Production of isophorone by the vapour-phase self-condensation of acetone over the hydrotalcite-derived catalysts

• Autorzy: Kuśtrowski P. , Sułkowska D. , Chmielarz L. , Cap S.
• Języki publikacji: EN

Abstrakty

EN

The magnesium-aluminum precursor with the structure of hydrotalcite, confirmed by XRD and FTIR, was transformed into mixed metal oxides by a thermal activation at 450, 500, 550 or 600°C for 16 h. The obtained catalysts were characterized with respect to their textural properties (surface area, total porosity and pore size distribution) and used in the gas-phase aldolization of acetone. The effect of reaction temperature and calcination conditions on the catalytic performance was studied. The highest initial conversion of acetone (87.1%) with the selectivity to isophorone of 89.7% was measured for the hydrotalcite-derived Mg-Al oxides calcined at 600°C in the reaction carried out at 240°C.

Słowa kluczowe

EN

aldol condensation; acetone; mesityl oxide; isophorone; hydrotalcite-derived catalysts; continuous flow microreactor

PL

aldol; aceton; tlenek mezytylu; izoforon

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2004
• Tom: Vol. 6, nr 4
• Strony: 41--46
• Opis fizyczny: Bibliogr. 13 poz., rys.

Twórcy

autor

Kuśtrowski P.

• Jagiellonian University, Department of Chemical Technology, Faculty of Chemistry, 30-060 Kraków, ul. Ingardena 3

autor

Sułkowska D.

• Jagiellonian University, Department of Chemical Technology, Faculty of Chemistry, 30-060 Kraków, ul. Ingardena 3

autor

Chmielarz L.

• Jagiellonian University, Department of Chemical Technology, Faculty of Chemistry, 30-060 Kraków, ul. Ingardena 3

autor

Cap S.

• Jagiellonian University, Department of Chemical Technology, Faculty of Chemistry, 30-060 Kraków, ul. Ingardena 3

Bibliografia

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