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Reaction kinetics of CO2 in aqueous methyldiethanolamine solutions using the stopped-flow technique

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Języki publikacji
PL
Abstrakty
EN
The kinetics of the reaction between CO2 and methyldiethanolamine in aqueous solutions have been studied using the stopped-flow technique at 288, 293, 298 and 303 K. The amine concentration ranged from 250 to 875 molźm-3. The overall reaction rate constant was found to increase with amine concentration and temperature. The acid base catalysis mechanism was applied to correlate the experimentally determined kinetic data. A good agreement between the second order rate constants for the CO2 reaction with MDEA computed from the stopped-flow data and the values reported in the literature was obtained.
Rocznik
Strony
7--18
Opis fizyczny
Bibliogr. 24 poz. , tab., wykr.
Twórcy
autor
  • Technical University of Lodz, Faculty of Process and Environmental Engineering, ul. Wólczańska 213, 90-924 Łódź, Poland
Bibliografia
  • 1. Donaldson T.L. and Nguyen Y.N., 1980. Carbon dioxide reaction kinetics and transport in aqueous amine membranes. Ind. Eng. Chem. Fundam., 19, 260-266. DOI: 10.1021/il60075a005.
  • 2. Figueroa J. D., Fouta T., Plasynski S., Mcllvried H., Srivastava R. D., 2008. Advances in C02 capture technology - The U.S. Department of Energy's Carbon Sequestration Program. Int. J Greenhouse Gas Control, 2, 9-20. DOI: 10.1016/S1750-5836(07)00094-1.
  • 3. Haimour N., Bidarian A., Sandall O.C., 1987. Kinetics of the reaction between carbon dioxide and methyldiethanolamine. Chem. Eng. Set, 42, 1393-1398. DOI: 10.1016/0009-2509(87)85011-X.
  • 4. Jamal A., Meisen A., Jim Lim C, 2006. Kinetics of carbon dioxide absorption and desorption in aqueous alkanolamine solutions using a novel hemispherical contactor - I. Experimental apparatus and mathematical modeling. Chem. Eng. ScL, 61, 6571-6589. DOI: 10.1016/j.ces.2006.04.046.
  • 5. Kierzkowska-Pawlak H., Chacuk A., 2010. Kinetics of carbon dioxide absorption into aqueous MDEA solutions. Ecol. Chem. Eng. S, 17, 463-475.
  • 6. Kierzkowska-Pawlak H., Chacuk A., 2011. Numerical simulation of C02 absorption into aqueous MDEA solutions, Korean J. Chem. Eng., 29 (6), accepted for publication.
  • 7. Knipe A. C, McLean D., Tranter N. L., 1974. A fast response conductivity amplifier for chemical kinetics, J. Phys. E., 1, 586-590. DOI: 10.1088/0022-3735/7/7/025.
  • 8. Li J., Henni A., Tontiwachwuthikul P., 2007. Reaction kinetics of C02 in aqueous ethylenediamine, ethylethanolamine, and diethylmonoethanolamine solutions in the temperature range of 298-313 K, using the stopped-flow technique. Ind. Eng. Chem. Res., 46, 4426-4434. DOI: 10.1021/ie0614982.
  • 9. Khorassani S. M. H., Ebrahimi A., Maghsoodlou T., Shahrakia M., Price D., 2011. Establishing a new conductance stopped-flow apparatus to investigate the initial fast step of reaction between l,l,l-trichloro-3-methyl-3-phospholene and methanol under a dry inert atmosphere, Analyst, 136, 1713-1721. DOI: 10.1039/c0an00817f.
  • 10. Ko J.-J., Li M.-H., 2000. Kinetics of absorption of carbon dioxide into solutions of N-mefhyldiethanolamine + water. Chem. Eng. ScL., 55,4139-4147. DOI: 10.1016/S0009-2509(00)00079-8.
  • 11. Kohl A. L. and Riesenfeld F. C, 1997. Gas Purification. 5* edition, Gulf Publishing, Houston.
  • 12. Littel R.J., Versteeg G.F., van Swaaij W.P.M., 1991. Kinetics of carbon dioxide with tertiary amines in aqueous solution. AIChEJ., 36, 1633-1640. DOI: 10.1002/aic.690361103.
  • 13. Moniuk W., Pohorecki R., 2000. Absorption of C02 in aqueous solutions of N-mefhyldiethanolamine. Inz. Chem. iProces., 2000, 21, 183-197 (in Polish).
  • 14. Notz R. J., Tonnies I., McCann N., Scheffknecht G., Hasse H., 2011. C02 capture for fossil fuel-fired power plants. Chem. Eng. TechnoL, 34, 163-172. DOI: 10.1002/ceat.201000491.
  • 15. Pani F., Gaunand A., Cadours R., Bouallou C, Richon D., 1997. Kinetics of absorption of C02 in concentrated aqueous methyldiethanolamine solutions in the range 296 K to 343 K. J. Chem. Eng. Data, 1997, 42, 353-359. DOI: 10.1021/je960251g.
  • 16. Pinsent B.R.W., Pearson L., Roughton J.W., 1956. The kinetics of combination of carbon dioxide with hydroxide ions. Trans. Faraday Soc, 52, 1512-1516. DOI: 10.1039/TF9565201512.
  • 17. Pohorecki R., Moniuk W., 1988. Kinetics of reaction between carbon dioxide and hydroxyl ions in aqueous electrolyte solutions, Chem. Eng. ScL, 43, 1677-1684. DOI: 10.1016/0009-2509(88)85159-5.
  • 18. Ramachandran N., Aboudheir A., Idem R., Tontiwachwuthikul P., 2006. Kinetics of the absorption of C02 into mixed aqueous loaded solutions of monoethanolamine and methyldiethanolamine. Ind. Eng. Chem. Res., 45, 2608-2616. DOI: 10.1021/ie0505716.
  • 19. Rinker E.B., Ashour S.S. and Sandall O.C. 1995. Kinetics and modeling of carbon dioxide absorption into aqueous solutions of N-methylodiethanolamine. Chem. Eng. ScL, 50 (5), 755-768. DOI: 10.1016/0009-2509(94)00444-V.
  • 20. Siemieniec M., Kierzkowska-Pawlak H., Chacuk A., 2012. Reaction kinetics of C02 in aqueous diethanolamine solutions in the temperature range of 293H-313 K using the stopped-flow technique, Ecological Chem. Eng. S, 19, 55-66. DOI: 10.2478/v 10216-011-0006-y.
  • 21. Steeneveldt R., Berger B., Torp T.A., 2006. C02 capture and storage. Closing the knowing-doing gap. Chem. Eng. Res. Des., 84, 739-763. DOI: 10.1205/cherd05049.
  • 22. Vaidya P.D., Kenig E.Y., 2007. C02-alkanolamine reaction kinetics: A review of recent studies. Chem. Eng. Technol, 30, 1467-1474. DOI: 10.1002/ceat.200700268.
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  • 24. Zhang X., Zhang C.-F., Liu Y., 2002. Kinetics of absorption of C02 into aqueous solution of MDEA blended with DEA. Ind. Eng. Chem. Res., 41, 1135-1141. DOI: 10.1021/ie010605j.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPK6-0021-0054
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