Porphyrin in the solvation shell. The volumetric properties of some derivatives of tetraphenylporphyrins in benzene solutions

• Autorzy: Zielenkiewicz W. , Perlovich G. L.
• Języki publikacji: EN

Abstrakty

EN

Volumetric properties of the porphyrin molecules in solution are approached in terms of the model of interactions of the solute with the solvent molecules which assumes the density of the solvation shell to be related to the structure and nature of the atoms in the solute molecule. Special attention is paid to analysis of the distribution functions of the conformational states of the molecules investigated in the solution, the topological structure of porphyrins, atropisomerism, and also the nature of atoms and functional groups occurring in the solute molecule. This approach is used to describe the volumetric properties of the benzene solutions of some derivatives of tetraphenylporphyrins.

Słowa kluczowe

EN

volumetric properties; tetraphenylporphyrins; benzene; solution

PL

objętość; porfiryny; benzen; roztwór

• Wydawca: Centrum Upowszechniania Nauki PAN
• Czasopismo: Bulletin of the Polish Academy of Sciences. Chemistry
• Rocznik: 2001
• Tom: Vol. 49, No. 4
• Strony: 305--312
• Opis fizyczny: bibliogr. 24 poz.

Twórcy

autor

Zielenkiewicz W.

autor

Perlovich G. L.

• Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/45, 01-224 Warsaw, Poland (Instytut Chemii Fizycznej PAN)