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Polyglycerol esters of lauric acid with defined hydrophile-lipophile properties

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The synthesis of polyglycerol esters of lauric (dodecanoic) acid was investigated. The effect of the temperature, the catalyst concentration and the time of the reaction on glycerol polymerization and polyglycerol esterification was examined. It has been shown that changes of this parameters influenced the composition of emulsifiers and the HLB value. It was found that mixtures of mono-, di-, triacylglycerols and esters of di- and triglycerols are the products of esterification. The obtained emulsifiers with the HLB values from 4.9 - 14.0 may be used to stabilize the O/W and W/O emulsions. For the preparation of emulsifiers - ester of polyglycerols and fatty acids, renewable fatty raw materials may be used.
Rocznik
Strony
66--71
Opis fizyczny
Bibliogr. 16 poz., tab., rys.
Twórcy
autor
  • Gdańsk University of Technology, Department of Technology of Fats and Detergents, ul. Narutowicza 11/12, 80-952 Gdańsk
autor
  • Gdańsk University of Technology, Department of Technology of Fats and Detergents, ul. Narutowicza 11/12, 80-952 Gdańsk
autor
  • Gdańsk University of Technology, Department of Technology of Fats and Detergents, ul. Narutowicza 11/12, 80-952 Gdańsk
Bibliografia
  • (1) Hasenhuettl G., Hartel R.: Food Emulsifiers and Their Applications, Chapman & Hall, New York, 1997.
  • (2) Lemke D. Wayne: Processes for preparing linear polyglycerols and polyglycerols esters, U.S. Patent Application 20020058781, 2002.
  • (3) Jakobson G., Siemanowski W., Dillenburg H.: Process for the preparing of diglycerol and/or polyglycerol, U.S. Patent 5243086, 1993.
  • (4) Harris E., Hees U., Bunte R., Hachgenei J. W., Kuhm P.: Process for the production of oligoglycerol mbrtures of increased diglycerol content, U.S. Patent 5349094, 1994.
  • (5) Marquez-Alvarez C., Sastre E., Perez-Pariente J.: Solid catalyst for the synthesis of fatty esters of glycerol, polyglycerols and sorbitol from renewable resources, Top Catal, 2004, 27, 105.
  • (6) Charlemagne D., Legoy M. D.: Enzymatic synthesis of polyglycerol fatty acid esters in a solvent free system, J. Am. Oil Chem. Soc, 1995, 72, 61.
  • (7) Van Heteren J., Poot C., Rechweg F., Stewart M.: Polyglycerol esters, U.S. Patent 4456627, 1984.
  • (8) Bunczek M., Mazzone P., Urnezis P., Greeberg M., Yatka R., Richey L., Chapdelaine A.: Chewing gum containing polyglycerol ester, PCT International Patent Application WO 96/13986 A, 1997.
  • (9) Dziennik Ustaw Rzeczypospolitej Polskiej, Nr 9, poz. 72, 2001.
  • (10) European Parlament and Council Directive 95/2/EC, 20 February 1995.
  • (11) Code of Federal Regulation, Vol. 3, Title 21, Food and Drug Administration, US Government, 2003.
  • (12) Szeląg H., Zwierzykowski W.: Determination of Monoacylglycerols, Monoacylethyleneglycols, Glycerol and Ethylene Glycol Contents in Products of Corresponding Synthesis, Pollena-TŚPK, 1992, 36, 337.
  • (13) IUPAC, 1979 (International Union of Pure and Applied Chemistry, Commission on Oils, Fats and Derivatives). Determination of the Acid Value (A. V.) and the Acidity. In: Standard Methods for the Analysis of oils, Fats and Derivates. Part 1 (Section 1 and 2), 6th ed., Oxford Pergamon Press, s. 52.
  • (14) Neissner R.: Polyglycerine und Fettsaure -Polyglycerinpartialester (Herstellung, Kennzahlen, DC -Trennung), Fette, Seifen, Anstrichmittel, 1980, 3, 93.
  • (15) Becher P.: Hydrophile - lipophile balance, in: Becher P. (Ed.), Encyclopedia of Emulsion Technology, vol. 2, Marcel Dekker, New York, 1985.
  • (16) Mengual O., Meunier G., Cayre I., Puech K., Snabre P.: Characterisation of instability of concentrated dispersions by a new optical analyzer: the TURBISCAN MA 1000, Colloids Surf. A, 1999, 152, 111.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0035-0052
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