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Abstrakty
The behaviour of polyvinyl protective coating on steel under conditions of immersin in 3% NaCl and exposure in a salt fog chamber has been investigated by impedance spectroscopy. The parameters of the proposed equivalent circuit, based on a physical model for the corrosion of steel protected by coatings were calculated from data of the impedance spectra by means of the nonlinear least squares fitting. Analysis of the change of parameters with exposure time was used in the assessment of the degree of coating degradation. Conclusions were in good agreement with the visual examination after long-time exposure.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
71--78
Opis fizyczny
Bibliogr. 24 poz.,rys.
Twórcy
autor
- Technical University of Gdańsk, Faculty of Chemistry, Narutowicza Str. 11/12, 80-952 Gdańsk, Poland
autor
- Technical University of Gdańsk, Faculty of Chemistry, Narutowicza Str. 11/12, 80-952 Gdańsk, Poland
Bibliografia
- [1] J.R. MACDONALD, Impedance Spectroscopy. Emphasizing Solid Materials and Systems, John Wiley & Sons, New York 1987.
- [2] C. GABRIELLI, Impedance Spectroscopy. Principles, Instrumentation and Application, in Physical Electrochemistry, ed. l, Rubinstein, Marcel Dekker, New York, Basel, Hong, Kong, 209.
- [3] D.D. MACDONALD, in Techniques for Characterization pf Electrodes and Electrochemical Processes, ed. R. Varma, J.R. Selman, John Wiley & Sons, New York 1991, Chapt. 11, 515.
- [4] F. MANSFELD, W.J. LORENZ, in Techniques for Characterization of Electrodes and Electrochemical Processes, ed. R. Varma, J.R. Selman, John Wiley &. Sons, New York 1991, Chapt. 12, 581.
- [5] W. BOGUSZ, F. KROK, Elektrolity stałe. Właściwości elektryczne i sposoby ich pomiaru, WNT, Warszawa 1995 (in Polish).
- [6] J.R. SCULLY, Corrosion Testing and Evaluation: Silver Anniversary Volume, ASTM STP 1000, R. Barboian and S.W. Dean, Eds., ASTM, Philadelphia 1990, 351.
- [7] F. MANSFELD, M. KENDIG, S. TSAI, Corrosion, 38, 478 (1982).
- [8] M.W. KENDIG, J.R. SCULLY, Corrosion, 46, 22 (1990),
- [9] F.M. GEENEN, J.H.W. DE Wrr, Prog- Org. Coatings, 18, 299 (1990).
- [10] J.H.W. DE Wrr, 12th International Corrosion Congress, September 19-24, 1993, Houston, Texas USA, Vol. 1,420.
- [11] J- MANSFELD, J. Appl. Elektrochem., 25, 187 (1995).
- [12] A. MISZCZYK, K. DAROWICKI, Z. KLENOWICZ, Corrosion, 53, 572 (1997).
- [13] A. MISZCZYK, K. DAROWICKI, Corrr. Sci., 40, 663, 1998.
- [14] W.S. TAIT, J. Coatings Technol., 61, 57 (1989).
- [15] F.S. BOVARD, T.D. BURLEIGH, AT. SMITH, Electrochim. Acta, 40, 201 (1995).
- [16] S. HARUYAMA, M. ASARI, T. TSURU, ECS Procs Corrosion Protection by Organic Coatings, ed. M.W. Kendig, H. Leidheiser, Vol. 87-2, The Electrochemical Society, Pennington, NJ, 1987, 197.
- [17] J.R. SCULLY, J. Electrochem. Soc., 136, 979 (1989).
- [18] R. HIRAYAMA, S. HARUYAMA, Corrosion, 47, 952 (1991).
- [19] F. MANSFELD, Electrochim. Acta, 38, 891 (1993).
- [20] G. CHIODELLI, P. LUPOTTO, J. Electrochem. Soc., 138, 2703 (1991).
- [21] B.A. BOUKAMP, Manual AC-immittance Data Analysis System Equivalent Circuit, Twente University of Technology, Enschede, The Netherlands, 1989.
- [22] E.P.M. VAN WESTING, G.M. FERRARI, J.H.W. DE Wrr, Electrochem. Acta, 39, 899 (1994).
- [23] I. COSTA, S.E. FAIDI J.D. SCANTLEBURY, 12th International Corrosion Congress, September 19-24,1993, Houston, Texas USA, Vol. l, 437.
- [24] S.A. LINDQUIST, Corrosion, 41, 69 (1985).
Typ dokumentu
Bibliografia
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