PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Detergenty pochodzące ze ścieków w środowisku przyrodniczym

Autorzy
Identyfikatory
Warianty tytułu
EN
Surfactants from the sewage in the environment
Języki publikacji
PL
Abstrakty
PL
Jedną z największych grup substancji syntetycznych wprowadzanych do środowiska przyrodniczego stanowią substancje powierzchniowo czynne. Największe ilości detergentów znajdują się w wodach powierzchniowych i w glebach. Syntetyczne środki powierzchniowo czynne trafiają do środowiska przede wszystkim wraz ze ściekami i osadami ściekowymi.
EN
One of the biggest group of anthropogenic synthetic substances in the environment are surfactants. Sewage treatment plants do not ensure the ultimate biodegradation of surfactants. Incomplete, primary degradation products are not well known yet, and can be far by more toxic than precursors. In consequence of incomplete degradation and sorption, considerable amount of surfactants and derivatives are introduced with effluents and sludge to surface waters and soils. Biodegradation rate under environmental conditions is slower, where specific microbial community and adaptation period is required. Strong sorption of surfactants to sediments and soil cause a delay of biodegradation of pollutants. Sorption is positively correlated with clay content, organic matter (especially humic substances) and calcium carbonate content. Even for easily-degradable detergents the half-live time can be two times longer in heavy soils, and there often occurs refractory surfactant pool, not available for bioconversion processes. The toxicity of detergents is not very high, but the exposure to a small concentration over a long time can be dangerous because of bioaccumulation risk. One of the best investigated examples is endocrine-disrupting activity of alkylphenols as a product of incomplete degradation of polyethoxylated alkylphenols. In soils toxic concentrations of surfactants occurs rare, and the main part of pollutants is immobilised. The risk of sewage sludge utilisation seems low but agricultural way of waste incineration requires a careful dosage and continuos monitoring of pollutants fate in the environment.
Czasopismo
Rocznik
Strony
156--163
Opis fizyczny
Bibliogr. 51 poz., rys., tab.
Twórcy
  • Akademia Techniczno-Rolnicza, Bydgoszcz
Bibliografia
  • [1] Abd-Allach M.A., Srorr T. 1998. Biodegradation of anionie surfactants in the presence of organie contaminants. Wat. Res. 32: 944-947.
  • [2] Abe-S., Seno M. 1987. Biodegradation of sodium linear alkyl benzene sułfonates evaluated with a soil perfusion method. J. Am. Oil. Chem. Soc., 64: 148-152.
  • [3] Ahel M., Giger W. 1993. Aqueous solubility of alkylphenols and alkylphenol polyethoxylates. Chemosphere, 26: 1461-70.
  • [4] Balson T., Felix M.S.B. 1995. The biodegradability of non-ionic surfactants. in: D.R. Karsa, M.R. Porter (Eds.), Biodegradability of Surfactants, Blackie Academic and Professional, 204-230.
  • [5] Battersby N.S. 1997. The ISO headspace CO2 biodegradation test. Chemosphere, 34: 1813-1822.
  • [6] Bechmann R.K. 1999. Effect of the endocrine disrupter nonyphenol on the marine copepod Tsibe battagliai. The Science of the Total Environment, 233: 33-46.
  • [7] Berna J.L., Ferrer J., Moreno A., Prats D., Bevia F.R. 1989. The fate of LAS in environment. Tenside Surf. Det.. 26: 101-107.
  • [8] Berna J.L., Moreno A., Ferrer J. 1991. The behavior of LAS in environment. J. Chem.Technol. Biotechnol.. 50: 387-398.
  • [9] Bester K., Theobald N., Schróder H.Fr. 2001. Nonylphenols, nonylphenol-ethoxylat.es, linear alkylbenzenesulfonates (LAS) and bis (4-chlorophenyl)-sulfone in the German Bight of the North Sea. Chemosphere. 45: 817-826.
  • [10] Carlsen L., Metzon M.B., Kjelsmark J. 2002. Linear alkylbenzene sulfonates (LAS) in the terrestrial environment. The Science of the Total Environment, 290: 225-230.
  • [11] Comber M.H.L, de Wolf W.. Cavalli L., van Egmond R.. Steber J., Tattersfield L.. Priston R.A. 2003. Assessment of bioconcentration and secondary poisoning of surfactants. Chemosphere. 52: 23-32.
  • [12] Cserhati T., Forgacs E., Oroś G. 2002 Biological activity and environmental impact ofanionie surfactants. Environment International, 28: 337-348.
  • [13] Dalzell D.J.B., Alte S., Aspichueta E., de la Sota A., Ebcebarria J.. Gutierrez M., HolTmann C.C., Sales D., Obst U., Christofi N. 2002. Acomparison of five rapid toxicity assessrnent methods to determine toxicity of pollutants to activated sludge. Chemosphere, 47: 535-545.
  • [14] DiToro D.M., Dodge L.J., Hand V.C. 1990. A model for anionie surfactant sorption. Environ. Sci. Technol.. 24: 1013-1020.
  • [15] Eichhorn P., Flavier M. E., Paje M., Knepper T.P. 2001. Ocourrence and fate oflinear and branched alkylbenzenesulfonates and their metabolites in surface waters in the Philippines. The Science of the Total Environment. 269: 75-85.
  • [16] Eichhorn P., Rodrigues S. V., Baumann W., Knepper T.P. 2002 Incomplete degradation of linear alkylbenzene sulfonate surfactants in Brazilian surface waters and pursuit of their polar metabolites in drinking waters. The Science of the Total Emvironment, 284: 123-134.
  • [17] Elsgaard L., Pojana G., Miraval T., Eriksen J., Marcomini A. 2003. Biodegradation of linear alkylbenzene sulfonates in sulfate-leached soil mesocosms. Chemosphere 50: 929-937.
  • [18] EPA/630/R-96/012. 1997. Special report on environmental endocrine disruption: an effects assessment and analysis. U.S. Environment Protection Agency. Washington. D.C. 20460. February 1997.
  • [19] Figge K., Klahn J., Koch J. 1986. Kinetic distribution model for chemicals based on results from a standard environmental system. Ecotoxicology and Environmental Safety, 11: 320-338.
  • [20] Figge K., Schóbert P. 1989. LAS and application of sewage sludge in agriculture. Tenside Surfactants Detergents, 26: 122-128.
  • [21] Gaca J. 2001. Problematyka ściekowa w chemii gospodarczej. Ekologia i Technika, IX.
  • [22] Gonzalez-Mazo E., Gómez-Parra A. 1996. Monitoring anionie surfactants (LAS) and their intermediate degradation products in the marine environment. TrAC Trends in Analytical Chemistry, 15: 375-380 .
  • [23] Haigh S.D. 1996. A review of the interaction of surfactants with organie contaminants in soil. The Science of the Total Environment. 185: 161-170.
  • [24] Hampel M., Blasco J. 2002. Toxicity oflinear alkylbenzene sulfonate and one long-chain degradation intermediate, sulfophenyl carboxylic acid on early life-stages of seabream (Sparus Aurata). Ecotoxicology and Environmental Safety. 51: 53-59.
  • [25] Isobe T., Nishiyama H., Nakashima A. 2001. Distribution and behaviour of nomdophenol. octylphenol. and nonylophenol monoethoxylate in Tokyo metropolitan area: their associacions with aquatic particles and sedimentary distributions. Environ. Sci. Technol., 35: 1041-1049.
  • [26] Jensen J. 1999. Fate and effects oflinear alkylbenzene sulphonat.es (LAS) in the terrestrial environment. The Science of the Total Environment, 226: pp. 93-1 11.
  • [27] Johnson A.C., White C., Besien T.J., Jurgens M.D. 1998. The sorption of octylphenol. a xenobiotic oestrogen, to suspended and bed-sediments from indijstrial and rura! reaches of three rivers. Sci. Total Environ., 219/211: 271-82.
  • [28] Kloepper-Sams P., Torfs F., Feijtel T., Gooch J. 1996. Effects assessments for surfactants in sludge-amended soils: a literature review and perspectives for terrestrial risk assessment The Science of the Total Environment. 185: 171-185.
  • [29] Klópffer W. 1996. Environmental hazard assessment of chemicals and products. Part V. Anthropogenic chemicals in sewage sludge. Chemosphere. 33: 1067-1081.
  • [30] Knaebel D., Federle T.W., McAvoy D.C., Vesial J.R. 1996. Microbial mineralization of organiecompounds in acidic agriculural soil: effect of predisposition to various soil constituents. Environ. Toxicol. Chem.. 15: 1865-1875.
  • [31] Knaebel D., Vestal J.R. 1992. Effects of intanrhizosphere microbial communities on the mineralization of surfactants in the surface soil. Can. J. Microbiol. 38: 643-663.
  • [32] Larson R.J., Federle T.W., Shimp R.J., Ventullo R.M. 1989. Behavior of linear alkylbenze sulfonate (LAS) in soil infiltration and groundwater. Tenside Surfactants Detergents, 26: 116-121.
  • [33] Lee C., Russell N.J., White G.F. 1995. Modelling the kinetics of biodegradation of anionie surfactants by biofilm baeteria from polluted riverine sites: A comparison of five classes of surfactant at three sites. Water Res.. 29: 2491-2497.
  • [34] Litz N., Doerning H.W., Thiele M., Blume H.P. 1987. The behavior of linear alkylbenzene sulfonate in different soils: A comparison between field studies. Ecotoxicology and Environmental Safety. 14:103-106.
  • [35] Liu Z., Edwards A., Luthy R.G. 1992. Non-ionic surfactant sorption onto soil. Water. Sci. Technol., 26: 2337-2340.
  • [36] Mann R.M., Boddy M.R. 2000. Biodegradation of a nonylphenol ethoxylate by the autochthonous microflora in lake water with observations on the influence oflight. Chemosphere, 41: 1361-1369.
  • [37] Margesin R., Schinner F. 1999. Biodegradnnon of diesel oil by cold-adapted microorganisms in presence of sodium dodecyl sulfate. Chromosphere. 38:3463-3472.
  • [38] Marschner A. 1992. Phytotoxizitatsuntersuchungen mit zwei anion-ischen detergentien (TPBS.LAS) und einem herbizid (Atrazin). Schriften-Reihe der vereins fur wasser -boden und lufthygiene, 89: 459-483.
  • [39] Matthijs E., de Henau H. 1985. Adsorption and desorption of LAS. Tenside Surfaetants Detergents, 22: 299-304.
  • [40] Montgomery-Brown J., Drewes J.E., Fox P., Reinhard M. 2003 Behavior of alkylphenol polyethoxlate metabolites during soil aquifer treatment. Water Research, 37: 3672-3681.
  • [41] Renner R., 1997. European bans on surfactant trigger transatlantic debatę. Environ. Sci. Technol., 31: 316-320.
  • [42] Reuschenbach R., Pagga U., Strotmann U. 2003. A critical comparison of respirometric biodegradation tests based on OECD 301 and related test methods. Wat. Res. 37: 1571-1582.
  • [43] Rogers H.R. 1996. Sources. behaaviour aand fate of orgaaanic contamitants during sewage treatment and sewage sludges. The Science of Total Environment, 185: 3-26.
  • [44] Scott M.J., Jones M.N. 2000. The biodegradation of surfactants in the emrironment. Biochimica et Biophysica Acta. 1508:235-251.
  • [45] Shurin J.B., Dodson S.T. 1997. Sublethal toxic effects of cyanobacteria and nonylphenol on environmental sex determination and development in Daphnia. Environ. Toxicol. Chem., 16: 1269-1276.
  • [46] Sonnenschein C., Soto A.M. 1998. Ań apdaate review of environmental estrogen.
  • [47] Swisher R.D. 1987. Surfactant. Biodegradation, Marcel Dekker. New York.
  • [48] Tolls J., Sijm D. 1993. Bioconcentration of surfactants. RITOX. University of Utrecht.
  • [49] Wolf W., Feitel T. 1998. Terresrial risk assessment for linear alkyl benzene sulfonate (LAS) in sludge-amended soils. Chomosphere, 3
  • [50] Ying G-G., Williams B., Kookana R. 2002. Environmental fate of alkylphenols and alkylphenol ethoxylates - a review. Environmental International, 28:215-226.
  • [51] Zieliński R. 2000. Surfaktanty - towaroznawcze i ekologiczne aspekty ich stosowania. Wydawnictwo Akademii Ekonomicznej, Poznań.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPOA-0018-0004
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.