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Abstrakty
The thermal decomposition of tin(II), lead(II), cadmium(II) and mercury(II) metal-alginate complexes has been studied using thermogravimetry (TG) and differential thermogravimetry (DTG) measurements. The TG curves showed three stages of weight loss, the DTG curves indicated the presence of a series of thermal stages associated with the TG curves. Dehydration of the coordinated water molecules occurred in the first stage, followed by decomposition of the dehydrated complexes in the next two stages. Thermal stability of these complexes in terms of the strength of chelation and coordination geometry is discussed.
Rocznik
Tom
Strony
105--113
Opis fizyczny
Bibliogr. 25 poz.
Twórcy
autor
- Department of Chemistry, Faculty of Sciences, Assiut University, Assiut, 71516 Egypt
autor
- Department of Chemistry, Faculty of Applied Sciences, Umm Al-Qura University, Makkah Al-Mukarramah 5576, Kingdom of Saudi Arabia
autor
- Department of Chemistry, Faculty of Applied Sciences, Umm Al-Qura University, Makkah Al-Mukarramah 5576, Kingdom of Saudi Arabia
Bibliografia
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- [10] R. M. Hassan, Polym. Int., 31 (1993) 81.
- [11] M. A. Ahmed, F. A. Radwan, A. M. El-Refae, S. M. Abdel Wahab, R. M. Hassan, Ind. J. Phys., 71A (1997) 395.
- [12] S. M. Abdel Wahab, M. A. Ahmed, F. A. Radwan, R. M. Hassan, A. M. El-Refae, Mater. Lett., 20 (1997) 183.
- [13] A. Haug, O. Smidsrod, Acta Chem. Scand., 19 (1965) 341.
- [14] L. J. Bellamy, The Infrared Spectra of Complex Molecules, 2nd ed. 1966.
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- [19] R. T. Sanderson, Chemical Bonds and Bond Energy, 2nd ed., Academic Press, New York 1976.
- [20] K. S. Khairou, Therm. Anal. Calorim., in press.
- [21] K. S. Khairou, W. El-Gethami, R. M. Hassan, Bull. Pol. Ac.: Chem., 50 (2002).
- [22] F. A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, 3rd. ed., Wiley, New York 1972.
- [23] A. Haugh, Acta Chem. Scand., 13 (1959) 601, 1250.
- [24] R. M. Hassan, Coll. Surf., 60 (1991) 203.
- [25] R. M. Hassan, A. Awad, A. Hassan, J. Polym. Sci., 29 (1991) 1645.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPP1-0036-0068