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Tytuł artykułu

Jet pump crystallizers in the reaction crystallization processes of sparingly soluble salts

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The research results concerning the reaction crystallization processes of hydroxyapatite (HAP) and struvite (MAP) in the two flow jet pump DTM crystallizers with the internal circulation of the suspension are presented. Calcium or/and magnesium ions precipitation from the diluted water solutions was taken into effect by the addition of ammonium dihydrogenphosphate NH4H2PO4 solution in the alkali environment (T = 298 K, pH = 9, t = 900 s). The influence of calcium (0.1 - 1.5 mass %) and magnesium (0.1 - 2.0 mass %) ions concentration in the feeding stream on the resulting product crystal size distribution was investigated. The test results can be utilized in the improvement of the jet pump DTM crystallizers design. This construction is especially recommended for the precipitation of the calcium or/and magnesium ions, as well as the phosphate(V) ions from the diluted solutions or the liquid wastes.
Rocznik
Strony
56--63
Opis fizyczny
Bibliogr. 23 poz., tab., rys.
Twórcy
autor
  • Wrocław University of Technology, Institute of Inorganic Technology and Mineral Fertilizers, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław
  • Wrocław University of Technology, Institute of Inorganic Technology and Mineral Fertilizers, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław
  • Wrocław University of Technology, Institute of Inorganic Technology and Mineral Fertilizers, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław
  • Silesian University of Technology, Department of Chemical & Process Engineering, ul. Strzody 7, 44-101 Gliwice, Poland
Bibliografia
  • (1) Rojkowski Z., Synowiec J.: Krystalizacja i krystalizatory; WNT: Warszawa, 1991.
  • (2) Mullin J. W.: Crystallization; Butterworth-Heinemann: Oxford, 1993.
  • (3) Myerson A. S.: Handbook of Industrial Crystallization; Butterworth-Heinemann: Boston, 1993.
  • (4) Mersman A.: Crystallization Technology Handbook; Marcel Dekker, New York, 1995.
  • (5) Goliński J. A., Troskolański A. T.: Strumienice; WNT: Warszawa, 1979.
  • (6) Matveenko P. S., Stabnikov V. N.: Strujnye apparaty v piščevoj promyšlennosti; Piščevaja promyšl., Moskva, 1980.
  • (7) Matynia A.: Crystallizers with a jet pump, Inż. Ap. Chem., 1997, 36, 6, 9 (in Polish).
  • (8) Valsami-Jones E.: Recent scientific and technical developments: Calcium phosphate precipitation, Scope Newslett., 2001, 41, 8.
  • (9) Parsons S.: Recent scientific and technical developments: Struvite precipitation, Scope Newslett., 2001, 41, 15.
  • (10) Matynia A., Koralewska J., Kwiecień J.: The influence of continuous crystallization process parameters on the crystal size distribution of hydroxyapatite, Pol. J. Appl. Chem., 2002, XLVI, 81.
  • (11) Matynia A., Koralewska J., Piotrowski K.: The influence of the process parameters on the hydroxyapatite continuous crystallization kinetics, Pol. J. Chem. Technol, 2005, 7, 1, 44.
  • (12) Matynia A., Koralewska J., Kwiecień J.: The influence of the continuous crystallization process parameters on the crystal size distribution of struvite, Pol. J. Chem. Technol, 2003, 5, 4, 83.
  • (13) Matynia A., Koralewska J., Piotrowski K., Wierzbowska B.: The influence of the process parameters on the struvite continuous crystallization kinetics, Chem. Eng. Comm. (in press).
  • (14) Pol. Pat. No. 96 631, 1978.
  • (15) Matynia A., Bechtold Z., Wierzbowska B.: An algorithm for the calculation of vacuum crystallizers with jet pump and internal circulation of suspension, Inż. Ap. Chem., 1981, 20, 5, 14 (in Polish).
  • (16) Matynia A., Bechtold Z., Wierzbowska B.: Application of a jet pump in crystallizers with inner circulation, Scientific Papers of the Inst. Heat Eng. and Fluid Mechanics, Wrocław University of Technology, 1998, 53, 627 (in Polish).
  • (17) Pol. Pat. No. 98 137, 1980.
  • (18) Matynia A., Wierzbowska B., Bechtold Z.: Vacuum crystallizer with liquid jet pump and the receipt of classified product, Inż. Ap. Chem., 1984, 23, 4, 18 (in Polish).
  • (19) Bechtold Z., Matynia A., Małasińska M.: Circulation of suspension in crystallizer with jet pump, Inż. Chem. Proc, 2001, 22, 3B, 229 (in Polish).
  • (20) Bechtold Z., Matynia A., Małasińska M.: Visualisation of suspension movement in the crystallizer with a jet pump, Inż. Ap. Chem., 2001, 40, 5, 9 (in Polish).
  • (21) Bechtold Z., Matynia A., Małasińska M.: Production of suspension in the apparatus with a jet pump, Inż. Ap. Chem., 2003, 42, 3s, 13 (in Polish).
  • (22) Bechtold Z., Małasińska M., Koralewska J., Piotrowski K., Matynia A.: The influence of suspension properties on the minimal power of feeding stream in the DTM MSMPR crystallizer with jet pump, Chemistry for Agriculture, 2005, 6, 887.
  • (23) Matynia A., Wierzbowska B., Koralewska J., Piotrowski K., Bechtold Z., Ćwiertnia E.: DTM type crystallizer with jet pump in reaction crystallization processes. A novel efficacious approach, Chemistry for Agriculture, 2005, 6, 879.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0034-0100
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