Epoxidation of allyl alcohol with hydrogen peroxide on TS-1 catalyst in acetone solution

Wróblewska, A.; Milchert, E.

Artykuł - szczegóły

Tytuł artykułu

Epoxidation of allyl alcohol with hydrogen peroxide on TS-1 catalyst in acetone solution

Autorzy

Wróblewska A. , Milchert E.

Identyfikatory

Warianty tytułu

Epoksydowanie alkoholu allilowego przy użyciu nadtlenku wodoru na katalizatorze TS-1 w acetonie

Języki publikacji

Abstrakty

The epoxidation of allyl alcohol with a 30 wt% hydrogen peroxide at various concentrations of acetone as the aprotic solvent within the range of 0-80 wt% over the TS-l has been performed. Glycidol was the major product at the high concentration of acetone. Glycerol was the major product in the region of lower concentrations of acetone. On the basis of the studies published on the epoxidation of allyl alcohol in the protic solvents the course of reaction in an aprotic environment (acetone) has been proposed. The etherification of allyl alcohol has been found to proceed relatively easily in acetone solution. The molecules of water and hydrogen peroxide are involved in the formation of the active forms of the catalyst. These forms participate in the epoxidation of allyl alcohol to glycidol. The presence of other active form of the catalyst with the contribution of the allyl alcohol molecules results in the formation of diallyl ether.

Słowa kluczowe

epoxidation allyl alcohol glycidol diallyl ether

epoksydacja alkohol allilowy glicydol eter diallilowy

Wydawca

Centrum Materiałów Polimerowych i Węglowych PAN

Czasopismo

Polish Journal of Applied Chemistry

Rocznik

2001

Tom

Vol. 45, nr 1-2

Strony

1--11

Opis fizyczny

Bibliogr. 33 poz., Tabl. 2, Rys.

Twórcy

autor

Wróblewska A.

awroblewska@mailbox.tuniv.szczecin.pl

Technical University of Szczecin, Department of Organic Technology, Pułaskiego 10, PL 70-322 Szczecin, Poland

autor

Milchert E.

Technical University of Szczecin, Department of Organic Technology, Pułaskiego 10, PL 70-322 Szczecin, Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

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