienia międzyfazowego

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2006
• Tom: Vol. 8, nr 1
• Strony: 2--3
• Opis fizyczny: Bibliogr. 13 poz., tab., rys.

Twórcy

autor

Baj S.

autor

Siewniak A.

autor

Hefczyc J.

• Silesian University of Technology, Department of Chemical Organic Technology and Petrochemistry, ul. Krzywoustego 4, 44-100 Gliwice,

Bibliografia

• (1) Baj S., Chrobok A.: The Synthesis of Organic Peresters via the Phase Transfer Catalysis, Polish J. Chem., 1999, 73, 1185.
• (2) Baj S., Chrobok A.: PTC Acylation of organic hydroperoxides with use of sodium carbonate as HCl scavenger. Kinetic study, Polish J. Appl. Chem., 2002, 1, 31.
• (3) Baj S., Chrobok A., Gottwald I.: Kinetic Study of Hydroperoxides Acylation in the Presence of Sodium Carbonate in Solid-Liquid PTC System, Applied Catal. A: General, 2002, 224, 89.
• (4) Ando W. (Editor): Organic Peroxides, Wiley- Interscience, New York, 1992.
• (5) Swern D. (Editor): Organic Peroxides, Wiley-Interscience, New York, London, Sydney, Toronto, 1970.
• (6) Kulicki Z.: Studia nad kinetyką autooksydacji lumenu i jego chlorowcowych i nitowych pochodnych, Zesz. Nauk. Pol. Śl. Chem., 1967, 183, 61.
• (7) Regen S. L.: Triphase Catalysis, J. Am. Chem. Soc, 1975, 97, 5556.
• (8) Starks Ch. M., Liotta Ch. L.: Phase-Transfer Catalysis. Fundamentals, Applications and Industrial Perspectives, Chapman&Hall, New York, London, 1994.
• (9) Sasson Y., Newmann R. (Editors): Handbook of Phase Transfer Catalysis, Balckie Academic and Professional, London, Weinheim, New York, Tokyo, Melbourne, Madras, 1997.
• (10) Miyajima F., Iijima X., Tomoi M., Kimura Y.: Aromatic nucleophilic fluorination with KF catalyzed by polymer-supported phosphonium salts under solid-solid-liquid phase transfer conditions, React. Funct. Polym., 2000, 43, 315.
• (11) McKenzie W. M., Sherrington D. C: Polymer-supported Phase Transfer Catalysts in Solid-Liquid Reactions, J. Chem. Soc. Chem. Commun., 1978, 541.
• (12) Heffernan J. G., Sherrington D. C: Optimization of Polymer-supported Oligoethers as Solid-Liquid Phase Transfer Catalysts, Tetrahedron Lett., 1983, 24, 1661.
• (13) Desikan S., Doraiswamy L. K.: Enhanced activity of polymer-supported phase transfer catalysts, Chem. Eng. Sci., 2000, 55, 6119