Tytuł artykułu
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Abstrakty
Solid Oxalic and Maleic acid pellets are exposed to an inductively coupled oxygen plasma to investigate the oxidizing properties of the plasma on organic powders in view of ageing studies. Both acids degrade to carbon dioxide according to pseudo 1 st order reactions with kinetic constants k= 0.250 min- 1 and k=0.098 min-I respectively, relevant to the experimental conditions. Models involving the oxygen atoms present in the plasma phase are proposed [or the degradation mechanism.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
23--28
Opis fizyczny
Bibliogr. 11 poz.
Twórcy
autor
- Laboratoire d'Electrochimie (L.E.I.C.A.); UFR des Sciences; Universite de Rouen; F-76821 Mont-Saint-Aignan Cedex, France
autor
- Laboratoire d'Electrochimie (L.E.I.C.A.); UFR des Sciences; Universite de Rouen; F-76821 Mont-Saint-Aignan Cedex, France
Bibliografia
- [1] M.C. GONZALES, A.M. BRAUN, Res. Chem. Intermed., 21, 837-859 (1995)
- [2] F. CACACE, Acc. chem. Res. 21, 215-222 (1988)
- [3] R. WAYNE, Principles and Applications of Photochemistry, Oxford University Press, Oxford, (1988).
- [4] M.T. BOWERS, Gas Phase Chemistry, J. Wiley, London (1985).
- [5] T.J. MASON, P.J. LORIMER, Sonochemistry: Theory, Applications and Uses of Ultrasound in Chemistry, J. Wiley, New York (1988).
- [6] F.K. McTAGGART, Plasma Chemistry in Electrical Discharges, Elsevier, Amsterdam (1967)
- [7] B. PENETRANTE, S.E. SCHULTHEIS Eds., Non-Thermal Plasma Techniques for Pollution Control, NATO ASI series; Series G, Vol. 34; Springer-Verlag, Berlin (1992).
- [8] S. GOPALAN, P.E. SAVAGE, J. Phys. Chem., 98, 12646-12652 (1994).
- [9] N. BELLKHAL, K. DRAOU, B. CHÉRON, J.-L. BRISSET, Mat. Sci. Engin. B, 41, 206-216 (1996).
- [10] ZAHER KHAN, ATHAR A. HASHMIL, LATEEF AHMED, M.M. HAQ, Int. J. Chem. Kin., 30, 335-340 (1998).
- [11] J .Y. YAN, P.S. FEDKIW, C.G. LAW, J. Appl. Electrochem. 26, 175-185 (1996).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPP1-0013-0074