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Tytuł artykułu
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Abstrakty
The kinetics of hexachloroiridate (IV) oxidation of N-(2-acetamido) imino diacetic acid in aqueous perchloric acid solution at a constant ionic strength of 0:1 mol dm(-3) have been investigated spectrophotometrically. The reaction was found to be firstorder in [IrCl(6)2-, second-order in (ADA) and inverse fractional order with respect to (H+). Kinetic evidence for the formation of intermediate complexes between the substrate and iridium (IV) is presented. The activation parameters have been calculated and a tentative reaction mechanism consistent with the kinetics is discussed.
Słowa kluczowe
Rocznik
Tom
Strony
147--156
Opis fizyczny
Bibliogr. 25 poz.
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autor
autor
- Department of Chemistry, Faculty of Applied Science, UMM AL-Qura University, Makkah El Mukarramah 715, Saudi Arabia
Bibliografia
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPP1-0002-0071