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Utilization of the waste ion exchange resin for the preparation of microporous adsorbents

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The possibility of obtaining sorbents from the waste ion exchange resin by using CO2 as a gasifying agent, was investigated. The precursor of the study was Amberjet 1200H waste ion exchange resin. The activation process of the char has been carried out at the temperatures of 800, 850 and 900°C by the use of CO2 as a gasifying agent. The activation time was changed in the range of 15 - 90 min. In the activation process, spherical sorbents with a microporous structure, characterized by a high mechanical strength and a high efficiency of the model contamined water treatment, have been obtained. The studies have shown that the optimal activation conditions are the temperature of 850°C, the activation time 30 min or the temperature of 900°C, the activation time 15 or 30 min.
Rocznik
Strony
9--13
Opis fizyczny
Bibliogr. 17 poz., tab., rys.
Twórcy
autor
  • Institute of Chemistry and Technology of Petroleum and Coal, Wrocław University of Technology, ul. Gdańska 7/9, 50-344 Wrocław
autor
  • Institute of Chemistry and Technology of Petroleum and Coal, Wrocław University of Technology, ul. Gdańska 7/9, 50-344 Wrocław
  • Institute of Chemistry and Technology of Petroleum and Coal, Wrocław University of Technology, ul. Gdańska 7/9, 50-344 Wrocław
Bibliografia
  • (1) Dubois H.A., Dozol J.F., Nicotra C., Serose J., Massiani G., Pyrolysis and incineration of cationic and anionie ionexchange resins: Identification of volatile degradation compounds, Journal of Analytical and Applied Pyrolysis, 1995, 31, 129 - 140.
  • (2) Kyotani T., Control of pore structure in carbon, Carbon, 2000, 38, 269 - 86.
  • (3) Nakagawa H., Watanabe K., Harada Y., Miura K., Control of micropore formation in the carbonized ion exchange resin by utilizing pillar effect, Carbon, 1999, 37, 1455 - 1461.
  • (4) Grzegorczyk W., Skubiszewska-Zieba J., Leboda R., The recycling of ion-exchange resin for carbon sorbent. In: Abstract of the 3rd Congress of Chemical Technology, Gliwice, Poland, 2000, p. 185.
  • (5) Sentek J., Kowalczyk Z., Raróg W., Jedynak A., Ruthenium catalyst for ammonia synthesis deposited on carbon support obtained from synthetic resin, Przem.Chem. 1999, 78, 363 - 365.
  • (6) Kocirik M., Brych J., Hradil J., Carbonisation of beadshaped polymers for application in adsorption and in composite membranes, Carbon, 2001, 39, 1919.
  • (7) Bratek K., Bratek W,. Waste ion exchange resin – raw material for obtaining sorbents, Karbo, 2003, 48, 36 - 41.
  • (8) Bratek K., Bratek W., Kułażyński M , Carbon adsorbents from waste ion exchange resin, Carbon, 2002, 40, 2213 - 2220.
  • (9) Bratek W., Bratek K., Kułażyński M., Properties and structure of spherical sorbents from waste ion exchange resin, Fuel Processing Technology, 2003, 81, 87 - 102.
  • (10) Bratek W., Bratek K., Kułażyński M., The utilization of waste ion exchange resin in the environment protection, Fuel Processing Technology, 2002, 77 - 78, 431 - 436.
  • (11) Kolarz B.N., Wojaczynska M., Kaczmarczyk J., Siemieniewska T, Tomków K., Influence of heat treatment conditions on the porosity changes of sulfonated styrene/divinylbenzene copolymers, Journal of Polymer Science, 1994, 32, 1977 - 1990.
  • (12) Ragan M., Marsh H., Carbonization and liquid-crystal development. Micro-strength and optical textures of cokes from coal-pitch co-carbonization, Fuel, 1981, 60, 522 - 528.
  • (13) Gregg S.J., Sing K. S. W., Adsorption, Surface Area and Porosity, Academic Press, London 1982.
  • (14) Siemieniewska T, Tomków K, Kaczmarczyk J., Albiniak A., Grillet Y., Francois M., Application of the Dubinin-Astakhov eauation to evaluation of benzene and cyclohexane adsorption isoterms on steam gasified humic acid chars from brown coal, Energy and Fuels, 1990, 4, 61 - 70.
  • (15) Siemieniewska T, Tomków K., Kaczmarczyk J., Albiniak A., Broniek E., Jankowska A., Grillet Y., Francois M., Development of porosity in steam activated brown coal chars obtained in different conditions of pyrolysis. In: Characterization of Porous Solids III. Studies in surface science and catalysis, vol. 87, Elsevier Science Publishers Amsterdam, 1994, pp. 695 - 704.
  • (16) Dubinin M. M., Fundamentals of the theory of adsorption in micropores of carbon adsorbents: characteristics of their adsorption properties and microporous structure, Carbon, 1989, 27, 457 - 67.
  • (17) Brunauer S., Emmett P.H., Teller E., Adsorption of gases in multimolecular layers, Journal of American Chemical Society, 1938, 60, 309 - 19.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0028-0093
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