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The behavior of the chemical affinity at the stage of intermediate product formation was analyzed in a three different schemes of a composite reaction involving one intermediate. It was derived expressions defining the validity of the assumption that the rate formation and the rate of decay of the intermediate are equal. These relations become a quantity criterion of the well - known Bodenstein approximation. The method by which the criterion had been derived was given and examples of application were provided. The approach has a general character and can be used with reference to any composite reaction.
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1--6
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Bibliogr. 1 poz.
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autor
- Institute of Inorganic Technology, Department of Chemistry, Wrocław University of Technology, Poland, 50-370 Wrocław, ul. Wybrzeże Wyspiańskiego 27
autor
- Institute of Inorganic Technology, Department of Chemistry, Wrocław University of Technology, Poland, 50-370 Wrocław, ul. Wybrzeże Wyspiańskiego 27
autor
- Institute of Inorganic Technology, Department of Chemistry, Wrocław University of Technology, Poland, 50-370 Wrocław, ul. Wybrzeże Wyspiańskiego 27
Bibliografia
- [1] J. GŁOWIŃSKI, W.TYLUS and T. BACZYŃSKA, Reaction Rates and Affinities in Consecutive Reaction, International Conference “Progress in Computing of Physicochemical Properties”, 18-20.11.1999. Warszawa
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Bibliografia
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bwmeta1.element.baztech-article-BPP1-0021-0084