Mechanizmy i skuteczność i ozonowania katalitycznego w oczyszczaniu wody

Nawrocki, J.; Fijołek, L.

Artykuł - szczegóły

Tytuł artykułu

Mechanizmy i skuteczność i ozonowania katalitycznego w oczyszczaniu wody

Autorzy

Nawrocki J. , Fijołek L.

Treść / Zawartość

Pełne teksty:

Pobierz

Identyfikatory

Warianty tytułu

Mechanisms and efficiency of catalytic ozonation in water treatment

Języki publikacji

Abstrakty

W pracy omówiono stan współczesnej wiedzy w dziedzinie ozonowania katalitycznego i jego wykorzystania w procesach oczyszczania wody. Ozonowanie katalityczne zalicza się do procesów tzw. zaawansowanego (pogłębionego) utleniania, a jego skuteczność wiąże się zwykle z tworzeniem rodników hydroksylowych. Podkreślono główne zalety ozonowania katalitycznego, takie jak szybkość procesu, znacznie silniejsza mineralizacja substancji organicznych oraz znacznie większa skuteczność wykorzystania ozonu niż w procesach samego ozonowania. Przedyskutowano zarówno zjawiska katalizy homogenicznej, jak i heterogenicznej. Wykazano, że w homogenicznym ozonowaniu katalitycznym dochodzi do tworzenia rodników hydroksylowych głównie w wyniku następczych reakcji ozonu z kompleksami organicznymi jonów metali. Heterogeniczne ozonowanie katalityczne omówiono według grup katalizatorów, jak tlenki metali, materiały ceramiczne, metale na nośnikach oraz węgiel aktywny. Omówiono systemy niepolarne stabilizujące ozon cząsteczkowy, jak również możliwość wykorzystania tych systemów jako czynników wspomagających proces ozonowania. Wykazano, że w literaturze spotyka się wiele sprzecznych lub kontrowersyjnych doniesień, szczególnie na temat mechanizmów tworzenia rodników hydroksylowych.

The paper gives a critical account of state-of-the-art methods and mechanisms dealt with in catalytic ozonation and analyzes their applicability to water treatment. Catalytic ozonation is classified as an advanced oxidation process and its efficiency generally depends on the generation of hydroxyl radicals. The main advantages of catalytic ozonation over processes involving ozonation alone are emphasized (the high rate of the process, the substantially higher efficiency of organic matter mineralization, and the notably higher extent of ozone utilization). An analysis is performed of the phenomena occurring both in homogeneous and heterogeneous catalysis. It has been demonstrated that during homogeneous catalytic ozonation hydroxyl radicals are formed predominantly in the consecutive reactions of ozone with organic-metal ion complexes. Heterogeneous catalytic ozonation is analyzed according to the types of the catalysts being used (metal oxides, ceramic materials, supported metals, and active carbon). Consideration is also given to some nonpolar systems stabilizing molecular ozone, as well as to their potential use in support of the ozonation process. A review of publications dealing with the catalytic ozonation issue makes it clear that many of the results and conclusions reported in the literature are inconsistent, contradictory and controversial, specifically those relating to the mechanisms governing the formation of hydroxyl radicals.

Słowa kluczowe

oczyszczanie wody heterogeniczne ozonowanie katalityczne homogeniczne ozonowanie katalityczne rodnik hydroksylowy

water treatment organic matter mineralization heterogeneous catalytic ozonation homogeneous catalytic ozonation hydroxyl radical

Wydawca

Polskie Zrzeszenie Inżynierów i Techników Sanitarnych, Oddział Dolnośląski

Czasopismo

Ochrona Środowiska

Rocznik

2009

Tom

Vol. 31, nr 3

Strony

3--16

Opis fizyczny

Bibliogr. 161 poz.

Twórcy

autor

Nawrocki J.

autor

Fijołek L.

Uniwersytet im. A. Mickiewicza, Wydział Chemii, Zakład Technologii Uzdatniania Wody, ul. M. Drzymały 24, 60-613 Poznań, jaceknaw@amu.edu.pl

Bibliografia

1. B. DHANDAPANI, S.T. OYAMA: Review. Gas phase ozone decomposition catalysts. Applied Catalysis B: Environmental 1997, Vol. 11, No. 2, pp. 129–166.
2. S.T. OYAMA: Chemical and Catalytic Properties of Ozone. Catalysis Reviews: Science and Engineering 2000, Vol. 42, No. 3, pp. 279–322.
3. A.L. KOWAL, M. ŚWIDERSKA-BRÓŻ: Oczyszczanie wody. Podstawy teoretyczne i technologiczne, procesy i urządzenia. Wydawnictwo Naukowe PWN, Warszawa 2007.
4. B. LANGLAIS, D.A. RECKHOW, D.R. BRINK: Ozone in Water Treatment: Application and Engineering. Lewis Publishers, Chelsea, Michigan, USA, 1991.
5. Water Treatment Handbook. Degremont, Rueil-Malmaison Cedex 2007.
6. R.D. LETTERMAN [Ed.]: Water Quality and Treatment. A Handbook of Community Water Supplies. AWWA Fifth Edition, McGraw-Hill Inc., 1999.
7. J. NAWROCKI, S. BIŁOZOR [red.]: Uzdatnianie wody. Procesy chemiczne i biologiczne. Wydawnictwo Naukowe PWN, Warszawa–Poznań 2000.
8. F.J. BELTRÁN: Ozone Reaction Kinetics for Water and Wastewater Systems. Lewis Publishers, Boca Raton 2004.
9. B. LEGUBE, N. KARPEL VEL LEITNER: Catalytic ozonation: a promising advanced oxidation technology for water treatment. Catalysis Today 1999, Vol. 53, No. 1, pp. 61–72.
10. K. PIRKANNIEMI, M. SILLANPÄÄ: Heterogeneous water phase catalysis as an environmental application: a review. Chemosphere 2002, Vol. 48, No. 10, pp. 1047–1060.
11. B. KASPRZYK-HORDERN, M. ZIÓŁEK, J. NAWROCKI: Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment – a review. Applied Catalysis B: Enviromental 2003, Vol. 46, No. 4, pp. 639–669.
12. K. GROMADZKA, J. NAWROCKI: Degradation of diclofenac and clofibric acid using ozone-loaded perfluorinated solvent. Ozone Science and Engineering 2006, Vol. 28, No. 2, pp. 85–94.
13. R. GRACIA, J.L. ARAGÜES, J.L. OVELLEIRO: Study of the catalytic ozonation of humic substances in water and its ozonation by-products. Ozone Science and Engineering 1996, Vol. 18, No. 3, pp. 195–208.
14. E. PIERA, J.C. CALPE, E. BRILLAS, X. DOMÈNECH, J. PERAL: 2,4-dichlorophenoxyacetic acid degradation by catalyzed ozonation: TiO2/UVA/O3 and Fe(II)/UVA/O3 systems. Applied Catalysis B: Enviromental 2000, Vol. 27, No. 3, pp. 169–177.
15. R. SAULEDA, E. BRILLAS: Mineralization of aniline and 4-chlorophenol in acidic solution by ozonation catalyzed with Fe2+ and UVA light. Applied Catalysis B: Enviromental 2001, Vol. 29, No. 2, pp. 135–145.
16. D.S. PINES, D.A. RECKHOW: Effect of dissolved cobalt(II)on the ozonation of oxalic acid. Environmental Science and Technology 2002, Vol. 36, No. 19, pp. 4046–4051.
17. F.J. BELTRÁN, F.J. RIVAS, R. MONTERO-DE-ESPINOSA: Ozone enhanced oxidation of oxalic acid in water with cobalt catalysts. 1. Homogeneous catalytic ozonation. Industrial & Engineering Chemistry Research 2003, Vol. 42, No. 14, pp. 3210–3217.
18. F.J. BELTRÁN, F.J. RIVAS, R. MONTERO-DE-ESPINOSA: Iron type catalysts for the ozonation of oxalic acid in water. Water Research 2005, Vol. 39, No. 15, pp. 3553–3564.
19. S. CORTÉS, J. SARASA, P. ORMAD, R. GRACIA, J.L. OVELLEIRO: Comparative efficiency of the systems O3/high pH and O3/catalyst for the oxidation of chlorobenzenes in water. Ozone: Science and Engineering 2000, Vol. 22, No. 4, pp. 415–426.
20. T. LØGAGER, J. HOLEMAN, K. SEHESTED, T. PEDERSEN: Oxidation of ferrous ions by ozone in acidic solutions. Inorganic Chemistry 1992, Vol. 31, No. 17, pp. 3523–3529.
21. R. GRACIA, J.L. ARAGÜES, S. CORTÈS, J.L. OVELLEIRO: Conf. proc. “12th World Congress of the International Ozone Association”, Lille, France, 15-18 May 1995, p. 75.
22. R. ANDREOZZI, V. CAPRIO, A. INSOLA, R. MAROTTA, V. TUFANO: The ozonation of pyruvic acid in aqueous solutions catalysed by suspended and dissolved manganese. Water Research 1998, Vol. 32, No. 5, pp. 1492–1496.
23. R. ANDREOZZI, A. INSOLA, V. CAPRIO, R. MAROTTA, V. TUFANO: The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution. Applied Catalysis A: General 1996, Vol. 138, No. 1, pp. 75–81.
24. Y. PI, M. ERNST, J-CH. SCHROTTER: Effect of phosphate buffer upon CuO/Al2O3 and Cu(II) catalyzed ozonation of oxalic acid solution. Ozone Science and Engineering 2003, Vol. 25, No. 5, pp. 393–397.
25. A.A. ABD EL-RAADY, T. NAKAJIMA: Decomposition of Carboxylic Acids in Water by O3, O3/H2O2, and O3/Catalyst. Ozone: Science and Engineering 2005, Vol. 27, No. 1, pp. 11–18.
26. J. MA, N.J.D. GRAHAM: Degradation of atrazine by manganese-catalysed ozonation – influence of radical scavengers. Water Research 2000, Vol. 34, No. 15, pp. 3822–3828.
27. J. MA, N.J.D. GRAHAM: Degradation of Atrazine by Manganese-Catalysed Ozonation: Influence of Humic Substances. Water Research 1999, Vol. 33, No. 3, pp. 785–793.
28. H. XIAO, R. LIU, X. ZHAO, J. QU: Enhanced degradation of 2,4-dinitrotoluene by ozonation in the presence of manganese(II) and oxalic acid. Journal of Molecular Catalysis A: Chemical 2008, Vol. 286, pp. 149–155.
29. H. XIAO, R. LIU, X. ZHAO, J. QU: Effect of manganese ion on the mineralization of 2,4-dichlorophenol by ozone. Chemosphere 2008, Vol. 72, No. 7, pp. 1006–1012.
30. M. SÁNCHEZ-POLO, J. RIVERA-UTRILLA: Ozonation of 1,3,6-naphthalenetrisulfonic acid in presence of heavy metals. Journal of Chemical Technology and Biotechnology 2004, Vol. 79, No. 8, pp. 902–909.
31. M. TRAPIDO, Y. VERESSININA, R. MUNTER, J. KALLAS: Catalytic Ozonation of m-dinitrobenzene. Ozone: Science and Engineering 2005, Vol. 27, No. 5, pp. 359–363.
32. S.-P. TONG, W.-P. LIU, W.-H. LENG, Q.-Q. ZHANG: Characteristics of MnO2 catalytic ozonation of sulfosalicylic acid and propionic acid in water. Chemosphere 2003, Vol. 50, No. 10, pp. 1359–1364.
33. R. MUNTER, M. TRAPIDO, Y. VERESSININA: Oxidative decomposition of benzoic acid in the presence of metal ionic catalysts. Proceedings of Estonian Academy of Sciences Chemistry 2005, Vol. 54, No. 1, pp. 16–23.
34. M. CARBAJO, F.J. RIVAS, F.J. BELTRÁN, P. ALVARES, F. MEDINA: Effects of different catalysts on the ozonation of pyruvic acid in water. Ozone: Science and Engineering 2006, Vol. 28, No. 4, pp. 229–235.
35. F.B. BELTRÁN, F.J. RIVAS, R. MONTERO-DE-ESPINOSA: Ozone enhanced oxidation of oxalic acid in water with cobalt catalysts. 2. Heterogeneous catalytic ozonation. Industrial and Engineering Chemistry Research 2003, Vol. 42, No. 14, pp. 3218–3224.
36. D.S. PINES, D.A. RECKHOW: Solid phase catalytic ozonation process for the destruction of a model pollutant. Ozone: Science and Engineering 2003, Vol. 25, No. 1, pp. 25–39.
37. J. MA, N.J.D. GRAHAM: Preliminary investigation of manganese-catalysed ozonation for the destruction of atrazine. Ozone: Science and Engineering 1997, Vol. 19, No. 3, pp. 227–240.
38. R. ANDREOZZI, M.S. LO CASALE, R. MAROTTA, G. PINTO, A. POLLIO: N-methyl-p-aminophenol (metol) ozonation in aqueous solution: kinetics, mechanism and toxicological characterization of ozonized samples. Water Research 2000, Vol. 34, No. 18, pp. 4419–4429.
39. R. ANDREOZZI, A. INSOLA, V. CAPRIO, M.G. D’AMO-RE: The kinetics of Mn(II)-catalysed ozonation of oxalic acid in aqueous solution. Water Research 1992, Vol. 26, No. 7, pp. 917–921.
40. R. ANDREOZZI, V. CAPRIO, R. MAROTTA, V. TUFA-NO: Kinetic modeling of pyruvic acid ozonation in aqueous solutions catalysed by Mn(II) and Mn(IV) ions. Water Research 2001, Vol. 35, No. 1, pp. 109–120.
41. R. ANDREOZZI, R. MAROTTA, R. SANCHIRICO: Manganese-catalysed ozonation of glyoxalic acid in aqueous solutions. Journal of Chemical Technology and Biotechnology 2000, Vol. 75, No. 1, pp. 59–65.
42. S.-P. TONG, W.-P. LIU, W.-H. LENG, Q.-Q. ZHANG: Characteristics of MnO2 catalytic ozonation of sulfosalicylic acid and propionic acid in water. Chemosphere 2003, Vol. 50, No. 10, pp. 1359–1364.
43. F.J. RIVAS, E. RODRÍGUEZ, F.J. BELTRÁN, J.F. GARCÍA-ARAYA, P. ALVAREZ: Homogeneous catalyzed ozonation of simazine. Effect of Mn(II) and Fe(II). Journal of Environmental Science and Health B 2001, Vol. 36, No. 3, pp. 317–330.
44. C.-H. NI, J.-N. CHEN, P.-Y. YANG: Catalytic ozonation of 2-dichlorophenol by metallic ions. Water Science and Technology 2002 Vol. 47, No. 1, pp. 77–82.
45. M.M. KSENOFONTOVA, A.N. MITROFANOVA, N.A. MAM-LEEVA, A.N. PRYAKHIN, V.V. LUNIN: Ligninsulfonate ozonation in the presence of transition metal ions. Ozone: Science and Engineering 2003, Vol. 25, No. 6, pp. 505–512.
46. CH.-H. WU, CH.-Y. KUO, CH.-L. CHANG: Homogeneous catalytic ozonation of C.I. Reactive Red 2 by metallic ions in a bubble column reactor. Journal of Hazardous Materials 2008, Vol. 153, No. 3, pp. 1052–1058.
47. M. MATHESWARAN, S. BALAJI, S.J. CHUNG, I.S. MOON: Studies on cerium oxidation in catalytic ozonation process: A novel approach for organic mineralization. Catalysis Communications 2007, Vol. 10, No. 6, pp. 1497–1501.
48. T. ZHANG, C. LI, J. MA, H. TIAN, Z. QIANG: Surface hydroxyl groups of synthetic α-FeOOH in promoting •OH generation from aqueous ozone: Property and activity relationship. Applied Catalysis B: Environmental 2008, Vol. 82, No. 1–2, pp. 131–137.
49. T. ZHANG, J. LU, J. MA, Z. QIANG: Fluorescence spectroscopic characterization of DOM fractions isolated from a filtered river water after ozonation and catalytic ozonation, Chemosphere 2008, Vol. 71, No. 5, pp. 911–921.
50. Y. YANG, J. MA, Q. QIN, X. ZHAI: Degradation of nitrobenzene by nano-TiO2 catalyzed ozonation. Journal of Molecular Catalysis A: Chemical 2007, Vol. 267, pp. 41–48.
51. P.C.C. FARIA, D.C.M. MONTEIRO, J.J.M. ÓRFÃO, M.F.R. PEREIRA: Cerium, manganese and cobalt oxides as catalysts for the ozonation of selected organic compounds. Chemosphere 2009, Vol. 74, No. 6, pp. 818–824.
52. Y. DONG, H. YANG, K. HE, S. SONG, A. ZHANG: β-MnO2 nanowires: A novel ozonation catalyst for water treatment. Applied Catalysis B: Enviromental 2009, Vol. 85, No. 3–4, pp. 155–161.
53. M.A. ALSHEYAB, A.H. MUÑOZ: Comparative study of ozone and MnO2/O3 effects on the elimination of TOC and COD of raw water at the Valmayor station. Desalination 2007, Vol. 207, No. 1–3, pp. 179–183.
54. C. COOPER, R. BURCH: An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water preparation. Water Research 1999, Vol. 33, No. 18, pp. 3695–3700.
55. Z. YUNRUI, Z. WANPENG, L. FUDONG, W. JIANBING, Y. SHAOXIA: Catalytic activity of Ru/Al2O3 for ozonation of dimethyl phthalate in aqueous solution. Chemosphere 2007, Vol. 66, No. 1, pp. 145–150.
56. B. KASPRZYK, J. NAWROCKI: Preliminary results on ozonation enhancement by a perfluorinated bonded alumina phase. Ozone: Science and Engineering 2002, Vol. 24, No. 1, pp. 63–68.
57. B. KASPRZYK-HORDERN, U. RACZYK-STANISŁAWIAK, J. ŚWIETLIK, J. NAWROCKI: Catalytic ozonation of natural organic matter on alumina. Applied Catalysis B: Environmental 2006, Vol. 62, No. 3–4, pp. 345–358.
58. M. ERNST, F. LUROT, J.-CH. SCHOTTER: Catalytic ozonation of refractory organic model compounds in aqueous solution by aluminium oxide. Applied Catalysis B: Environmental 2004, Vol. 47, No. 1, pp. 15–25.
59. F.J. BELTRÁN, F.J. RIVAS, R. MONTERO-DE-ESPINOSA: A TiO2/Al2O3 catalyst to improve the ozonation of oxalic acid in water. Applied Catalysis B: Environmental 2004, Vol.47, No. 2, pp. 101–109.
60. P.M. ÁLVAREZ, F.J. BELTRÁN, J.P. POCOSTALES, F.J. MASA: Preparation and structural characterization of Co/Al2O3 catalysts for the ozonation of pyruvic acid. Applied Catalysis B: Environmental 2007, Vol. 72, No. 3–4, pp. 322–330.
61. L. CHEN, F. QI, B. XU, Z. XU, J. SHEN, K. LI: The efficiency and mechanism of γ-alumina catalytic ozonation of 2-methylisoborneol in drinking water. Water Science and Technology: Water Supply 2006, Vol. 6, No. 3, pp. 43–51.
62. F. QI, B. XU, Z. CHEN, J. MA, D. SUN, L. ZHANG: Influence of aluminum oxides surface properties on catalyzed ozonation of 2,4,6-trichloroanisole. Separation and Purification Technology 2009, Vol. 66, No. 2, pp. 405–410.
63. F. QI, Z. CHEN, B. XU, J. SHEN, J. MA, C. JOLL, A. HEITZ: Influence of surface texture and acid–base properties on ozone decomposition catalyzed by aluminum (hydroxyl) oxides. Applied Catalysis B. Environmental 2008, Vol. 84, No. 3–4, pp. 684–690.
64. J. LIN, A. KAWAI, T. NAKAJIMA: Effective catalysts for decomposition of aqueous ozone. Applied Catalysis B: Environmental 2002, Vol. 39, No. 2 , pp. 157–165.
65. M. JEKEL, R. SEITH: The removal of arsenic: comparison of conventional and new techniques for the removal of arsenic in a full-scale water treatment plant. Water Supply 2000, Vol. 18, No. 1, pp. 628–631.
66. J.-S. PARK, H. CHOI, K.-H. AHN: The reaction mechanism of catalytic oxidation with hydrogen peroxide and ozone in aqueous solution. Water Science and Technology 2003, Vol. 47, No. 1, pp. 179 184.
67. J.-S. PARK, H. CHOI, K.-H. AHN, J.-W. KANG: Removal Mechanism of Natural Organic Matter and Organic Acid by Ozone in the Presence of Goethite. Ozone: Science and Engineering 2004, Vol. 26, No. 2, pp. 141–151,
68. J.-S. PARK, H. CHOI, J. CHO: Kinetic decomposition of ozone and parachlorobenzoic acid (p-CBA) during catalytic ozonation. Water Research 2004, Vol. 38, No. 9, pp. 2285–2292.
69. T. ZHANG, J. MA: Catalytic ozonation of trace nitrobenzene in water with synthetic goethite. Journal of Molecular Catalysis A: Chemical 2008, Vol. 279, No. 1, pp. 82–89.
70. T. ZHANG, J. LU, J. MA, Z. QIANG: Comparative study of ozonation and synthetic goethite-catalyzed ozonation of individual NOM fractions isolated and fractionated from a filtered river water. Water Research 2008, Vol. 42, No. 6–7, pp. 1563–1570.
71. J.-E. LEE, B.-S. JIN, S.-H. CHO, S.-H. HAN, O.-S. JOO, K.-D. JUNG: Catalytic ozonation of humic acids with Fe/MgO. Reaction Kinetics and Catalysis Letter 2005, Vol. 85, No. 1, pp. 65–71.
72. T. ZHANG, W. CHEN, J. MA, Z. QIANG: Minimizing bromate formation with cerium dioxide during ozonation of bromide-containing waters. Water Research 2008, Vol. 42, No. 14, pp. 3651–3658.
73. P.C.C. FARIA, J.J.M. ÓRFÃO, M.F.R. PEREIRA: Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents. Applied Catalysis B: Environmental 2009 Vol. 88, No. 3–4, pp. 341–350.
74. R.C. MARTINS, R.M. QUINTA-FERREIRA: Screening of ceria-based and commercial ceramic catalysts for catalytic ozonation of simulated olive mill wastewaters. Industrial and Engineering Chemistry Research 2009, Vol. 48, No. 3, pp. 1196–1202.
75. N. KARPEL VEL LEITNER, F. DELANOË, B. ACEDO, B. LEGUBE: Reactivity of various Ru/CeO2 catalysts during ozonation of succinic acid aqueous solutions. New Journal of Chemistry 2000, Vol. 24, No. 4, pp. 229–233.
76. Z. Z. XU, Z. L. CHEN, C. JOLL, Y. BEN, J.M. SHEN, H. TAO: Catalytic efficiency and stability of cobalt hydroxide for decomposition of ozone and p-chloronitrobenzene in water. Catalysis Communications 2009, Vol. 10, No. 8, pp. 1221–1225.
77. F.J. RIVAS, F.J. BELTRÁN, E. VERA, O. GIMENO: Aqueous ozone decomposition onto a Co2O3-alumina supported catalyst. Journal of Environmental Science and Health. Part A, Toxic/Hazardous Substances and Environmental Engineering 2004, Vol. 39, No. 11/12, pp. 2915–2924.
78. F. HAN, V.S.R. KAMBALA, M. SRINIVASAN, D. RAJARATHNAM, R. NAIDU: Tailored titanium dioxide photocatalysts for the degradation of organic dyes in wastewater treatment: A review. Applied Catalysis A: General 2009, Vol. 359, No. 1–2, pp. 25–40.
79. U.I. GAYA, A.H. ABDULLAH: Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: A review of fundamentals, progress and problems. Journal of Photochemistry and Photobiology C: Photochemistry Reviews 2008, Vol. 9, No. 1, pp. 1–12.
80. D. CHATTERJEE, S. DASGUPTA: Visible light induced photocatalytic degradation of organic pollutants. Journal of Photochemistry and Photobiology C: Photochemistry Reviews 2005, Vol. 6, No. 2–3, pp. 186–205.
81. H. SUTY, C. DE TRAVERSAY, M. COST: Applications of advanced oxidation processes: Present and future. Water Science and Technology 2004, Vol. 49, No 4, pp. 227–233.
82. V.P. VINOD, T.S. ANIRUDHAN: Photocatalytic degradation for environmental applications – A review. Journal of Chemical Technology and Biotechnology 2002, Vol. 77, No. 1, pp. 102–116.
83. F.J. BELTRÁN, F.J. RIVAS, R. MONTERO-DE-ESPINOZA: Catalytic ozonation of oxalic acid in an aqueous TiO2 slurry reactor. Applied Catalysis B: Environmental 2002, Vol. 39, No. 3, pp. 221–231.
84. M. ADDAMO, V. AUGUGLIARO, E. GARCÍA-LÓPEZ, V. LODDO, G. MARCÌ, L. PALMISANO: Oxidation of oxalate ion in aqueous suspensions of TiO2 by photocatalysis and ozonation. Catalysis Today 2005, Vol. 107–108, pp. 612–618.
85. M. YE, Z. CHEN, X. LIU, Y. BEN, J. SHEN: Ozone enhanced activity of aqueous titanium dioxide suspensions for photodegradation of 4-chloronitrobenzene. Journal of Hazardous Materials 2009, Vol. 167, pp. 1021–1027.
86. R. ROSAL, A. RODRÍGEZ, M.S. GONZALO, E. GARCÍA-CALVO: Catalytic ozonation of naproxen and carbamazepine on titanium dioxide. Applied Catalysis B: Environmental 2008, Vol. 84, No. 1–2, pp. 48–57.
87. H. JUNG, H. CHOI: Catalytic decomposition of ozone and parachlorobenzoic acid (pCBA) in the presence of nanosized ZnO. Applied Catalysis B: Environmental 2006, Vol. 66, No. 3–4, pp. 288–294.
88. M. MURUGANANDHAM, J.J. WU: Synthesis, characterization and catalytic activity of easily recyclable zinc oxide nanobundles. Applied Catalysis B: Environmental 2008, Vol. 80, No. 1–2, pp. 32–41.
89. Y.-F. ZENG, Z.-L. LIU, Z.-Z. QIN: Decolorization of molasses fermentation wastewater by SnO2-catalyzed ozonation. Journal of Hazardous Materials 2009, Vol. 162, No. 2–3, pp. 682–687.
90. S.M. AVRAMESCU, C. BRADU, I. UDREA, N. MIHALACHE, F. RUTA: Degradation of oxalic acid from aqueous solutions by ozonation in presence of Ni/Al2O3 catalysts. Catalysis Communications 2008, Vol. 9, No. 14, pp. 2386–2391.
91. V.S.R. RAJASEKHAR PULLABHOTLA, C. SOUTHWAY, S.B. JONNALAGADDA: Ozone initiated oxidation of hexadecane with metal loaded γ-Al2O3 catalysts. Catalysis Letters 2008, Vol. 124, No. 1/2, pp. 118–126.
92. J. QU, H. LI, H. LIU, H. HE: Ozonation of alachlor catalyzed by Cu/Al2O3 in water. Catalysis Today 2004, Vol. 90, No. 3–4, pp. 291–296.
93. I. UDREA, C. BRADU: Ozonation of substituted phenols in aqueous solutions over CuO-Al2O3 catalyst. Ozone: Science and Engineering 2003, Vol. 25, No. 4, pp. 335–343.
94. C.H. NI, J.N. CHEN: Heterogeneous catalytic ozonation of 2-chlorophenol aqueous solution with alumina as a catalyst. Water Science and Technology 2001, Vol. 43, No. 2, pp. 213–220.
95. R. GRACIA, S. CORTÉS, J. SARASA, P. ORMAD, J.L. OVELLEIRO: Heterogeneous catalytic ozonation with supported titanium dioxide in model and natural waters. Ozone: Science and Engineering 2000, Vol. 22, No. 5, pp. 461–471.
96. R. GRACIA, S. CORTÉS, J. SARASA, P. ORMAD, J.L. OVELLEIRO: Catalytic ozonation with supported titanium dioxide. The stability of catalyst in water. Ozone: Science and Engineering 2000, Vol. 22, No. 2, pp. 185–193.
97. R. GRACIA, S. CORTES, J. SARASA, P. ORMAD, J.L. OVELLEIRO: TiO2 catalysed ozonation of raw Ebro river water. Water Research 2000, Vol. 34, No. 5, pp. 1525–1532.
98. CH. VOLK, P. ROCHE, J.C. JORET, H. PAILLARD: Comparison of the effect of ozone, ozone-hydrogen peroxide system and catalytic ozone on the biodegradable organic matter of a fulvic acid solution. Water Research 1997, Vol. 31, No. 3, pp. 650–656.
99. J. MA, M.-H. SUI, Z.-L. CHEN, L.-N. WANG: Degradation of refractory organic pollutants by catalytic ozonation - activated carbon and Mn-loaded activated carbon as catalysts. Ozone: Science and Engineering 2004, Vol. 26, No. 1, pp. 3–10.
100. J. LIN, T. NAKAJIMA, T. JOMOTO, K. HIRAIWA: Effective catalysts for wet oxidation of formic acid by oxygen and ozone. Ozone: Science and Engineering 2000, Vol. 22, No. 3, pp. 241–247.
101. H. FU, N. KARPEL VEL LEITNER, B. LEGUBE: Catalytic ozonation of chlorinated carboxylic acids with Ru/CeO2-TiO2 catalysts in aqueous system. New Journal of Chemistry 2002, Vol. 26, No. 11, pp. 1662–1666.
102. N. KARPEL VEL LEITNER, H. FU: pH effects on catalytic ozonation of carboxylic acids with metal on metal oxides catalysts. Topics in Catalysis 2005, Vol. 33, No. 1–4, pp. 249–256.
103. F. DELANOË, B. ACEDO, N. KARPEL VEL LEITNER, B. LEGUBE: Relationship between structure of Ru/CeO2 catalysts and their activity in the catalytic ozonation of succinic acid aqueous solutions. Applied Catalysis B: Environmental 2001, Vol. 29, No. 4, pp. 315–325.
104. V. FONATNIER, V. FARINES, J. ALBET, S. BAIG, J. MOLINER: Oxidation of organic pollutants of water to mineralization by catalytic ozonation. Ozone: Science and Engineering 2005, Vol. 27, No. 2, pp. 115 128.
105. N. KARPEL VEL LEITNER, B. DELOUANE, B. LEGUBE, F. LUCK: Effects of catalysts during ozonation of salicylic acid, peptides and humic substances in aqueous solution. Ozone: Science and Engineering 1999, Vol. 21, No. 3, pp. 261–276.
106. T.S. PING, L.W. HUA, Z.J. QING, C.C. NAN: Catalytic ozonation of sulfosalicylic acid. Ozone: Science and Engineering 2002, Vol. 24, pp. 117–122.
107. L. ZHAO, J. MA, Z.-Z. SUN: Oxidation products and pathway of ceramic honeycomb-catalyzed ozonation for the degradation of nitrobenzene in aqueous solution. Applied Catalysis B: Environmental 2008, Vol. 79, No. 3, pp. 244–253.
108. L. ZHAO, J. MA, Z. SUN, Z. LIU, Y. YANG: Experimental study on oxidative decomposition of nitrobenzene in aqueous solution by honeycomb ceramic-catalyzed ozonation. Frontiers of Environmental Science and Engineering in China 2008, Vol. 2, No. 1, pp. 44–50.
109. L. ZHAO, J. MA, Z.-Z. SUN, X.-D. ZHAI: Mechanism of influence of initial pH on the degradation of nitrobenzene in aqueous solution by ceramic honeycomb-catalytic ozonation. Environmental Science and Technology 2008, Vol. 42, No. 11, pp. 4002–4007.
110. L. ZHAO, J. MA, Z.-Z. SUN, X.-D. ZHAI: Preliminary kinetic study on the degradation of nitrobenzene by modified ceramic honeycomb-catalytic ozonation in aqueous solution. Journal of Hazardous Materials 2009, Vol. 161, No. 2–3, pp. 988–994.
111. Y.-J. HOU, J. MA, Z.-Z. SUN, Y.-H. YU, L. ZHAO: Degradation of benzophenone in aqueous solution by Mn-Fe-K modified ceramic honeycomb-catalyzed ozonation. Journal of Environmental Sciences (China) 2006, Vol. 18, No. 6, pp. 1065–1072.
112. L. ZHAO, Z.-Z. SUN, J. MA, H. LIU: Enhancement mechanism of heterogeneous catalytic ozonation by cordierite-supported copper for degradation of nitrobenzene in aqueous solution. Environmental Science and Technology 2009, Vol. 43, No. 6, pp. 2047–2053.
113. L. ZHAO, J. MA, Z.-Z. SUN, X.-D. ZHAI: Catalytic ozonation for the degradation of nitrobenzene in aqueous solution by ceramic honeycomb-supported manganese. Applied Catalysis B: Environmental 2008, Vol.83, No. 3–4,pp. 256–264.
114. K. AZRAGUE, S.W. OSTERHUS, J.G. BIOMORGI: Degradation of pCBA by catalytic ozonation in natural water. Water Science and Technology 2009, Vol. 59, No. 6, pp. 1209–1217.
115. J.L. SOTELO, G. OVEJERO, F. MARTINEZ, J.A. MELERO, A. MILIENI: Catalytic wet peroxide oxidation of phenolic solutions over LaTi1–xCuxO3 perovskite catalyst. Applied Catalysis B: Environmental 2004, Vol. 47, No. 4, pp. 281–294.
116. F.J. RIVAS, M. CARBAJO, F.J. BELTRÁN, B. ACEDO, O. GIMENO: Perovskite catalytic ozonation of pyruvic acid in water. Operating conditions influence and kinetics. Applied Catalysis B: Environmental 2006, Vol. 62, No. 1–2, pp. 93–103.
117. M. CARBAJO, F.J. BELTRÁN, F. MEDINA, O. GIMENO, F.J. RIVAS: Catalytic ozonation of phenolic compounds. The case of gallic acid. Applied Catalysis B: Environmental 2006, Vol. 67, No. 3–4, pp. 177–186.
118. M. CARBAJO, F.J. BELTRÁN, O. GIMENO, B. ACEDO, F.J. RIVAS: Ozonation of phenolic wastewaters in the presence of a perovskite type catalyst. Applied Catalysis B: Environmental 2007, Vol. 74, No. 3–4, pp. 203–210.
119. N. SANO, T. YAMAMOTO, D. YAMAMOTO, S.-I. KIM, A. EIAD-UA, H. SHINOMIYA, M. NAKAIWA: Degradation of aqueous phenol by simultaneous use of ozone with silica-gel and zeolite. Chemical Engineering and Processing 2007, Vol. 46, No. 6, pp. 513–519.
120. Y. DONG, H. YANG, K. HE, X. WU, A. ZHANG: Catalytic activity and stability of Y zeolite for phenol degradation in the presence of ozone. Applied Catalysis B: Environmental 2008, Vol. 82, No. 3–4, pp. 163–168.
121. B.-S. KIM, H. FUJITA, Y. SAKAI, A. SAKODA, M. SUZKI: Catalytic ozonation of an organophosphorous pesticide using microporous silicate and its effect on total toxicity reduction. Water Science and Technology 2002, Vol. 46, No. 4/5, pp. 35–41.
122. H. FUJITA, J. IZUMI, M. SAGEHASHI, T. FUJII, A. SAKODA: Adsorption and decomposition of water-dissolved ozone on high silica zeolites. Water Research 2004, Vol. 38, No. 1, pp. 159–165.
123. H. FUJITA, J. IZUMI, M. SAGEHASHI, T. FUJII, A. SAKODA: Decomposition of trichloroethene on ozone-adsorbed high silica zeolites. Water Research 2004, Vol. 38, No. 1, pp. 166–172.
124. H. FUJITA, M. SAGEHASHI, T. FUJII, A. SAKODA, J. IZUMI: Adsorbed phase ozonation of water-dissolved organic pollutants using high-silica zeolites. Adsorption 2005, Vol. 11, No. 1, pp. 835–839.
125. K. SHIRAISHI, H. FUJITA, J. IZUMI, T. FUJII, M. AKIBA, M. SAGEHASHI, A. SAKODA: Prevention of bromate formation by adsorption phase ozonation using high silica zeolites. Water Science and Technology: Water Supply 2004, Vol. 4, No. 5–6, pp. 289–296.
126. M. SAGEHASHI, K. SHIRAISHI, H. FUJITA, T. FUJII, A. SAKODA: Ozone decomposition of 2-methylisoborneol (MIB) in adsorption phase on high silica zeolites with preventing bromate formation. Water Research 2005, Vol. 39, No. 13, pp. 2926–2934.
127. M. SAGEHASHI, K. SHIRAISHI, H. FUJITA, T. FUJII, A. SAKODA: Adsorptive ozonation of 2-methylisoborneol in natural water with preventing bromate formation. Water Research 2005, Vol. 39, No. 16, pp. 3900–3908.
128. G. Mc KAY, G. Mc ALEAVEY: Ozonation and carbon adsorption in a three phase fluidized bed for color removal from peat water. Chemical Engineering Research & Design 1988, Vol. 66, No. 6, pp. 531–536.
129. C.A. ZAROR: Enhanced oxidation of toxic effluents using simultaneous ozonation and activated carbon treatment. Journal of Chemical Technology and Biotechnology 1997, Vol. 70, No. 1, pp. 21–28.
130. U. JANS, J. HOIGNÉ: Activated carbon and carbon black catalyzed transformation of aqueous ozone into OH-radicals. Ozone: Science and Engineering 1998 Vol. 20, No. 1, pp. 67–90.
131. F.J. BELTRÁN, J. RIVAS, P. ÁLVAREZ, R. MONTERO-DE-ESPINOZA: Kinetics of heterogeneous catalytic ozone decomposition in water on an activated carbon. Ozone: Science and Engineering 2002, Vol. 24, No. 4, pp. 227–237.
132. K.M. BULANIN, J.C. LAVALLEY, A.A. TSIGANENKO: Infrared study of ozone adsorption on TiO2 (Anatase). Journal of Physical Chemistry 1995, Vol. 99, No. 25, pp. 10294–10298.
133. K.M. BULANIN, J.C. LAVALLEY, J. LAMOTTE, L. MA-RIEY, N.M. TSYGANIENKO, A.A. TSIGANENKO: Infrared study of ozone adsorption on CeO2. The Journal of Physical Chemistry B 1998, Vol. 102, No. 35, pp. 6809–6816.
134. F.J. BELTRÁN, J. RIVAS, R.A. FERNÁNDEZ, P.M. ÁLVAREZ, R. MONTERO-DE-ESPINOZA: Kinetics of catalytic ozonation of oxalic acid in water with activated carbon. Industrial & Engineering Chemistry Research 2002, Vol. 41, No. 25, pp. 6510–6517.
135. P.C.C. FARIA, J.J.M. ÓRFÃO, M.F.M. PEREIRA: Activated carbon catalytic ozonation of oxamic and oxalic acids. Applied Catalysis B: Environmental 2008, Vol. 79, No. 3, pp. 237–243.
136. M. SÁNCHEZ-POLO, J. RIVERA-UTRILLA: Effect of the ozone-carbon reaction on the catalytic activity of activated carbon during the degradation of 1,3,6-naphthalenetrisulphonic acid with ozone. Carbon 2003, Vol. 41, No. 2, pp. 303–307.
137. F.J. BELTRÁN, B. ACEDO, F.J. RIVAS, O. GIMENO: Pyruvic acid removal from water by the simultaneous action of ozone and activated carbon. Ozone: Science and Engineering 2005, Vol. 27, No. 2, pp. 159–169.
138. F.J. BELTRÁN, J.H. GARCÍA-ARAYA, I. GIRÁLDEZ: Gallic acid water ozonation using activated carbon. Applied Catalysis B: Environmental 2006, Vol. 63, No. 3–4, pp. 249–259.
139. L. GU, X. ZHANG, L. LEI: Degradation of aqueous p-nitro-phenol by ozonation integrated with activated carbon. Industrial & Engineering Chemistry Research 2008, Vol. 47, No. 18, pp. 6809–6815.
140. F.J. BELTRÁN, P. POCOSTALES, P. ALVAREZ, A. ORO-PESA: Diclofenac removal from water with ozone and activated carbon. Journal of Hazardous Materials 2009, Vol. 163, No. 2–3, pp. 768–776.
141. J. MA, M. SUI, T. ZHANG, CH. GUAN: Effect of pH on MnOx/GAC catalysed ozonation for degradation of nitrobenzene. Water Research 2005, Vol. 39, No. 5, pp. 779–786.
142. X. LI, Q. ZHANG, L. TANG, P. LU, F. SUN, L. LI: Catalytic ozonation of p-chlorobenzoic acid by activated carbon and nickel supported activated carbon prepared from petroleum coke. Journal of Hazardous Materials 2009, Vol. 163, No. 1, pp. 115–120.
143. T. YAMAMOTO, S.-I. KIM, J. CHAICHANAWONG, E.-U. APILUCK, T. OHMORI: Removal of aqueous organic pollutants by adsorption-catalytic process using mesoporous carbon beads loaded with metal oxides. Applied Catalysis B: Environmental 2009, Vol. 88, No. 3–4, pp. 455–461.
144. Z. LIU, J. MA, L. ZHAO: Effect of preparation parameters on catalytic properties of Pt/graphite. Frontiers of Environmental Science & Engineering in China 2007, Vol. 1, No. 4, pp. 482–487.
145. Z-Q. LIU, J. MA, Y.-H. CUI: carbon nanotube supported platinium catalysts for the ozonation of oxalic acid in aqueous solutions. Carbon 2008, Vol. 46, No. 6, pp. 890–897.
146. D. BHATTACHARYYA, T.F. VAN DIERDONCK, S.D. WEST, A.R. FRESHOUR: Two-phase ozonation of chlorinated organics. Journal of Hazardous Materials 1995, Vol. 41, No. 1, pp. 73–93.
147. A.F. STICH, D. BHATTACHARYYA: Ozonolysis of organic compounds in a two-phase fluorocarbon-water system. Environmental Progress 1987, Vol. 6, No. 4, pp. 224–229.
148. A.R. FRESHOUR, S. MAWHINNEY, D. BHATTACHARYYA: Two-phase ozonation of hazardous organics in single and multicomponent systems. Water Research 1996, Vol. 30, No. 9, pp. 1949–1958.
149. C.Y. CHANG, J.N. CHEN: Ozonolysis of 2,4-dichlorophenol in a two-phase solvent/water system. Water Science and Technology 1994, Vol. 29, No. 9, pp. 343–346.
150. C.Y. CHANG, J.N. CHEN: Application of a fluorinated solvent to the conventional ozonation process for the destruction of 2,4-dichlorophenol. Environment International 1995, Vol. 21, No. 3, pp. 305–312.
151. D.B. WARD, C. TIZAOUI, M.J. SLATER: Extraction and destruction of organics in wastewater using ozone-loaded solvent. Ozone: Science and Engineering 2004, Vol. 26, No. 5, pp. 475–486.
152. D.B. WARD, C. TIZAOUI, M.J. SLATER: Ozone-loaded solvents for use in water treatment. Ozone: Science and Engineering 2003, Vol. 25, No. 6, pp. 485–495.
153. B. KASPRZYK, J. NAWROCKI: Preliminary results on ozonation enhancement by a perfluorinated bonded alumina phase. Ozone: Science and Engineering 2002, Vol. 24, No. 1, pp. 63–68.
154. I. NOWAK, B. KASPRZYK, M. ZIÓŁEK, J. NAWROCKI: A possible use of modified mesoporous molecular sieves in water treatment processes. Studies in Surface Science and Catalysis 2002, Vol. 141, pp. 591–598.
155. B. KASPRZYK, J. NAWROCKI: The feasibility of using a pefluorinated bonded alumina phase in the ozonation process. Ozone: Science and Engineering 2003, Vol. 25, No. 3, pp. 185–194.
156. B. KASPRZYK-HORDERN, K. GROMADZKA, P. ANDRZEJEWSKI, J. NAWROCKI: Zastosowanie faz niepolarnych do zwiększenia efektywności procesu ozonowania w technologii uzdatniania wody. Ochrona Środowiska 2003, vol. 25, nr 3, ss. 65–69.
157. B. KASPRZYK-HORDERN, A. DĄBROWSKA, J. ŚWIETLIK, J. NAWROCKI: The application of perfluorinated bonded alumina phase for organic matter catalytic ozonation. Journal of Environmental Engineering and Science 2004, Vol. 3, No. 1, pp. 41–50.
158. B. KASPRZYK-HORDERN, P. ANDRZEJEWSKI, A. DĄBROWSKA, K. CZACZYK, J. NAWROCKI: MTBE, DIPE, ETBE and TAME degradation in water using perfluorinated phases as catalysts for ozonation process. Applied Catalysis B: Environmental 2004, Vol. 51, No. 1, pp. 51–66.
159. B. KASPRZYK-HORDERN, A. DĄBROWSKA, J. ŚWIETLIK, J. NAWROCKI: Ozonation enhancement with non-polar bonded alumina phases. Ozone: Science and Engineering 2004, Vol. 26, No. 4, pp. 367–380.
160. B. KASPRZYK-HORDERN, P. ANDRZEJEWSKI, J. NAWROCKI: Catalytic ozonation of petroleum compounds in model and natural water in the presence of perfluorinated alumina bonded phases. Ozone: Science and Engineering 2005, Vol. 27, No. 4, pp. 301–310.
161. F. EROL, T.A. ÖZBELGE: Catalytic ozonation with non-polar bonded alumina phases for treatment of aqueous dye solutions in a semi-batch reactor. Chemical Engineering Journal 2008, Vol. 139, No. 2, pp. 272–283.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BPOK-0023-0001