A comparative study of thermodynamic electrolyte models applied to the Solvay soda system

Jaworski, Z.; Czernuszewicz, M.; Gralla, Ł.

Artykuł - szczegóły

Tytuł artykułu

A comparative study of thermodynamic electrolyte models applied to the Solvay soda system

Autorzy

Jaworski Z. , Czernuszewicz M. , Gralla Ł.

Treść / Zawartość

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Abstrakty

Fast development of computation techniques for electrolyte activities contributed recently to introduction of a few substantial programmes for thermodynamic computing of multiphase systems. The presented study comprises useful information for practical computing using selected thermodynamic models of aqueous electrolyte solutions. Those models enable quantitative description of both phase and ionic equilibria and provide values of activity coefficients. The carried out analysis of individual models involved a comparison of their practical effectiveness features along with problems encountered in evaluation of the coefficients. The authors conclude that for the Solvay soda system the exUNIQUAC model for an in-house code or the MSE model for a commercial one can be used.

Słowa kluczowe

thermodynamic model electrolytes activity coefficients soda system

model termodynamiczny elektrolit

Wydawca

Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk

Czasopismo

Chemical and Process Engineering

Rocznik

2011

Tom

Vol. 32, nr 2

Strony

135--154

Opis fizyczny

Bibliogr. 52 poz., tab., wybr.

Twórcy

autor

Jaworski Z.

autor

Czernuszewicz M.

autor

Gralla Ł.

West Pomeranian University of Technology, Szczecin; Institute of Chemical Engineering and Environmental Protection Processes, al. Piastów 42, 71-065 Szczecin, Poland

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