The oxidation technology of hydroxycholanic acids to the corresponding oxo- derivatives

• Autorzy: Piątkowski W. , Mazurkiewicz W.
• Języki publikacji: EN

Abstrakty

EN

Technological investigations of the oxidation of hydroxycholanic acids to the corresponding oxoderivatives are described. The reactions were conducted in various ways: by complete oxidation of all hydroxyl groups in hydroxycholanic acid or by applying methods for selective oxidation. Three various reactions: cholic acid to dehydrocholic acid, chenodeoxycholic acid to ursodeoxycholic acid and cholic acid to chenodeoxycholic acid are presented. In all the oxidation processes precisely determined amounts of aqueous sodium hypochlorite were used. Experiments were carried out from laboratory to semi-technical scale. Optimal conditions of oxidation were worked out.

Słowa kluczowe

EN

hydroxycholanic acid; oxidation; oxo-derivatives

PL

kwas cholowy; utlenianie

• Wydawca: Centrum Materiałów Polimerowych i Węglowych PAN
• Czasopismo: Polish Journal of Applied Chemistry
• Rocznik: 1999
• Tom: Vol. 43, nr 1-2
• Strony: 85--93
• Opis fizyczny: Bibliogr. 27 poz.

Twórcy

autor

Piątkowski W.

• Department of Chemical Engineering and Process Control, Chemistry Faculty, Rzeszów University of Technology

autor

Mazurkiewicz W.

• Department of Organic Chemistry, Chemistry Faculty, Rzeszów University of Technology

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