Formation of active sites in thermally treated hydrotalcite-based catalysts for acetone aldolization

• Autorzy: Kuśtrowski P. , Sułkowska D. , Chmielarz L. , Paczyńska J. , Dziembaj R.
• Języki publikacji: EN

Abstrakty

EN

Mg-AI hydrotalcite containing CO3(2-) and NO3(-) as interlayer anions was synthesized according to the coprecipitation method at constant pH (9.0) and temperature (50°C), and then transformed into mixed metal oxides by calcination at 450, 500, 550 or 600°C for 8 h. The as-prepared hydrotalcite-like sample was characterized with respect to its structure (XRD), chemical composition (XRF, elemental analysis) and thermal stability (EGA-MS). Moreover, the textural features of the thermally activated hydrotalcite were examined using low-temperature (77 K) sorption of N2. Changes in the acid-base properties of the precursor calcined at different temperatures were studied by means of temperature-programmed desorptions of NH3 and CO2. It was found that the hydrotalcite-like sample calcined at 450°C, containing a part of non-decomposed interlayer anions, showed a rather low concentration of acidic and basic surface sites. The increase in the calcination temperature caused the removal of the interlayer anions, and an increase in the concentration and strength of the acidic and basic surface centers. The formation of high number of acid/ base surface sites resulted in raising the catalytic activity of the calcined hydrotalcites in the liquid-phase aldol condensation of acetone.

Słowa kluczowe

EN

aldol condensation; acetone; diacetone alcohol; hydrotalcite-like compounds; mixed Mg-AI oxides

PL

aldol; aceton; alkohol dwuacetonowy; hydrotalkit

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2005
• Tom: Vol. 7, nr 1
• Strony: 33--37
• Opis fizyczny: Bibliogr. 14 poz., tab., rys.

Twórcy

autor

Kuśtrowski P.

• Jagiellonian University, Faculty of Chemistry, ul. Ingardena 3, 30-060 Kraków

autor

Sułkowska D.

• Jagiellonian University, Faculty of Chemistry, ul. Ingardena 3, 30-060 Kraków

autor

Chmielarz L.

• Jagiellonian University, Faculty of Chemistry, ul. Ingardena 3, 30-060 Kraków

autor

Paczyńska J.

• Jagiellonian University, Faculty of Chemistry, ul. Ingardena 3, 30-060 Kraków

autor

Dziembaj R.

• Jagiellonian University, Faculty of Chemistry, ul. Ingardena 3, 30-060 Kraków

Bibliografia

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