Introducing heterometal centers into a [XW₉O₃₃]^9- - type building block: a first step for related derivatives

• Autorzy: Botar B. , Bögge H. , Müller A.
• Języki publikacji: EN

Abstrakty

EN

For the first time it was possible to introduce heterometals (V(IV)) into the important [XW(9)O(33)](9-)(III) and Bi(III) building block thereby offering new pathways for related chemistry. By reaction of a VOSO(4)-5H(2)O solution in high excess with [(SbW(9)O(33))(2)(WO(2))4(OH(2)](12)- (molar ratio of 12:1) in acetic buffer solution, a compound containing the basic-typeanionslike[(SbW(8)VO(33)(2)(VO(2)(H(2)O)(4)(WO2)(2)](14-) which in principle could be protonated with different degrees, can be obtained. This opens new perspectives for magnetochemistry and reactivity studies of these types of compounds.

Słowa kluczowe

EN

introduce heterometals

• Wydawca: Centrum Upowszechniania Nauki PAN
• Czasopismo: Bulletin of the Polish Academy of Sciences. Chemistry
• Rocznik: 2002
• Tom: Vol. 50, No. 2
• Strony: 139--144
• Opis fizyczny: Bibliogr. 13 poz.

Twórcy

autor

Botar B.

autor

Bögge H.

autor

Müller A.

• Faculty of Chemistry of the University, D-33501 Bielefeld, Germany