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Application of flow microreactors for synthesis of noble metals nanoparticles (Pt, Pd, Au). Review
Języki publikacji
Abstrakty
W artykule zebrano informacje na temat możliwości zastosowania mikroreaktorów przepływowych do syntezy nanocząstek metali szlachetnych, takich jak: platyna, pallad i złoto. Na podstawie zebranych danych stwierdzono, że mikroreaktory przepływowe są obiecującym narzędziem umożliwiającym kontrolowaną syntezę nanocząstek metali o wąskiej dystrybucji rozmiarów w porównaniu do syntezowanych klasycznie, w tzw. reaktorze cyklicznym. Wyniki badań większości cytowanych autorów potwierdzają m.in., że szybkość przepływu reagentów przez mikroreaktor ma znaczący wpływ na wielkość i dystrybucję otrzymywanych nanocząstek. Są one mniejsze i bardziej jednorodne niż otrzymywane w reaktorze cyklicznym.
In this work, literature data about application of the flow microreactors for synthesis of noble metal nanoparticles (like gold, palladium and platinum) are collected. Using these information it was concluded that flow microreactor systems are promising tool for controlled synthesis of noble metal nanoparticles with the narrow size distribution in comparison with synthesized classically in the batch reactor. Collected results of the most cited authors here confirm that the flow rate of reactants through the microreactor significantly influences the size and size distribution synthesized nanoparticles. It can be generally concluded that obtained using such method nanoparticles are smaller and more uniform if compare with the synthesized in the batch reactor.
Wydawca
Czasopismo
Rocznik
Tom
Strony
745--752
Opis fizyczny
Bibliogr. 38 poz., tab.
Twórcy
autor
autor
autor
autor
autor
autor
autor
- AGH Akademia Górniczo-Hutnicza, Wydział Metali Nieżelaznych, Katedra Fizykochemii i Metalurgii Metali Nieżelaznych, al. Mickiewicza 30, 30-059 Kraków
Bibliografia
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- 21. Song Y., Kumar C. S. S. R., Hormes J.: Synthesis of palladium nanoparticles using a continuous flow polymeric microreactor. Journal of Nanoscience and Nanotechnology, 2004, t.4, nr 7, s. 788-793.
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- 23. Wagner J., Köhler J. M.: Continuous synthesis of gold nanoparticles in a microreactor. Nano Letters, 2005, t. 5, nr 4, s. 685-691.
- 24. Shalom D., Wootton R. C. R., Winkle R. F., Cottam B. F., Vilar R., de Mello A. J., Wilde C. P.: Synthesis of thiol functionalized gold nanoparticles using a continuous flow microfluidic reactor. Materials Letters, 2007, t. 61, s. 1146-1150.
- 25. Köhler J. M., Held M., Hubner U., Wagner J.: Formation of Au/Ag Nanoparticles in a Two Step Micro Flow‐Through Process. Chem. Eng. Technol. 2007, t. 30, nr 3, s. 347-354.
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- 29. Weng C. H., Huang C. C., Yeh C. S., Lei H. Y., Lee G. B.: Synthesis of hexagolan gold nanoparticles using a microfluidic reaction system. Journal of Micromechanics and Microengineering, 2008, t. 18, s. 1-8.
- 30. Moisan S., Marty J. D., Cansell F., Aymonier C.: Preparation of functional hybrid palladium nanoparticles using supercritical fluids: a novel approach to detach the growth and functionalization step. Chem. Comm, 2008, s. 1428-1430.
- 31. Singh A., Shirolkar M., Lalla N. P., Malek C. K., Kulkarni S. K.: Room temperature, water‐based, microreactor synthesis of gold and silver nanoparticles. International Journal of Nanotechnology, 2009, t. 6, s. 541-551. 752
- 32. Torgoe K., Watanabe Y., Endo T., Sakai K., Sakai H., Abe M.: Microflow reactor synthesis of palladium nanoparticles stabilized with poly(benzyl ether) Dendron ligands. Journal of Nanoparticle Resarch, dostępny on‐line 13 May 2009.
- 33. Wojnicki M., Pacławski K., Luty‐Błocho M., Fitzner K., Oakley P., Stretton A.: Synteza nanocząstek złota stabilizowanych PVA (alkohol poliwinylowy) w mikroreaktorze przepływowym. Rudy Metale, 2009, t. 54, nr 12, s.848-852.
- 34. Luty‐Błocho M., Fitzner K., Hessel V., Löb P., Maskos M., Metzke D., Pacławski K., Wojnicki M.: Synthesis of gold nanoparticles in an interdigital micromixer using ascorbic acid and sodium borohydride as reducers. Chemical Engineering Journal, 2011, nr 171, s. 279-290.
- 35. Luty‐Błocho M., Pacławski K., Jaworski W., Streszewski B., Fitzner K: Kinetic studies of gold nanoparticles formation in the batch and in the flow microreactor system. Prog. Colloid Polym. Sci., 2011, nr 138, s. 39-44.
- 36. Sung‐Yi Yang, Fong‐Yu Chang, Chen‐Sheng Yeh, Gwo‐Bin Lee: Size controlled synthesis of gold nanoparticles using a micro mixing system. Microfluid Nanofluid, 2009, t. 8, s. 303-311.
- 37. Desportes S., Fries D. M., Trachsel F., von Rohr P. R.: Synthesis of palladium nanoparticles from ogranometalic chemistry route in a two phase flow microreactor. Twelfth International Conference on Miniaturized Systems for Chemistry and life Sciences October 12-16, 2008, San Diego, California USA.
- 38. Kohler J. M., Romanus H., Hübner U., Wagner J.: Formation of star‐like and core‐shell AuAg nanoparticles during twoand three‐step preparation in batch and in microfluidic systems. Jurnal of Nanomaterials, 2007, s. 1-7.
Typ dokumentu
Bibliografia
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