Studies on the processes relating to the reduction of fertilizers manufacturing and their influence on the environment

Grzmil, B.

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Tytuł artykułu

Studies on the processes relating to the reduction of fertilizers manufacturing and their influence on the environment

Autorzy

Grzmil B.

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Abstrakty

The influence of fertilizers manufacturing and their application on the environment has been discussed. The necessity of curbing the negative impact of their production and application was pointed out. The studies conducted at the Institute of Inorganic Chemical Technology and the Environment Engineering at the Technical University of Szczecin, were thoroughly examined. The research regarded the production of solid and liquid mineral fertilizers demonstrating a variety of characteristics, the use of the side effects with a view to obtaining potassium fertilizers, as well as the recovery of phosphates from sewage in the form of useful products.

Słowa kluczowe

environment solid and liquid fertilizers potassium sulphate phosphate recovery

środowisko nawozy płynne nawozy stałe siarczan potasu odzysk fosforanów

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2005

Tom

Vol. 7, nr 3

Strony

49--55

Opis fizyczny

Bibliogr. 46 poz., tab., rys.

Twórcy

autor

Grzmil B.

barbara.grzmil@ps.pl

Szczecin University of Technology, Institute of Chemical and Environment Engineering, ul. Pułaskiego 10, 70-322 Szczecin

Bibliografia

(1) http://www.fertilizer.org/ifa - International Fertilizer Industry Association, 2005.
(2) Górecki H.: Environmental trends in fertilizer production and use, Przem. Chem., 2003, 82, 833.
(3) Czuba R.: Minerał Fertilization of Cultivated Plants; Chemical Plant „Police": Police, 1996.
(4) http://www.efma.org - European Fertilizer Manufactures Association, 2005.
(5) Górecki H.: Novel Technologies and New Techniques of Fertilizers Application in the World, Chemik, 1994, 47, 48.
(6) Glabisz U., Gabryel H.: The influence of aluminum and fluorine compounds on gypsum crystallization in the dihydrate process of phosphoric acid manufacturing. Przem. Chem., 1973, 52, 293.
(7) Glabisz U., Gabryel H.: The influence of fluoride complexes on the phosphogypsum crystallization, Przem. Chem., 1976, 55, 148.
(8) Glabisz U., Kacalski L., Grzmil B., Kuzko A., Kic B., Gabryel H.: The procedure of potassium hydroxide and synthetic fluorite manufacturing, Pat. PL 144 599, 1984.
(9) Glabisz U., Gabryel H., Kic B., Kacalski L., Grzmil B.: Utilization the waste fluorine from the fertilizer industry, Przem. Chem., 1989, 68, 20.
(10) Glabisz U., Grzmil B., Kic B.: Obtaining pure Solutions of phosphoric salts from the wet process phosphoric acid through the melamine phosphate, Prace Naukowe PS, 1990, 366, 347.
(11) Glabisz U., Gabryel H., Kic B., Grzmil B., Kacalski L.: Studies on the phosphoric raw material decomposition with the mineral acid in the presence of potassium ions. Ore pulping with the mixture of H2SO4 and KHSO4, Przem. Chem., 1984, 63, 201.
(12) Glabisz U., Gabryel H., Kic B., Grzmil B.: Studies on the phosphoric raw material decomposition with the mineral acid in the presence of potassium ions. Ore pulping with phosphoric acid in the presence of potassium ions. Chemical Industry, 1984, 63, 260.
(13) Glabisz U., Kacalski L.: The influence of inorganic impurities of the wet process phosphoric acid: aluminum, iron and fluorine on the solubility of the fertilizing potassium polyphosphate, Przem. Chem., 1979, 58, 374.
(14) Glabisz U., Grzmil B.: Studies on the preparation of micronutrients polyphosphate complexes. I. Determination of the physicochemical properties and the crystalline structure of the products, Pol. J. Appl. Chem., 1991, 35, 55.
(15) Grzmil B., Glabisz U.: Studies on the preparation of micronutrients polyphosphate complexes. II. Identification and quantitative determination of individual forms of condensed phosphates, Pol. J. Appl. Chem., 1991, 35, 65.
(16) Glabisz U., Kic B., Grzmil B.: Manufacturing of Low-Chloride Multicomponent Fertilizers Based on Aqueous Solution, J. Agric. Food Chem., 1992, 40, 1393.
(17) Low-Cl NPK and NPK-Mg fertilizers from KCl, Phosph. Potass., 1993, 185, 19.
(18) Glabisz U., Skowroński B., Kic B., Grzmil B., Fijołek Ł., Drobotowski J., Dziarkowski R., Masztalerz P., Krużyński Cz.: The procedure of manufacturing the multicomponent NPK fertilizer with a low content of chlorides and the adjustable K2O/P2O5 ratio, Pat. PL 158179, 1988.
(19) Grzmil B., Kic B., Kałucki K., Szczepańska M., Drobotowski J.: The multicomponent PK(Na) fertilizer with a variable K2O/P2O5 ratio, Pat. PL 186107, 2003.
(20) Grzmil B., Kic B.: Potassium, Sodium and Calcium Polyphosphates with Controlled Solubility, J. Agric. Food Chem., 1995, 43 2463.
(21) Grzmil B.: Manufacturing of Pyro- and Tripoly-phosphate Complexes of Micronutrients in the Process of Phosphate Condensation, Ind. Eng. Chem. Res., 1997, 36, 5282.
(22) Grzmil B.: Manufacturing of Neutral Sodium-Potassium Pyro- and Tripolyphosphates as Complexing Agents of Nutrient Microelements, J. Agric. Food Chem., 1997, 45, 4877.
(23) Grzmil B.: The effect of Potassium Sulphate on the Dehydration of Orthophosphates, Ind. Eng. Chem. Res., 1998, 37, 3741.
(24) Grzmil B.: Variable solubility with low waste, Phosph. Potass., 1998, 218, 30.
(25) Grzmil B., A Low Waste Process of the Complex Manufacture of Controlled Solubility Fertilizers, Prace Naukowe PS, Szczecin, 1998.
(26) Grzmil B., Kic B., Application of Ion Exchange Technique in Utilization of Waste Material, Pol. J. Chem. Tech., 2001, 3, 6.
(27) Kotula E., Faber A., Winiarski A.: Liquid Multicomponent Fertilizers with Microelements in Foliar Fertilization, Przem. Chem., 1988, 67, 157.
(28) Nielsson F. T.: Manual of Fertilizer Processing, Marcel Dekker, Inc.: New York, 1987.
(29) Grzmil B., Kic B.: Pyro- and Tripolyphosphates and Citratesas the Complexing Agents for Micronutrients in Liquid Fertilizers, Ind. Eng. Chem. Res., 2002, 41, 139.
(30) Grzmil B., Kic B.: Stability of Pyro- and Tripoly-phosphate Complexes with Micronutrients and Liquid Fertilizers, Pol. J. Chem. Tech., 2000, 2, 5.
(31) Grzmil B., Kic B., Kałucki K.: Liquid Fertilizer Concentrate for Onto-Leaf and Onto-Soil Fertilization, Patent Application P 340609, 2000, Biuletyn Urzędu Patentowego 2001, 730, 34.
(32) Czuba R., Spiak K., Sztuder H., Świerczewska M.: Evaluation of the Usefulness of the Three Multicomponent Fertilizer Formulations in the Vase Experiments, Scientific-Research Center of Chemistry, Agricultural Chemistry and Environmental Protection, Wrocław, 1999 (unpublished report).
(33) Let us put knowledge into practice, Fertilizer International, 2003, 392, 20.
(34) Potash alternatives, Phosph. Potass., 1999, 219, 26.
(35) Making chloride-free potash fertilizers, Phosph. Potass., 1988, 156, 27.
(36) Grzmil B., Kałucki K., Zienkiewicz M.: The procedure of obtaining potassium sulfate from the post-chromic sodium sulfate, Patent Application P. 344114, 2000, Biuletyn Urzędu Patentowego, 2002, 742, 26.
(37) Grzmil B., Kic B., Kałucki K., Czerniawska Cz.: The procedure of obtaining potassium sulfate, Patent Application P 357456, 2002 , Biuletyn Urzędu Patentowego, 2004, 794, 24.
(38) Grzmil B., Kic B., Zienkiewicz M.: Utilization of Waste Sodium Sulphate to Produce Potassium Sulphate, Pol. J. Chem. Tech., 2004, 6, 17.
(39) Grzmil B., Kic B., Zienkiewicz M.: The processes of obtaining potassium sulfate. Inżynieria i Aparatura Chemiczna, 2004, 25, 49.
(40) Phosphate removal and recovery from wastewaters, Phosp. Potass., 1998, 213, 30.
(41) Commission of the European Communites. Directive Concerning Urban Wastewater Treatment (91/271EEC), Official Journal, 1991:L135/40.
(42) Burke M.: Phosphates go full cycle, Chem. Brit., 2002, 38, 46.
(43) Battistoni P., Angelis A., Prisciandaro M., Boccadro R., Bolzonell D.: P removal from anaerobic supernatants by struvite crystallization: long term validation and process modeling, Water Res., 2002, 36, 1927.
(44) Morse G. K., Brett S. W., Guj J. A., Lester J. N.: Review: Phosphorus removal and recovery technologies, Sci. Total. Environ., 1998, 212, 69.
(45) Grzmil B., Wronkowski J.: Studies on phosphate recovery from industrial wastewater, Ann. Pol. Chem. Soc, 2003, 2, 708.
(46) Grzmil B., Wronkowski J.: Studies on magnesium-ammonium phosphate recovery from wastewater, Pol. J. Chem. Tech., 2004, 6, 13.

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Bibliografia

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