Kinetics and mechanism of oxidation of some unsaturated organic substrates by quinolinium chlorochromate

Mishra, K.; Singh, J. V.; Pandey, A.

Artykuł - szczegóły

Tytuł artykułu

Kinetics and mechanism of oxidation of some unsaturated organic substrates by quinolinium chlorochromate

Autorzy

Mishra K. , Singh J. V. , Pandey A.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

The oxidation of unsaturated organic compounds, viz. crotyl alcohol, allyl alcohol, crotonaldehyde and maleic acid by quinolinium chlorochromate (QCC) in acetic acid-water medium (50% v/v) leads to the formation of corresponding epoxide. The reaction is of first order each in QCC and the reductant. The reaction is catalysed by hydrogen ions. The increase in dielectric constant of the medium decreases the rate, while variation I in ionic strength has no perceptible change in rate. The reaction rates have been determined at different temperatures and the activation parameters have been evaluated. The mechanism consistent with the observed results has been discussed.

Słowa kluczowe

oxidation quinolinium chlorochromate unsaturated organic substrate epoxide

utlenianie QCC substrat organiczny nienasycony epoksydy

Wydawca

Centrum Upowszechniania Nauki PAN

Czasopismo

Bulletin of the Polish Academy of Sciences. Chemistry

Rocznik

2003

Tom

Vol. 51, No. 1

Strony

25--33

Opis fizyczny

Bibliogr. 24 poz.

Twórcy

autor

Mishra K.

Department of Chemistry, Dr. H.S. Gour Vishwavidyalaya, Sagar, (M.P.) 470 003 India

autor

Singh J. V.

Department of Chemistry, Dr. H.S. Gour Vishwavidyalaya, Sagar, (M.P.) 470 003 India

autor

Pandey A.

Department of Chemistry, Dr. H.S. Gour Vishwavidyalaya, Sagar, (M.P.) 470 003 India

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BPP1-0036-0060