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Anticorrosive properties of electrolytic Co-P alloy coatings
Języki publikacji
Abstrakty
Przedstawiono proces elektroosadzania powłok stopowych Zn-Cr i Zn-Ni w warunkach prądu stałego i impulsowego. Dyskutowano wpływ składu kąpieli oraz parametrów osadzania na proces elektroosadzania (zawartość Cr/Ni oraz katodowa wydajność prądowa) i właściwości korozyjne otrzymanych powłok stopowych cynku. Otrzymane powłoki stopowe Zn-Cr i Zn-Ni o dobrej jakości zawierały do 3%Cr i do 20%Ni. Zawartość chromu bądź molibdenu w powłoce zależała od składu kąpieli i warunków prądowych. Badania korozyjne wykazały, że wprowadzenie chromu bądź niklu do powłoki Zn zwiększa jej odporność na korozję.
The paper describes the electrodeposition process of Zn-Cr and Zn-Ni alloy coatings with direct and pulse current.The influence of bath composition and process parameters ( the Cr/Ni content and the cathodic current efficiency) on the electrodeposition and corrosion properties of Zn alloy coatings is discussed. Good quality Zn-Cr and Zn-Ni alloy deposited coatings with good quality contained up to 3%Cr and to 20%Ni. The percentage of chromium or nickel in the coatings depended on the bath composition and current conditions. The corrosion studies showed that introduction Cr or Ni additives in Zn coatings increases their corrosion resistance.
Czasopismo
Rocznik
Tom
Strony
40--47
Opis fizyczny
Bibliogr. 61 poz., tab., rys.
Twórcy
autor
autor
autor
autor
- Instytut Mechaniki Precyzyjnej, Warszawa
Bibliografia
- [1] Socha J., Weber J.: Podstawy elektrolitycznego osadzania stopów metali, IMP, Warszawa, 2001.
- [2] Hyashi T.: From art to technology: developments in electroplating in Japan, "Plat. Surf. Finish.", 78(9), 1991,30.
- [3] Duprat von J.J.: 2ink-Legierungsverfahren. Aktualisierte Entwicklung der Legierungsverfahren zum Schutz von Stahl und Gusseisen, „Galvanotechnik", 92(2), 2001,346.
- [4] Żaki N.: Corrosion potential of zinc alloys, PF Online Feature Article, 6/9/2003 (www. pfonline.com)
- [5] Żaki N.: Zinc alloy plating, PF Online Feature Article, 6/9/2003 (www.pfonline.com)
- [6] Marzano M., Biddulph C.: Zinc alloy plating, PF Online Feature Article, 6/9/2003 (www. pfonline.com)
- [7] Siegert W., O'Grady J.: Zink-Kobalt, Zink-Nickel oder Zink-Eisen?, „Metalloberflache", 8, 1993, 378.
- [8] Gavrila M., Millet J.P., Mazille H., Marchandise D., Cuntz J.M.: Corrosion behaviour of zinc-nickel coatings, electrodeposited on steel, "Surf. Coat. Technol.", 123(2-3), 2000, 164.
- [9] Heydarzadeh Sohi M., Jalali M.: Study of the corrosion properties of zinc-nickel alloy electrodeposits before and after chromating, "Journal of Materials Processing Technology", 138(1-3), 2003, 63.
- [10] Alexis J., Adrian D., Masri T., Petit J.: Adherence of electrodeposited Zn-Ni coatings on EN AW2024 T3 aluminium alloy, "Surf. Engineering", 20(2), 2004,121.
- [11] Petrauskas A., Grincevićiene L., Ćeśuniene A., Juśkenas R.: Studies of phase composition of Zn-Ni alloy obtained in acetate-chloride electrolyte by using XRD and potentiodynamic stripping, "Electrochimica Acta", 50(5), 2005, 1189.
- [12] Wright D., Gage N., Wilson B.: Zinc-Nickel electroplate as a replacement for cadmium on high strength steels, "Plating Surf. Finish.", (3), 2006,18.
- [13] Girćiene O., Gudavićiute L., Juśkenas R., Ramanauskas R.: Corrosion resistance of phosphated Zn-Ni alloy electrodeposits, "Surf. Coat. Technol.", 203(20-21), 2009, 3072.
- [14] Watson A., Su Y., el-Sharif M., Chisholm C.: The Electrodeposition of Zinc Chromium Alloys and the Formation of Conversion Coatings without use of Chromate Solutions, "Trans. Inst. Metal Finish.", 71(1), 1993, 15.
- [15] el-Sharif M., Su Y., Chisholm C., Watson A.: Corrosion resistance of electrodeposited zinc-chromium alloy coatings, "Corrosion Science", 35(5-8), 1993, 1259.
- [16] Cholewa E., Bieliński J.: Badania procesu elektroosadzania stopów Zn-Cr, „Inżynieria Powierzchni", (2), 2001,32.
- [17] Cholewa E.: Badanie procesu elektroosadzania cynku z roztworów z dodatkami soli chromowców, praca doktorska, PW, 2003.
- [18] Boiadjieva Tz., Kovacheva D., Petrov K., Hardcastle S., Monev M.: Effect of anodic treatment on the composition and structure of electrodeposited Zn-Cr alloy coatings, "Corrosion Science", 46(3), 2004,681.
- [19] Boiadjieva Tz., Petrov K., Kronberger H., Tomandl A., Avdeev G., Artner W., Lavric T., Monev M.: Composition of electrodeposited Zn-Cr alloy coatings and phase transformations induced by thermal treatment, "Journal of Alloys and Compounds", 480(2), 2009, 259.
- [20] Korobow W., Trofimienko W., Loszkariew Ju., Baturin A., Czmilenko F.: Elektroosażdienie legirowannych molibdienom cinkowych pokrytij iż cinkat-nomolibdatnych rastworow, "Galvanotech. i Obrąb. Poverchnost.", 1(3-4), 1992, 32.
- [21] Bażewa T., Burkat G., Tichonow K.: Sulifatnyje elektrolity cinkowanja s dobawkami degirujuszczich elemientow dlja osażdienia galwanostojkowo pokrytja na powierchnost' elektroliticzeskoj mednoj folgi, „Galvanotech. i Obrąb. Poverchnost", 2(4), 1993,48.
- [22] Atraszkowa W., Atraszkow W., Gjerasimienko A.: Osażdienie cink-molibdienowych pokrytij, „Zaszcz. Met.", 31(3), 1995, 313.
- [23] Bozzini B., Pavan F., Bollini G., Cavallotti P.: Zn-Mn alloy electrodeposittion on steel, "Trans. Inst. Metal Finish", 75(5), 1997, 175.
- [24] Bozzini B., Accardi V., Cavallotti P., Pavan F.: Electrodeposition and plastic behavior of low-manganese zinc-manganese alloy coatings for automotive applications, :Metal Finish.", 97(5), 1999, 33.
- [25] Domoń-Szmigielska K., Rychlik E., Bieliński J.: Badania procesu elektroosadzania stopów Zn-Mn, „Inżynieria Powierzchni", (4), 2002, 24.
- [26] Boshkov N., Petrov K., Vitkova S., Raichevsky G.: Galvanic alloys Zn-Mn-composition of the corrosion products and their protective ability in sulfate containing medium, "Surf. Coat. Technol.", 194(2-3), 2005, 276.
- [27] Boshkov N., Petrov K., Raichevski G.: Corrosion behavior and protective ability of multilayer Galvanic coatings of Zn and Zn-Mn alloys in sulfate containing medium, "Surf. Coat. Technol.", 200(20-21), 2006, 5995.
- [28] Ortiz Z. I., Diaz-Arista P., Meas Y., Ortega-Borges R., Trejo G.: Characterization of the corrosion products of electrodeposited Zn, Zn-Co and Zn-Mn alloys coatings, "Corrosion Science", 51(11), 2009, 2703.
- [29] Cholewa E., Lutze R., Kwiatkowski L., Okurowski W.: Elektrolityczne powłoki stopowe cynku - kierunki rozwoju i zastosowanie, „Inżynieria Powierzchni", 2, 2007, 24.
- [30] Kostin N., Kublanovskij W.: Impulsnyj elektroliz spławów, „Naukowa Dumka", Kiew, 1996.
- [31] Loszkariew Ju., Kostin N., Korobow W., Burow L, Czmilenko F.: Osobiennosti struktury i niekotorych swojstw cinkowych pokrytij, elektroosażdiennych impulsnym tokom iż szczelocznych elektrolitów, „Elektrochimija", 30(10), 1994, 1287.
- [32] Saber Kh., Koch C.C., Fedkiw P.S.: Pulse current electrodeposition of nanocrystalline zinc, "Materials Science and Engineering" A, 341(1-2), 2003, 174.
- [33] Youssef Kh.M.S., Koch C.C., Fedkiw P.S.: Im-proved corrosion behavior of nanocrystalline zinc produced by pulse-current electrodeposition, "Corr-osion Science", 46(1), 2004, 51
- [34] Boshkov N.: Galvanic Zn-Mn alloys-electrode-position, phase composition, corrosion behaviour and protective ability, "Surf. Coat. Technol.", 172(2-3), 2003,217.
- [35] Gomes A., da Silva Pereira M.l.: Pulsed electrode position of Zn in the presence of surfactants, "Electrochimica Acta", 51(7), 2006, 1342.
- [36] Ramanauskas R., Gudavićiute L., Juśkenas R., Śćit O.: Structural and corrosion Characterization of pulse plated nanocrystalline zinc coatings, "Electrochimica Acta", 53(4), 2007, 1801.
- [37] Beriezin N., Gudin N., Filippowa A., Matulenis E., Borisow Ju.: Elektroosażdienie spława cink-chrom impulsnym tokom, „Zaszcz. Met.", 29(1), 1993, 99.
- [38] Fei Jing-Yin, Wilcox G.D.: Electrodeposition of Zn-Co alloys with pulse containing reverse current, "Electrochimica Acta", 50(13), 2005, 2693.
- [39] PagottoJr. S.O., de Alvarenga Freire C.M., Ballester M.: Zn-Ni alloy deposits obtained by continuous and pulsed electrodeposition processes, "Surf. Coat. Technol.", 122(1), 1999,10.
- [40] Ge F.Y., Xu S.K., Yao S.B., Zhou S.M.: Study of the structures of pulse plating Zn-Fe deposits, "Surf. Coat. Technol.", 88(1-3), 1997, 1.
- [41] Ashassi-Sorkhabi H., Hagrah A., Parvini-Ahmadi N., Manzoori J.: Zinc-nickel alloy coatings electro-deposited from a chloride bath using direct and pulse current, "Surf.Coat.Technol.",140(3), 2001, 278.
- [42] Jiang Y., Guo X., Zhai C., Zhu Y., Ding W.: The influence of pulse parameters on Zn-Ni alloy coatings plated on AZ91 magnesium alloy, "Trans. Inst. Metal Finish.", 81(6), 2003, 182.
- [43] Miiller C., Sarret M., Andreu T.: ZnMn alloys obtained using pulse, reverse and superimposed current modulations, "Electrochimica Acta", 48(17), 2003,2397.
- [44] Ramanauskas R., Gudaviciute L., Kalinicenko A., Juskenas R.: Pulse plating effect on microstructure and corrosion properties of Zn-Ni alloy coatings, "Int. Conf. Modern Electroplating Processes", Szklarska Poręba, 2004.
- [45] Fei Jing-Yin, Wilcox G.D.: Electrodeposition of Zn-Co alloys with pulse containing reverse current, "Electrochimica Acta", 50(13), 2005, 2693.
- [46] Jiang Y.F., Zhai C.Q., Liu L.F., Zhu Y.P., Ding W.J.: Zn-Ni alloy coatings pulse-plated on magne¬sium alloy, "Surf. Coat. Technol.", 191(2-3), 2005, 393.
- [47] Jiang Y.F., Liu L.F., Zhai C.Q., Zhu Y.P., Ding W.J.: Corrosion behavior of pulse-plated Zn-Ni alloy coatings on AZ91 magnesium alloy in alkaline solutions, "Thin Solid Films", 484(1-2), 2005, 232 .
- [48] Lin Ch., Huang Ch.: Zinc-nickel alloy coatings electrodeposited by pulse current and their corrosion behavior, "JCT Research", 3(2), 2006, 99.
- [49] Chang L.M., Chen D., Liu J.H., Zhang R.J.: Effects of different plating modes on microstructure and corrosion resistance of Zn-Ni alloy coatings, "Journal of Alloys and Compounds", 479(1-2), 2009, 489.
- [50] Boonyongmaneerat Y., Saenapitak S., Saengkiettiyut K.: Reverse pulse electrodeposition of Zn-Ni alloys from a chloride bath, "Journal of Alloys and Compounds", 487(1-2), 2009, 479.
- [51] Chandrasekar M.S., Shanmugasigamani, Pushpavanam M.: Morphology and texture of pulse plated zinc-cobalt alloy, "Materials Chemistry and Physics", 115(2-3), 2009, 603.
- [52] Ben-Ali M.N., Danilov F.l., Mandryka M.M.: Issledovanie elektrovosstanovlenija ionov chroma(III) iż formiatnogo elektrolita, "Elektrochimija", 27(4), 1991, 532.
- [53] Danilov F.l., Protsenko V.S., Butyrina T.E.: Chromium electrodeposition kinetics in solutions of Cr(lll) complex ions, Russian "J. Electrochem.", 37(7), 2001,704.
- [54] Watson A., Anderson A.M.H., el-Sharif M.R., Chisholm C.U.: The role of chromium II catalysed olation reactions in the sustained deposition of chromium and its alloys from enviromentally acceptable chromium III electrolytes, "Trans. Inst. Metal Finish", 69(1), 1991,26.
- [55] Duan S., Li H., Zhang X., Sun G., Dash J.: Hard chromium plating from a trivalent plating bath, "Płat. Surf. Finish.", 82(6), 1995, 84.
- [56] Ibrahim S.K., Watson A., Gawne D.T.: The Role of formic acid and methanol on speciation rate and quality in the electrodeposition of chromium from trivalent electrolytes, "Trans. Inst. Metal Finish",7 5(5), 1997, 181.
- [57] Ibrahim S.K., Gawne D.T., Watson A.: Corrosion and wear resistance of thick chromium deposits from accelerated Cr(III) electrolytes, "Trans. Inst. Metal Finish", 76(4), 1998, 156.
- [58] Berezin N.B., Gudin N.N., Ćevela V.V., Filippova A.G.: Roi kompleksoobrazovanija pri katodnom na-nesenii cink-chromovych pokrytij iż kisłych glicinsoderżaszcich elektrolitov, „Zaść. Met.", 28(6), 1992, 961.
- [59] Alonso F., Madina V., Viviente J.L., Mursell T., Onate J.I.: Zn-Cr alloy coatings produced by ion beam assisted deposition, "Surf. Coat. Technol.", 103-104, 1998,87.
- [60] Brenner A.: Electrodeposition of alloys, vol.1 i 2, Academic Press, New York 1963
- [61] Suchotin A.M.: Spravocnik po elektrochimii, „Chimija", Leningrad 1981.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPG8-0034-0014