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Preparation of titanium(IV) phosphates

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This paper shows the results of investigation of titanium(IV) phosphates precipitation from acidic solution of titanyl sulfate. In investigation was used the titanyl sulfate solution obtained as the product of decomposition of ilmenite by sulfuric acid during production of titanium dioxide white pigments. The titanium(IV) phosphates were precipitated by the action of orthophosphoric acid, at different acid concentration. It has been found that precipitation of titanium phosphates occurs at phosphoric acid concentration range from 5 to 80 wt%. The prepared materials were analysed using chemical, thermogravimetric and X-ray diffractometric methods. It has been established that freshly precipitated titanium phosphates are practically amorphous. During their thermal treatment are formed crystalline products which, in dependence on used phosphoric acid concentration, are composed of titanium pyrophosphate, TiP2O7 or mixture of titanium pyrophosphate and titanium oxide biphosphate, Ti2O(PO4)2
Rocznik
Strony
91--100
Opis fizyczny
Bibliogr. 15 poz.
Twórcy
autor
autor
autor
  • Szczecin University of Technology, Institute of Chemistry and Environmental Protection, 71-065 Szczecin, Al. Piastów 42, Poland, alex@ps.pl
Bibliografia
  • [1] A. BORTUN, S. KHAINAKOV, L. BORTUN, D. POOJARY, J. RODRIGUEZ, J. GARCIA, A. CLEARFIELD, Synthesis and characterization of two novel fibrous titanium phosphates Ti20(P04)2-2H20, Chemistry of Materials, Vol. 9, 1997, pp. 1805-1811.
  • [2] G. GREVILLOT, J. DZYAZKO, K. KAZDOBIN, V. BELYAKOV, The electrochemically controlled sorption of d-metal cations by ion exchangers based on titanium phosphate, Journal of Solid State Electrochemistry, Vol. 3, 1999, pp. 111-116.
  • [3] V. LEBEDEV, N. MEL'NIK, A. RUDENKO, Sorption of cesium on titanium and zirconium phosphates, Radiochemistry, Vol. 45, No. 2, 2003, pp. 149-151.
  • [4] A. NILCHI, M. MARAGHEH, A. KHANCHI, A. FARAJZADEH, A. AGHAEI, Synthesis and ion-exchange properties of crystalline titanium and zirconium phosphates, Journal of Radioanalytical and Nuclear Chemistry, Vol. 261, No. 2, 2004, pp. 393-400.
  • [5] V. IVANEVKO, E. LOKSHIN, V. VLADIMIROVA, K. AVSARAGOV, Precipitation of titanium phosphate sorbents from products of processing sphene concentrate and properties of these sorbents, Russian Journal of Applied Chemistry, Vol. 78, No. 1, 2005, pp. 64-70.
  • [6] A. LUDMANY, S. KUREK, A. STOKŁOSA, G. WILCZYŃSKI, A. WÓJTOWICZ, J. ZAJĘCKI, Amorphous titanium hydrogenphosphate - an inorganic sorbent and a catalyst, Applied Catalysis A: General, Vol. 267, 2004, pp. 149-156.
  • [7] V. MARDANENKO, V. STRELKO, V. KANIBOLOTSKII, N. PATRILYAK, Preparation and properties of spherically granulated titanium phosphate modified with Fe(III) hexacyanoferrate(II), Russian Journal of Applied Chemistry, Vol. 77, No. 6, 2004, pp. 896-900.
  • [8] S. ROCA, C. AIROLDI, Thermodynamic data of ion exchange on amorphous titanium(IV) phosphate, Thermochimica Acta, Vol. 284, 1996, pp. 289-297.
  • [9] L. GERASIMOVA, M. MASLOVA, N. ZHDANOVA, R. OKHRIMENKO, Composition of solid phases isolated from sulfuric acid solutions of titanium(IV) by the action of phosphoric acid, Russian Journal of Applied Chemistry, Vol. 74, No. 11, 2001, pp. 1786-1788.
  • [10] N. IMANAKA, T. MASUI, H. HlRAI, Stabilization of amorphous titanium pyrophosphate by niobium or tantalum doping, Journal of Material Science, Vol. 40, 2005, pp. 3309-3311.
  • [11] T. MASUI, H. HIRAI, N. IMANAKA, New sunscreen materials based on amorphous cerium and titanium phosphate, Journal of Alloys and Compounds, Vol. 408--412, 2006, pp. 1141-1144.
  • [12] A. BORTUN, E. JAIMEZ, R. LLAVONA, J. GARCIA, J. RODRIGUEZ, Formation of crystalline titanium(IV) phosphates from titanium(III) solutions, Materials Research Bulletin, Vol. 30, No. 4,1995, pp. 413 -420.
  • [13] L. GERASIMOVA, M. MASLOVA, Precipitation of titanium(IV) and iron(III) phosphates from sulfuric acid solutions, Russian Journal of Applied Chemistry, Vol. 76, No. 11, 2003, pp. 1855-1857.
  • [14] K. OTHMER, Encyklopedia of chemical technology, Vol. 23, A Wiley Interscience Publication, John Wiley & Sons, New York, 1983, pp. 167.
  • [15] A. PRZEPIERA, Równowaga rozpuszczalności soli w roztworach elektrolitów. Układy typu MeSO4 H2SO4 - H20, Prace Naukowe Politechniki Szczecińskiej nr 551, Szczecin 1999, pp. 260, 263.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPP1-0093-0105
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