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TiO2-nitrogen doped for both the UV and Visible light photocatalysis

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The investigation on incorporating the nitrogen group into titanium dioxide (Degussa P25) in order to obtain a visible-light active TiO2-xNx photocatalyst was performed. Titanium dioxide was modified by a heat treatment at different temperatures (450, 500 and 550°C) in ammonia atmosphere for 3, 6, 8 or 10 hours, respectively. The presence of the nitrogen groups on the catalyst surface was determined by the Fourier Transform Infrared Spectroscopy (FT-IR). The amount of the nitrogen built in TiO2 was determined on the basis of the thermogravimetric analysis (TG/DTA). It was found that the modification of TiO2 with ammonia resulted in a shift of the absorption spectrum of TiO2 towards solar spectrum wavelength (lmax = 479 nm; EG = 2.59 eV). The sample of the highest photoactivity contained ca. 2% of nitrogen. The modification of titanium dioxide with nitrogen increases the range of practical applications of TiO2 in water treatment processes due to the enhancement of its activity under both UV and visible light. This gives the possibility to utilize the solar light.
Rocznik
Strony
81--86
Opis fizyczny
Bibliogr. 16 poz., rys.
Twórcy
  • Szczecin University of Technology, The Institute of Chemical and Environment Engineering, Dep. of Water Technology and Environment Engineering, ul. Pułaskiego 10, 70-322 Szczecin
autor
  • Szczecin University of Technology, The Institute of Chemical and Environment Engineering, Dep. of Water Technology and Environment Engineering, ul. Pułaskiego 10, 70-322 Szczecin
Bibliografia
  • (1) Schiavello M.: (Ed.), Photocatalysis in Environment; Trends and Application, NATO ASI Series C, Vol. 238, Kluwer Academic (London), 1987.
  • (2) Ollis D. F., Al-Ekabi H.: (Eds.), Photocatalytic Purification and Treatment of Water and Air, Elsevier, Amsterdam, 1993.
  • (3) Bahnemann D., Hutzinger O.: (Hrg.), The Handbook of Environmental Chemistry, Vol.2: Reactions and Process, Part L: Environmental Photochemistry. Boule P.: (Ed.), Springer Verlag (Heidelberg), 1999.
  • (4) Blake D. M.: Bibliography of work on the photocatalytic removal of hazardous compounds from water and air, NREL/TP-430-22197, National Renewable Energy Laboratory, Golden Co., 1997 and 1999.
  • (5) Herrmann J. -M.: Environmental Catalysis,. Jansen F., van Santen R. A.: (Eds), Catalytic Science Series, Vol. l, Chap. 9, Imperial College Press, London, pp. 171 - 194, 1999.
  • (6) Herrmann J. -M., Guillard C.: Photocatalytic degradation of pesticides in agricultural used waters. Acad C. R.: Sci (Paris), 2000, 3, 417 - 422.
  • (7) Matos J., Laine J., Herrmann J. -M.: Association of activated carbons of different origins with titania in the photocatalytic purification of water, Carbon, 1999, 37, 1870 - 1872.
  • (8) Lachheb H., Puzenat E., Houas A., Ksibi M., Elaloui E., Guillard C., Herrmann J. -M.: Photocatalytic degradation of various types of dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue) in water by UV-irradiated titania, Appl. Catal. B: Environ., 2002, 39, 75 - 90.
  • (9) Asahi R., Morikawa T., Ohwaki T., Aoki K., Taga Y.: Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides, Science, 2001, 293, 269 - 272.
  • (10) Pradhan K., Reucroft P. J.: A study of growth and morphological features of TiOxNy thin films prepared by MOCVD, J. Cryst. Growth, 2003, 250, 588 - 594.
  • (11) Martin N., Banakh O., Santo A. M. E., Springer S., Sanjinés R., Takadoum J., Lévy F.: Correlation between processing and properties of TiOxNy thin films sputter deposited by the reactive gas pulsing technique, App. Surf. Science, 2001, 185, 123 - 133.
  • (12) Kazemeini M. H., Berezin A. A., Fukuhara N.: Formation of thin TiNxOy films by using a hollow cathode reactive DC sputtering system, Thin Solid Films, 2000, 372, 70 - 77.
  • (13) Ihara T., Miyoshi M., Iriyama Y., Matsumoto O., Sugihara S.: Vible-light-active titanium oxide photocatalyst realized by an oxygen-deficient structure and by nitrogen doping, Appl. Catal. B: Environ., 2003, 42, 403 - 409.
  • (14) Li D., Haneda H.: Synthesis of nitrogen-containing ZnO powders by spray pyrolysis and their visible-light photocatalysis in gas-phase acetaldehyde decomposition, J. Photochem. and Photobiol. A: Chem., 2003, 155, 171 - 178.
  • (15) Arana J., Dona-Rodríguez J. M., Tello Rendón E., Garriga i Cabo C., González-Díaz O., Herrera-Melián J. A., Pérez-Pena J., Colón G., Navío J. A.: TiO2 activation by using activated carbon as a support Part II. Photoreactivity and FTIR study, Appl. Catal. B: Environ., 2003, 44, 153 - 160.
  • (16) Einaga H., Futamura S., Ibusuki T.: Heterogeneous photocatalytic oxidation of benzene, toluene, cyclohexene and cyclohexane in humidified air: comparison of decomposition behavior on photoirradiated TiO2 catalyst, Appl. Catal. B: Environ., 2002, 38, 215 - 225.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0034-0103
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