Mezoporowate materiały węglowe: Synteza z wykorzystaniem matryc krzemionkowych i charakterystyka właściwości adsorpcyjnych

Choma, J.; Jaroniec, M.; Kloske, M.; Zawislak, A.

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Mezoporowate materiały węglowe: Synteza z wykorzystaniem matryc krzemionkowych i charakterystyka właściwości adsorpcyjnych

Autorzy

Choma J. , Jaroniec M. , Kloske M. , Zawislak A.

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Warianty tytułu

Mesoporous carbon materials: Silica-templating synthesis and characterization of adsorption properties

Języki publikacji

Abstrakty

Przedstawiono krytyczny przegląd badań dotyczących otrzymywania i charakterystyki właściwości mezoporowatych materiałów węglowych, w tym w szczególności materiałów uporządkowanych. Omówiono najważniejsze metody otrzymywania uporządkowanych mezoporowatych węgli przy użyciu uporządkowanych mezoporowatych krzemionek, koloidalnych cząstek krzemionkowych oraz koloidalnych kryształów krzemionkowych. Szczególną uwagę poświęcono metodzie wykorzystującej monolity ze sprasowanej koloidalnej krzemionki jako matryce, które impregnowano kwasem szczawiowym (katalizator) i następnie pochodnymi fenolu z formaldehydem (te ostanie po polimeryzacji były karbonizowane). Wykazano, że ta metoda umożliwia otrzymanie jednorodnego mezoporowatego materiału węglowego, również takiego materiału węglowego z nanocząstkami np. srebra, a także - po procesie aktywacji za pomocą KOH - mikro-mezoporowatego materiału węglowego. Omówione materiały węglowe mają interesujące właściwości adsorpcyjne i strukturalne, takie jak względnie duże pole powierzchni, jednorodne i często uporządkowane mezopory oraz dużą objętość porów, które czynią je atrakcyjnymi materiałami do zastosowań w adsorpcji, katalizie oraz do magazynowania i przetwarzania energii.

This work presents a critical survey of accomplishments in the research on the synthesis and characterization of mesoporous carbon materials, especially ordered mesoporous carbons. An account is given of the major methods for the synthesis of ordered mesoporous carbons, using ordered mesoporous silicas, colloidal silica and colloidal silica crystals. Special attention was devoted to the method involving monoliths obtained from colloidal silica as templates, which after impregnation with oxalic acid (catalyst) were filled with phenol derivatives and formaldehyde; the latter were carbonized after polymerization. This method produced carbon materials with uniform mesopores, as well as carbons with nanoparticles such as silver, and after KOH activation, also carbons with micro- and mesopores. The aforementioned carbonaceous materials have interesting adsorption and structural properties (a relatively large surface area, uniform and often ordered mesopores, a large pore volume), which make them attractive for applications in adsorption, catalysis and energy storage, as well as for conversion-related uses.

Słowa kluczowe

materiał węglowy matryca krzemionkowa nanocząstka inżynieria środowiska właściwości adsorpcyjne

carbonaceous materials mesoporous silicas silica-templating nanoparticles environmental engineering sorption properties

Wydawca

Polskie Zrzeszenie Inżynierów i Techników Sanitarnych, Oddział Dolnośląski

Czasopismo

Ochrona Środowiska

Rocznik

2008

Tom

Vol. 30, nr 2

Strony

3--15

Opis fizyczny

Bibliogr. 77 poz.

Twórcy

autor

Choma J.

autor

Jaroniec M.

autor

Kloske M.

autor

Zawislak A.

Uniwersytet Humanistyczno-Przyrodniczy Jana Kochanowskiego, Instytut Chemii, jchoma@wat.edu.pl

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