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The process of carbon dioxide removal from monoethanolamine (MEA) - water solution was investigated on Poly Di Methyl Siloxane (PDMS) hydrophobic tubular membrane with a ceramic support. The effects of feed temperature, liquid flow rate and MEA concentration on C02 mass transfer and selectivity were examined and found to be with a reasonable deviation (+/-25%) with predictions based on the multilayer film model. The membrane resistance was evaluated in separate experiments. The measured C02 mass fluxes (0.17-0.45 kg/(m2h)) were found to be independent of the MEA concentration in the feed.
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280--290
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Bibliogr. 15 poz., rys.
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autor
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- Institute of Chemical Engineering Polish Academy of Sciences, ul. Bałtycka 5, 44-100 Gliwice, Poland
Bibliografia
- 1. Astarita G., Savage D.W., 1980a. Theory of chemical desorption. Chem. Eng. Sci., 35, 649-656. DOI: 10.1016/0009-2509(80)80015-7.
- 2. Astarita G., Savage D.W., 1980b. Gas absorption and desorption with reversible instantaneous chemical reaction. Chem. Eng. Sci., 35, 1755-1764. DOI: 10.1016/0009-2509(80)85011-1.
- 3. Astarita G., Savage D.W., Bisio A., 1983. Gas treating with chemical reaction. Wiley, New York, 213 - 216.
- 4. Browning G.J., Weiland R.H., 1994. Physical solubility of carbon dioxide in aqueous alkanolamine via nitrous oxide analogy. J. Chem. Eng. Data, 39, 817-822. DOI: 10.1021/je00016a040.
- 5. Burkett R. J., 1977. The mathematical modeling and simulation of a monoethanolamine carbon dioxide plant. PhD Thesis, University of London.
- 6. DeCoursey W.J., 1982. Enhancement factors for gas absorption with reversible reaction. Chem. Eng. Sci., 37, 1483-1489. DOI: 10.1016/0009-2509(82)80005-5.
- 7. Disli I., 1996. A case study in optimal process operation; control of a carbon dioxide absorption plant. PhD Thesis, Imperial College, University of London.
- 8. Donaldson T.L., Nguyen Y.N., 1980. Carbon dioxide reaction kinetics and transport in aqueous amine membranes. Ind. Eng. Chem. Fundam., 19, 260-266. DOI: 10.1021/il60075a005.
- 9. Dugas R., Rochelle G., 2009. Absorption and desorption rates of carbon dioxide with monoethanolamine and piperazine. Energy Procedia, 1, 1163-1169. DOI: 10.1016/j.egypro.2009.01.153.
- 10. Kierzkowska-Pawlak H., Chacuk A., 2011. Kinetics of C02 desorption from aqueous N-methyldiethanolamine solutions. Chem. Eng. J., 168, 367-375. DOI: 10.1016/j.cej.2011.01.039.
- 11. Koonaphapdeelert S., Wu Z., Li K., 2009. Carbon dioxide stripping in ceramic hollow fibre membrane contactors. Chem. Eng. Sci., 64, 1-8. DOI:10.1016/j.ces.2008.09.010.
- 12. Kosarjan P., Kovvali A.S., Korikov A., Sirkarato K.K., 2005. Hollow fibre membrane contactor based C02 absorption-stripping using novel solvents and membranes. Ind. Eng. Chem. Res., 44, 1250-1258. DOI: 10.1021/ie0495630.
- 13. Kreulen H., Smolders C.A., Versteeg G.F., van Swaaij W.P.M., 1993. Microporous hollow fiber membrane module as gas-liquid contactors; Part 2. Mass transfer with chemical reaction. J. Membrane Sci., 78, 217-238. DOI: 10.1016/0376-7388(93)80002-F.
- 14. VDI Heat Atlas, 1993. VDI-Verlag GmbH, Diisseldorf.
- 15. Weiland R.H.,. Raval M, Rice M.G., 1982. Stripping of carbon dioxide from monoethanolamine solution in a packed column. AIChE J., 28, 963-073. DOI: 10.1002/aic.690280611.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPK6-0014-0039