Występowanie i oznaczanie pestycydów w owocach i warzywach

Fenik, J.; Tankiewicz, M.; Biziuk, M.

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Tytuł artykułu

Występowanie i oznaczanie pestycydów w owocach i warzywach

Autorzy

Fenik J. , Tankiewicz M. , Biziuk M.

Identyfikatory

Warianty tytułu

The occurrence and determination of pesticides in fruits and vegetables

Języki publikacji

Abstrakty

Powszechnie stosowane pestycydy uważane są za jedne z najbardziej niebezpiecznych zanie-czyszczeń środowiska, ze względu na trwałość, mobilność oraz długofalowe skutki działania na organizmach żywych. Niebezpieczna jest ich obecność w środowisku ponieważ stanowią one źródło narażenia zdrowia ludzkiego na choroby. Z tego też względu niezbędne jest kontrolowanie pozostałości pestycydów w owocach i warzywach za pomocą dostępnych metod analitycznych. Analiza próbek pod kątem obecności pestycydów przysparza wiele trudności ze względu na przygotowanie próbki poprzez wieloetapowe operacje oczyszczania próbki zawierającej śladowe ilości analitu przy jednocześnie dużym obciążeniu substancjami przeszkadzającymi. Omówiono poszczególne etapy wykorzystywane w procedurach oznaczania pozostałości pestycydów w próbkach środowiskowych. Omówiono najczęściej stosowane techniki ekstrakcji i oznaczeń pestycydów współcześnie stosowanych.. Ponadto przedstawiono trudności analityczne występujące na poszczególnych etapach postępowania analitycznego.

Applied all over the world, pesticides are some of the most dangerous pollutants of the environment because of their stability, mobility, their ability to accumulate in the environment and their consequent long-term adverse effects on living organisms in general and human health in particular. For these reasons it is essential to monitor and analyse pesticide residues in the fruits and vegetables. The analysis of food samples for the presence of pesticides causes a lot of difficulties in consideration of specificity of sample preparation based on multistage operations of purification of sample containing vestigial amount of analyte with simultaneous large amount interferents. The extraction and determination of pesticide residues in environmental samples are discussed, as are the techniques most commonly used in these processes. The difficulties occurring at each stage in the analytical procedure are outlined.

Słowa kluczowe

pestycydy owoce warzywa przygotowanie próbek techniki oznaczeń końcowych

pesticides fruits vegetables sample preparation extraction final determination techniques

Wydawca

Bydgoskie Towarzystwo Naukowe

Czasopismo

Ekologia i Technika

Rocznik

2010

Tom

R. 18, nr 4

Strony

186--197

Opis fizyczny

Bibliogr. 73 poz. rys., tab.

Twórcy

autor

Fenik J.

autor

Tankiewicz M.

autor

Biziuk M.

Politechnika Gdańska, Wydział Chemiczny, Katedra Chemii Analitycznej, 80-233 Gdańsk, ul. G. Narutowicza 11/12

Bibliografia

1. Biziuk M., Hupka J., Wardencki W., et.al, 2001, Pestycydy, występowanie, oznaczanie i unieszkodliwianie, Wydawnictwo Naukowo-Techniczne WNT, Warszawa.
2. Moreno J. L., Liebanas F. J., Frenich A. G., Vidal J.L., 2006, Evaluation of different sample treatments for determining pesticide residues in fat vegetable matrices like avocado by low-pressure gas chromatography-tandem mass spectrometry, J. Chromatogr. A., 1111, 97-105.
3. Hajslova J., Zrostlikova J., 2003: Matrix effects in (ultra)trace analysis of pesticide residues in food and biotic matrices, J. Chromatogr. A., 1000, 181-197.
4. Namieśnik J., Jaśkowski J., 1995, Zarys Ekotoksykologii, Eko-Pharma, Gdańsk.
5. Biziuk M., Przyjazny A., Czerwiński J., Wiergowski M., 1996, Occurrence and determination of pesticides in natural and treated eathers, J. Chromatogr. A., 754, 103-123.
6. Jokanović M., 2009, Medical treatment of acute poisoning with organophosphorus and carbamate pesticides, Toxicol. Lett., 190, 107-115.
7. Jokanović M., 2001, Biotransformation of organophosphorus compounds, Toxicology, 166, 139-160.
8. Zhang J., Lee H.K., 2006, Application of liquid-phase microextraction and on-column derivatization combined with gas chromatog-raphy-mass spectrometry to the determination of carbamate pesticides, J. Chromatogr. A., 1117, 31-37.
9. Papadakis E.N., Yryzas Z., PapadopoulouMourkidou E., 2006, Rapid method for the determination of 16 organochlorine pesticides in sesame seeds by microwave-assisted extraction and analysis of extracts by gas chromatography-mass spectrometry, J. Chromatogr. A., 1127, 6-11.
10. Chen S., Shi L., Shan Z., , Hu Q., 2007, Determination of organochlorine pesticide residues in rice and human and fish fat by sim-plified two-dimensional gas chromatography, Food Chem., 104, 1315-1319.
11. Adeyeye A., Osibanjo O., 1999, Residues of organochlorine pesticides in fruits, vegetables and tubers from Nigerian markets, The Science of theTotal Environ., 23, 227-233.
12. Escuderos-Morenas M.L., Santos-Delgado M.J., Rubio-Barroso S., Polo-Diez L.M. 2003, Direct determination of monolinuron, linuron and chlorbromuron residues in pota-to samples by gas chromatography with nitrogen-phosphorus detection J. Chromatogr. A., 1011, 143-153.
13. http://www.bip.minrol.gov.pl/DesktopDe-fault.aspx?TabOrgId=907&LangId=0 (accessedMarch2010).
14. http://ec.europa.eu/sanco_pesticides/pub-lic/index.cfm (accessed March 2010).
15. Namieśnik J., Jamrógiewicz Z., Pilarczyk M., Torres L., 2000, Przygotowanie próbek środo-wiskowych do analizy; Wydawnictwo Nauko-wo-Techniczne WNT, Warszawa.
16. Stajnbaher D., Zupancic-Krall L., 2003, Multiresidue method for determination of 90 pes-ticides in fresh fruits and vegetables using solid-phase extraction and gas chromatography-mass spektrometry, J. Chromatogr. A., 1015, 185-198.
17. Namieśnik J., Szef er P., Ecol. Chem. Eng., 2008, 15, 167-249.
18. Ramos J.J., Gonzalez M.J., Ramos L., 2009, Comparison of gas chromatography-based approaches after fast miniaturized sample preparation for the monitoring of selected pesticide classes in fruits, J. Chromatogr. A., 1216, 7307-7313.
19. Cal L., Gong S., Chen M., Wu C., 2006, Vinyl crown ether as a novel radical crosslinked solgel SPME fiber for determination of organophosphorus pesticides in food samples, Anal. Chem. Acta., 559, 89-96.
20. Tanaka T., Hori T., Asada T, Oikawa K., Ka-wata K., 2007, Simple one-step extraction and cleanup by pressurized liquid extraction for gas chromatographic-mass spectrometric determination of pesticides in green leafy vegetables, J. Chromatogr. A., 1175, 181-186.
21. Brug J., Dębie S., van Assema P., Weijts W., 1995, Psychosocial Determinants of Fruit and Yegetable Consumption AmongAdults: Results of Focuc Group Interviews, Food Quality and preference., 6, 99-107.
22. EL-Saeid M. H., AL-Dosari S. A., 2010, Monitoring of pesticide residues in Riyadh dates by SFE, MSE, SFC, and GC techniąues, Arabian J. of Chem. - article in press.
23. Guan H., Brewer W. E., Garris S. T., Morgan S. L., 2010, Disposable pipette extraction for the analysis of pesticides in fruit and vegetables using gas chromatography/mass spectrometry, J. Chromatogr. A., 1217, 1867-1874.
24. Berrada H., Fernandez M., Ruiz M.J., Moltó J.C., Mańes J., Font G., 2010, Capillary electrophoresis for analyzing pesticides in fruits and vegetables using solid-phase extraction and stirbar sorptive extraction, Food Con-trol, 21,36-44.
25. Kende A.; Csizmazia Z.; Rikker T.; Angyal V.; Torkos K., 2006, Combination of stir bar sorptive extraction-retention time locked gas chromatography-mass spectrometry and automated mass spectral deconvolution for pes¬ticide identification in fruits and vegetables Microchem. J., 84, 63-69.
26. Knezewvic Z., Serdar M., 2009, Screening of fresh fruit and vegetables for pesticide residues on Croatian market, Food Control, 20, 419-422.
27. Blasco C., Font G., PicoY., 2002, Comparison of microextraction procedures to determine pesticides in oranges by liquid chromatography-mass spectrometry, J. Chromatogr. A., 970, 201-212.
28. Sancho J.V., Ibanez M., Grimalt S., Pozo O.J., Hernandez F., 2005, Residue determination of cyromazine and its metabolite melamine in chard samples by ion-pair liquid chromatography coupled to electrospray tandem mass spectrometry, Anal. Chim. Acta., 530, 237-243.
29. Soler C., Manes J., PicoY., 2005, Comparison of liquid chromatography using triple quadrupole and quadrupole ion trap mass analyzers to determine pesticide residues in oranges, J. Chromatogr. A., 1067, 115-125.
30. Blasco C., Font G., Pico Y., 2004, Multiple-stage mass spectrometric analysis of six pes-ticides in oranges by liquid chromatography-atmospheric pressure chemical ionization-ion trap mass spectrometry, J. Chromatogr. A. 1043, 231-238.
31. Ferrer I., Garcia-Reyes J.F., Mezcua M., Thurman E. M., Fernandez-Alba A. R., 2005, Multi-residue pesticide analysis in fruits and vegetables by liquid chromatography-time-of-flight mass spectrometry, J. Chromatogr. A., 1082, 81-90.
32. Norii H. R., Christiansen A., Holen B., 2010, Independent evaluation of a commercial de-convolution reporting software for gas chromatography mass spectrometry analysis of pesticide residues in fruits and vegetables, J. Chromatogr. A., 217, 2056-2064.
33. Ińigo-Nuńez S., Herreros M.A., Encinas T., Gonzalez-Bulnes A., 2010, Estimated daily intake of pesticides and xenoestrogenic exposure by fruit consumption in the female population from a Mediterranean country (Spain), Food Control, ,21, 471-477.
34. Wu J., Luan T., Łan Ch., Wai Hung Lo T., Yuk Sing Chan G., 2007, Removal of residual pesticides on vegetable using ozonated water, Food Control, 18, 466-472.
35. Lambropoulou D. A., Albanis T. A., 2003, Headspace solid-phase microextraction in combination with gas chromatography-mass spectrometry for the rapid screening of organophosphorus insecticide residues in strawberries and cherries, J. Chromatogr. A., 993, 197-203.
36. Juan-Garcia A., Picó Y., Font G., 2005, Capillary electrophoresis for analyzing pesticides in fruits and vegetables using solid-phase extraction and stir-bar sorptive extraction, J. Chromatogr. A., 1073, 229-236.
37. Liu W., Hu Y., Zhao J., Xu Y., Guan Y., 2005, Determination of organophosphorus pesticides in cucumber and potato by stir bar sorptive extraction, J. Chromatogr. A., , 1095, 1-7.
38. Soler C., Manes J., Picó Y., 2005, Routine application using single quadrupole liquid chromatography-mass spectrometry to pesti¬cides analysis in citrus fruits, J. Chromatogr. A., 1088, 224-233.
39. Riu-Aumatell M., Castellari M., Lopez-Tamames E., Galassi S., Buxaderas S., 2004, Characterisation of volatile compounds of fruit juices and nectars by HS/SPME and GC/MS, Food Chem., 87, 627-637.
40. Torres C. M., Pico Y., Mafles J., 1996, Determination of pesticide residues in fruit and vegetables, J. Chromatogr. A., 754, 301-331.
41. Melo L.F.C., Collins C.H., Jardim I.C.S.F., 2004, New materials for solid-phase extraction and multiclass high-performance liquid chromatographic analysis of pesticides in grapes, J. Chromatogr. A., 1032, 51-58.
42. Sanusi A., Guillet V., Montury M., 2004, Advanced method using microwaves and solid-phase microextraction coupled with gas chromatography-mass spectrometry for the determination of pyrethroid residues in strawberries, J. Chromatogr. A., 1046, 35-40.
43. Sanchez A. G., Martos N. R.; Ballesteros E., 2006, Multiresidue analysis of pesticides in olive oil by gel permeation chromatography followed by gas chromatography-tandem mass-spectrometric determination, Anal. Chim. Acta., 558, 53-61.
44. Gelsomino A., Petrovicowa B., Tiburtini S., Magnani E., Felici M., 1997, Multiresidue analysis of pesticides in fruits and vegetables by gel permeation chromatography followed by gas chromatography with electron-capture and mass spectrometric detection, J. Chromatogr. A., 782, 105-122.
45. Yreuls J. J., Swen R. J.J., Goudriaan V. R, Kerkhoff M. A.T., Jongenotter G. A., Brink-man U. A.Th., 1996, Automated on-line gel permeation chromatography-gas chromatography for the determination of organophos-phorus pesticides in olive oil, J. Chromatogr. A., 750, 275-286.
46. Mezcua, M., Ferrer, C., Garcia-Reyes, J. F., Martinez-Bueno, M. J., Sigrist, M., Fernandez-Alba A. R., 2009, Analyses of selected non-authorized insecticides in peppers by gas chromatography/mass spectrometry and gas chromatography/tandem mass spectrometry, Food Chemistry, 112, 221-225.
47. Lehotay S. T., Ae Son K., Kwon H., Koesukwiwat U., Fu W., Mastovska K., Hoh E., Leepi-patpiboo N. N., 2010, Comparison of QuECh-ERS sample preparation methods for the analysis of pesticide residues in fruits and vegetables, J. Chromatogr. A., 1217, 2548-2560.
48. Thanh Dong N., Ji Eun Y., Dae Myung L., Gae-Ho L., 2008, A multiresidue method for the determination of 107 pesticides in cab-bage and radish using QuEChERS sample preparation method and gas chromatography mass spectrometry, Food Chem., 110, 207-213.
49. Lesueur C., Knittl P., Gartner M., Mentler A., Fuerhacker M., 2008, Analysis of 140 pesti-cides from conventional farming foodstuff samples after extraction with the modified QuECheRS method, Food Control., 19, 906-914.
50. Nocentini M., Focardi C., Fortini M., 2010, Single laboratory validation and uncertainly estimation of multiresidues method for determination of pesticides in vegetables and fruits by using QuEChERS sample extraction and GC-MS, Toxicology Letters, 196S, S37-S351
51. Łacina O., Urbanova J., Poustka J., Hajslo-va J., 2010, Identification/quantification of multiple pesticide residues in food plants by ultra-high-performance liquid chromatography-time-of-flłght mass spectrometry, J. Chromatogr. A., 1217, 648-659.
52. Koesukwiwat U., Lehotay S. J., Miao S., Leepi-patpiboon N., 2010, High Throughput Analy-sis of 150 Pesticides in Fruits and Vegetables using QuEChERS and Low-Pressure Gas Chromatography-Time-of-Flight Mass Spectrometry, J. Chromatogr. A., 1016.
53. CunhaS.C.,FernandesJ.O.,OliveiraM.B.P.P., 2009, Fast analysis of multiple pesticide resiues in apple juice using dispersive liquid-liquid microextraction and multidimensional gas chromatography-mass spectrometry, J. Chromatogr. A., 1216, 8835-8844.
54. Economou A., Botitsi H., Antoniou S., Tsipi D., 2009, Determination of multi-class pesti-cides in wines by solid-phase extraction and liquid chromatography-tandem mass spec¬trometry, J. Chromatogr. A., 1216, 5856-5867.
55. Mayer-Helm B., 2009, Method development for the determination of 52 pesticides in to-bacco by liquid chromatography-tandem mass spectrometry, J. Chromatogr. A., 1216, 8953-8959.
56. Nguyen T. D., Lee K. J., Lee M. H., Lee G. H., 2010 A multiresidue method for the determi¬nation 234 pesticides in Korean herbs using gas chromatography mass spectrometry, Mi- • crochem. J., 95, 43-49.
57. Gilbert-López B., Garcia-Reyes J. F., Molina- . Diaz A., 2009, Sample treatment and determi- f nation of pesticide residues in fatty vegetable j matrices: A review, Talanta., 79, 109-128.
58. Morał A., Sicilia M. D., Rubi O. S., 2009, De- i termination of benzimidazolic fungicides i in fruits and vegetables by supramolecular solvent-based microextractłon/liquid chro-matography/fluorescence detection, Anal. ChimI. Acta, 650, 207-213.
59. Dugo G., Di Bella G., La Torre M., Saitta M., 2005, Rapid GC-FPD determination of or-ganophosphorus pesticide residues in Sicil-ian and Apullan olive oil, Food Control., 16, 435-438.
60. Chai M.K., Tan G.H., 2010, Headspace solid phase microextraction for the evaluation of pesticide residue contents in cucumber and strawberry after washing treatment, Food Chem. -article in press.
61. Cunha S.C., Fernandes J.O., Alves A., Ol-iveira M.B.P.P., 2009, Fast low-pressure gas chromatography-mass spectrometry method for the determination of multiple pesticides in grapes, musts and wines, J. Chromatogr. A., 1216, 119-126.
62. http://www.pg.gda.pl/chem/Katedry/Anali-tyczna/index.php?option=com_content&tas k=view&id= 130&Itemid=86
63. Mol H.G.J., van Dam R.C.J., Streijger O.M., 2003, Determination of polar organophosphorus pesticides in vegetables and fruits using liquid chromatography with tandem mass spectrometry: selection of extraction solvent, J. Chromatogr. A., 1015, 119-127.
64. Kmellar B., Fodor P., Pareja L., Ferrer C., Martinnez-Uroz M. A., Yalwerde A., Fernandez Alba A. R., 2008, Validation and uncertainty study of a comprehensive list of 160 pesticide residues in multi-class vegetables by liquid chromatography-tandem mass spectrome¬try, J. Chromatogr. A., 1215, 37-50.
65. Delgado M.J.S., Barroso S. R., Fernandez-Tostado G. T., Polo-Diez L.M., 2001, Stability studies of carbamate pesticides and analysis by gas chromatography with flame ionization and nitrogen-phosphorus detection, J. Chromatogr. A., 921, 287-296.
66. Juan-Garcia A., Manes J., Font G., Pico Y., 2004, Evaluation of solid-phase extraction and stir-bar sorptive extraction for the determination of fungicide residues at low ug kg-1 levels in grapes by liquid chromatography-mass spectrometry, J. Chromatogr. A., 1050, 119-127.
67. Sadowska-Rociek A., Cieślik; E., 2008, Stosowane techniki i najnowsze trendy w oznaczaniu pozostałości pestycydów w żywności metodą chromatografii gazowej, Metrologia, 13, 33-38.
68. Dalluge J., van Rijn M., Beens J., Yreuls R. J. J., Brinkman U. A.Th., 2002, Comprehensive two-dimensional gas chromatography with time-off light mass spectrometric detection applied to the determination of pesticides in food extracts, J. Chromatogr. A., 965, 207-217.
69. Górecki T., Harynuk J., Panić O., 2003, Nowe horyzonty i wyzwania w analityce i monitoringu środowiskowym, Wyd. Centrum Doskonałości Analityki i Monitoringu Środowiskowego, Gdańsk.
70. Górecki T., Harynuk J., 2006, Comparison of comprehensive two-dimensional gas chromatography in conventional and stop-flow modes, J. Chromatogr. A., 1105, 159-167.
71. Marriott P., Shellie R., 2002, Principles and applications of comprehensive two-dimensional gas chromatography, Trends in Anal. Chem., 21, 573-583.
72. Dalluge J., Beens J., Brinkman U. A.Th., 2003, Comprehensive two-dimensional gas chromatography: a powerful and versatile analytical tool, J. Chromatogr. A. 1000, 69-108.
73. Ong R., Lundstedt S., Haglund P., Marriott P., 2003, Pressurised liquid extraction-comprehensive two-dimensional gas chromatography for fast-screening of polycyclicaromatic hydrocarbons in soil, J. Chromatogr. A., 1019, 221-232.

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