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Silver particles having fine or ultrafine sizes are one of the fastest growing research interests with wide applications. Here we report the preparation method of silver modified paints which revealed antimicrobial activity against gram-negative bacteria Escherichia coli, gram-positive Staphylococcus aureus, yeast Saccharomyces cerevisiae and pathogenic fungi belonging to Candida family. In this work, we choose heptane and cyclohexane, as the oil phase for preparation nanometer sized metallic particles. We have also studied the effect of different silver precursors – silver nitrate, silver citrate and different surfactants: anionic AOT, non-ionic Triton X100, Span 80 and Tween 85 for stabilization of obtained silver colloids. UV-VIS spectrum contained a strong plasmon band near 410 nm, which confirmed silver ions reduction to Ag° in microemulsion system or aqueous phases. Prepared samples contained from 500 to 2000 ppm of silver. The diameter size of silver nanoparticles was in the range from 16 nm to 82 nm and were stable for 3 months without precipitation.
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12--20
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Bibliogr. 20 poz., rys., tab.
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autor
autor
autor
autor
autor
- 1Department of Chemical Technology, Faculty of Chemistry, Gdansk University of Technology, 80-233 Gdansk, Poland
Bibliografia
- 1. Zielinska A., Skwarek E., Gazda M., Zaleska A., Hupka J., Preparation of silver nanoparticles with controlled particle size, Procedia Chemistry 1 (2009) 1560–1566.
- 2. Kelsall R. W., Hamley I. W., Geoghegan M., K. Kurzydłowski [Ed.], Nanotechnologie, PWN, Warszawa 2008.
- 3. Rujitanaroj P., Pimpha N., Supaphol P.: Wound-dressing materials with antibacterial activityfrom electrospun gelatin fiber mats containing silver nanoparticles. Polymer 49 (2008), pp. 4723-4732.
- 4. Davies R. L., Etris S.F.: The Tdevelopment and functions of silver in water purification and disease control. Catal. Today 36 (1997), pp. 107-114.
- 5. Pike-Biegunski M. J.: Nanotechnologia w medycynie i farmacji, Lek w Polsce 15 (2005), pp. 98-103.
- 6. Zhang W., Qiao X., Chen J., Wang H.: Preparation of silver nanoparticles in water-in-oil AOT reverse micelles. J. Coll. Int. Sci. 302 (2006), pp. 370-373.
- 7. Lopez-Quintela M. A.: Synthesis of nanomaterials in microemulsions: formation mechanism and growth control. Curr. Opin. Coll. Int. Sci. 8 (2003), pp. 137-144.
- 8. Mazur M.: Elecrochemically prepared silver nanoflakes and nanowires. Electrochem. Comm. 6 (2006) pp. 400-403.
- 9. Khaydarov R. A., Khaydarov R.R., Gapurova O., Estrin Y., Scheper T.: Electrochemical method for the synthesis of silver nanoparticles. J. Nanopart. Res. 11 (2009), pp. 1193-1200.
- 10. Song K. C., Lee S. M., Park T. S., Lee B. S.: Preparation of colloidal silver nanoparticles by chemical reduction method. Korean J. Chem. Eng. 26 (2009), pp. 153-155.
- 11. Lee S. M., Song K. C., Lee B. S.: Antibacterial activity of silver nanoparticles prepared by a chemical reduction method. Korean J. Chem. Eng. 27 (2010), pp. 688-692.
- 12. Zhu Y., Wang X., Guo W., Wang J., Wang C.: Sonochemical synthesis of silver nanorods by reduction of silver nitrate. Ultrason. Sonochem. 17 (2010), pp. 675-679.
- 13. Ghosh S. K., Kundu S., Pal T.: Evolution, dissolution and reversible generation of gold and silver nanoclusters in micelle by UV-activation. Bull. Mater. Sci. 25 (2002), pp. 581-582.
- 14. Mallick K., Witcomb M. J., Scurrell M. S.: Polymer stabilized silver nanoparticles: A photochemical synthesis route. J. Mater. Sci. 39 (2004), pp. 4459-4463.
- 15. Barcikowski S., Hustedt M., Chichkov B.: Nanocomposite manufacturing using ultrashort-pulsed laser ablation in solvent and monomers. Polimery 53 (2008), pp. 657-662.
- 16. Kabashin A. V., Meunier M.: Laser ablation-based synthesis of functionalized colloidal nanomaterials in biocompatible solutions. J. Photochem. Phothobiol. A 182 (2006), pp. 330-334.
- 17. Zhang W., Qiao X., Chen J.: Synthesis of silver nanoparticles—Effects of concerned parameters in water/oil microemulsion. Mater. Sci. Eng. B 142 (2007), pp. 1–15.
- 18. Parameswari E., Udayasoorian C., S. Paul Sebastian and R.M. Jayabalakrishnan,International Research Journal of Biotechnology 1(3) (2010) pp.044-049.
- 19. Ruparelia J.P., Chatterjee A.K., Duttagupta S.P., Mukherji S., Strain specificity in antimicrobial activity of silver and copper nanoparticles, Acta Biomater. 4(3) (2008) pp. 707-16.
- 20. Morones JR, Elechiguerra JL, Camacho A, Holt K, Kouri JB, Ramirez JT, The bactericidal effect of silver nanoparticles, Nanotechnology, 16 (2005) pp. 2346–53.
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Bibliografia
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