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Aim of this paper is evaluation of susceptibility of plasma nitrided structural steel to hydrogen absorption and degradation. Structural steel, nitrided at glow discharge in the gas mixture of various N2, H2, Ar content was subjected to cathodic hydrogen charging in acid solution simulating the aged engine oil. The effect of the nitrided layers on the hydrogen transport and on the irreversible trapping was evaluated by the measurements of the hydrogen permeation rate and by the vacuum extraction, respectively. Surfaces with modified layers were examined with the use of a scanning electron microscope (SEM) before and after hydrogen permeation tests. In the presence of the not defected compact nitride layer, no hydrogen permeation through the steel has been stated under the experimental conditions. Absorbed hydrogen was accumulated within this layer. Using the atmosphere of the higher nitrogen to hydrogen ratio at plasma assisted nitriding provides the formation of thin compact nitride zone, highly protective against corrosion and hydrogen degradation.
Słowa kluczowe
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Czasopismo
Rocznik
Tom
Strony
4--13
Opis fizyczny
Bibliogr. 18 poz., rys., fot., tab.
Twórcy
autor
- Gdańsk University of Technology, Faculty of Mechanical Engineering, Poland
Bibliografia
- 1. Y. Archakov, Vodorodoustojchivost stali, Metallurgia, Moskva, 1978.
- 2. E. Łunarska, O. Czerniajewa, A. Nakonieczny, Influence of surface treatments on 40HM steel resistance to general, pitting and stress corrosion, Surface Engineering 4 (2000) 12-19, (in Polish).
- 3. E. Łunarska, J. Michalski, Hydrogen behavior in the iron surface layer modified by plasma nitriding and ion boronising, Werkstoffe und Korrosion 51 (2000) 1-9.
- 4. P. Kula, The comparison of resistance to “hydrogen wear” of hardened surface layers, Wear 178 (1994) 117-121.
- 5. P. Kula, The “self-lubrication” by hydrogen during dry friction of hardened surface layers, Wear 201 (1996) 155-162.
- 6. T. Zakroczymski, N. Łukomski, J. Flis, The effect of plasma nitriding-base treatments on the absorption of hydrogen by iron, Corrosion Science 37 (1995) 811-822.
- 7. Nitriding Technology. Theory and Practice. Proc. 9th International Seminar, A. Nakonieczny (ed.), Institute of Precise Mechanics, Warsaw, Poland, 2003.
- 8. J. Michalski, J. Tacikowski, P. Wach, E. Łunarska, N. Tafta, T. Fraczek, The modern anticorrosion nitriding, International Journal of Physico-Chemical Mechanics of Materials 39 (2004) 541-547.
- 9. T. Burakowski, T. Wierzchoń, Surface Engineering, WNT, Warsaw, 2005, (in Polish).
- 10. M. Śmiałowski, Hydrogen in steel, WNT, Warsaw, 1961, (in Polish).
- 11. J. Ćwiek, K. Nikiforow, Hydrogen degradation of high-strength weldable steels in sea-water, Proceedings of Michal Smialowski International Symposium on Corrosion and Hydrogen Degradation „Advances in Corrosion Science and Application”, Zakopane, Poland, 9-13.09, 2003, 225-232.
- 12. J. Ćwiek, Research report of grant KBN 4 T08C 048 25 „Estimation of possibilities of increasing hydrogen degradation resistance of low-alloy steels by advanced thermo-chemical processes”, Gdańsk University of Technology, Gdańsk, 2006.
- 13. S.P. Lynch, Failures of structures and components by environmentally assisted cracking, Engineering Failure Analysis 1 (1994) 77-90.
- 14. PN-EN 10085:2003 Nitriding steels – Technical delivery conditions.
- 15. A. Bratkov, Teoreticheskie osnowy khimmotologii, Khimija, Moskva, 1980.
- 16. M.A.V. Devanathan, Z. Stachurski, W. Beck, A technique for the evaluation of hydrogen embrittlement characteristics of electroplating baths, Journal of the Electrochemical Society 110 (1963) 886-890.
- 17. E. Łunarska, K. Nikiforow, Topography of the environmental degradation of nitrided layers, Corrosion Protection 48 (2005) 62-65.
- 18. E. Łunarska, K. Nikiforow, E. Sitko, Stress corrosion cracking of bainite 0.3C-1Cr-1Mn-1Si-1Ni type steel in acid rain simulated solution, Werkstoffe und Korrosion 55 (2004) 373-380.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPG8-0018-0033