Multinuclear spin relaxation study on mercury(II) cyanide

• Autorzy: Molchanov S. , Gryff-Keller A.
• Języki publikacji: EN

Abstrakty

EN

Following coupling constants for Hg(CN)2 in DMSO solution have been measured: 1J(13C-199Hg), 1 J(13C-15N), 2 J (199Hg-15N). The longitudinal (13)C and (15)N relaxation times and transverse (13(C relaxation times at two magnetic fields, and additionally the longitudinal (199)Hg relaxation time for 13C or 15(N) enriched samples have also been measured. Quantitative interpretation of those data has delivered the values of the reori-entation rate of the solute molecule and the shielding anisotropy parameters of carbon and nitrogen nuclei. Some earlier literature results concerning water solution of the inves-tigated molecule have also been commented.

Słowa kluczowe

EN

mercury cyanide; NMR; spin relaxation

• Wydawca: Centrum Upowszechniania Nauki PAN
• Czasopismo: Bulletin of the Polish Academy of Sciences. Chemistry
• Rocznik: 1999
• Tom: Vol. 47, No. 1
• Strony: 83--88
• Opis fizyczny: Bibliogr. 19 poz.

Twórcy

autor

Molchanov S.

autor

Gryff-Keller A.

• Faculty of Chemistry, Technical University, Noakowskiego 3, 00-664 Warsaw (Zakład Chemii Organicznej, Politechnika Warszawska)