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Simulated catalytic properties of Ce02 and Ru02 nanostructured dioxides under air-CH4 gas flow

Identyfikatory
Warianty tytułu
Konferencja
Advanced Materials and Technologies, AMT 2007 : XVIII Physical Metallurgy and Materials Science Conference (XVIII; 18-21.06.2007; Warszawa-Jachranka, Polska)
Języki publikacji
EN
Abstrakty
EN
In this work, we present the elaboration of nanostructured powders of cerium dioxide (Ce02.z) and ruthenium dioxide Ru02 by sol gel wute and their catalytic activities in presence of air methane mixtures. Prom Fourier transform infrared spectroscopy, the conversion rate of CH4 into C02 and H20 was determined as function of time. Nanostructured powders of Ce02 and Ru02 presented very different activities in presence of air-CH4 flows. We propose a semi-empirical Avrami' s approach of catalytic kinetics for these two different systems exposed to gas reduction during long times.
Słowa kluczowe
Rocznik
Strony
313--316
Opis fizyczny
Bibliogr. 19 poz., rys., tab.
Twórcy
autor
autor
autor
  • Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, Krakow, Poland
Bibliografia
  • [1] J. Kašpar, P. Fornasiero, M. Graziani, Catalysis Today, 50 (1999) 285-298.
  • [2] A. Trovarelli, Catalysis Review Science and Engineering, 38, 4, (1996), 439-520.
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  • [4] A. Tschöpe, J.Y. Ying, G.C. Hadjipanayis and R.W. Siegeles, Eds., 781, Kluwer Academic, Dordrecht/Norwell, MA, 1994.
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  • [7] A. Martinez-Arias, M. Fernandez-Garcia, O. Galvez, J.M. Coronado, J.A. Anderson, J.C. Conesa, J. Soria, G. Munuera, Journal of catalysis, 195, (2000), 207-216.
  • [8] G. Avgouropoulos, T. Ioannides, Applied Catalysis A: General, 6424, (2003), 1-4.
  • [9] H.C. Yao, H.F. Yu Yao, Journal of catalysis 86, (1984), 254- 265.
  • [10] M. Mogensen, N. M. Sammes, G. A. Tompsett, Physical, Solid State Ionics 129, (2000), 63-94.
  • [11] S. Villain, Ch. Leroux, J. Musso, J.R. Gavarri, A. Kopia, M. Klimczak, J. Kusinski, Journal of metastable and nanocrystalline materials, 12, (2002), 59-69.
  • [12] Saitzek S., Villain S., Gavarri J.R. – Nano-crystalline Cuox- Ceo2 systems for gas sensors: FTIR analyses of catalytic reactions. – Material Science Forum, Trans Tech Publications, vol. 513, p. 1-14, 2006
  • [13] M. Avrami,J. Chem. Phys. 7 pp.1103-1112, (1939).
  • [14] M. Avrami, J. Chem. Phys. 8 pp. 212-224, (1940).
  • [15] M. Avrami, J. Chem. Phys. 9 pp. 177-184, (1941).
  • [16] W.A. Johnson and R.F. Mehl, Trans. Am. Inst. Mining Met. Engrs, 135 pp 416-438, (1939).
  • [17] M. Chmielowska, A. Kopia, C. Leroux, S. Saitzek, J. Kusinski, J-R. Gavarri, Solid State Phenomena, vol. 99-100, p. 235-238, 2004
  • [18] A. Kopia, I. Suliga, P. Nowakowski, Comparison of the calculated methods the crystalline size of nanomaterials for catalytic application, Inżynieria Materiałowa, vol. 5, p. 1077- 1080, 2006
  • [19] A. Kopia, P. Nowakowski, I. Suliga, S. Villain, JR. Gavarri, Comparison of the catalytic properties the nanocrystaline oxides CeO2 and RuO2, Inżynieria Materiałowa, vol. 5, p. 1069-1072, 2006
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPL8-0005-0062
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