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Modification of the Microstructure and Properties of Laminate Titanium Alloy - TiAl Intermetallic Phases Composites By A Duplex Surface Engineering Treatment

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Laminate TiAl3 - titanium alloy composites have unique mechanical properties which result from a combination of the properties of the Ti-Al type intermetallic phases, such as the high stiffness and low density, and the properties of the titanium alloy, primarily its high ductility. These composite materials have already been used in industry, but their application is limited by the low resistance to frictional wear and to oxidation at elevated temperatures. The process of diffusion bonding of titanium alloys with an aluminum foil, followed by magnetron sputtering combined with glow ischarge-assisted oxidizing, yields a gradient-type material, i.e. a laminate composite built of the TiAl3-reinforced titanium alloy with a diffusion surface layer of the Al2O3+Ti-Al intermetallic phase type. The paper presents the results of examination of the structure (by optical, SEM and TEM microscopy), phase composition, chemical composition, frictional wear resistance of the Al2O3+TixAly intermetallic composite surface layers produced on the composites, described above, by a duplex method that combines magnetron sputtering and plasma oxidizing processes. The composite surface layers have a diffusion character, and their microstructure, thickness and phase composition can be modified by modifying the parameters of the hybrid process, in particular the parameters of the glow discharge oxidizing, since these decide about whether the structure of the layer is nano-crystalline or fine-grained and thereby about the properties of the laminate composite.
Rocznik
Strony
23--31
Opis fizyczny
Bibliogr. 12 poz., rys., fot., tab.
Twórcy
autor
  • Faculty of Materials Science and Engineering. Warsaw University of Technology, Warsaw 02-507, Wołoska 141, Poland
Bibliografia
  • 1. Rohatgi, D.J.Harach, K.S. Vecchio, K.P. Harvey, Resistance-curve and fracture behavior of Ti–Al3Ti metallic–intermetallic laminate (MIL) composites, Acta Materialia, 51 (2003), pp.2933-2957.
  • 2. Vecchio K.S., Synthetic Multifunctional Metallic-Intermetallic Laminate Composites, JOM, 3 (2005), pp.25-29.
  • 3. Wierzchoń T., Ossowski M., Advances in Science and Technology, Structure and Properties of αβ Titanium Alloy- TixAly Intermetallic Phases Laminate Composite 45 (2006), pp.1287-1292.
  • 4. Peng L.M., Wang J.H., Li H., Zhao J.H., He L.H., Synthesis and microstructural characterization of Ti–Al3Ti metal–intermetallic laminate (MIL) composites, Scripta Materialia, 52 (2005), pp.243-248.
  • 5. Kainuma R., Sato J., Ohnuma I., Ishida K., Phase stability and interdiffusivity of the L10-based ordered phases in Al-rich portion of the Ti–Al binary system, Intermetallics 13 (2005), pp. 784–791.
  • 6. Rolinski, G. Sharp, D.F. Cowgill, D.J. Peterman, Ion nitriding of titanium alpha plus beta alloy for fusion reactor applications, J. Nucl. Mater., 252 (1998), pp.200-208.
  • 7. Czyrska –Filemonowicz A., Buffat P.A., Łucki M., Moskalewicz T., Rakowski W., Wierzchon T., Transmission electron microscopy and atomic force microscopy characterisation of titanium-base alloys nitrided under glow discharge, Acta Materialia 53, 16 (2005), pp. 4367-4377.
  • 8. Sobiecki J.R., Wierzchoń T., Structure and properties of plasma carbonitrided Ti–6Al–2Cr–2Mo alloy, Surf. And Coat. Tech. 200(2006), pp. 4363-4367.
  • 9. Lutering G., Williams J.G., Titanium, Springer-Verlag, Berlin, Heidelberg 2003.
  • 10. Wierzchon T., Garbacz H. , Ossowski M., Structure and properties of Ti-Al intermetallic layers produced on titanium alloys by duplex treatment, Mat. Sci. Forum., 475-479 (2005), pp. 3883-3886.
  • 11. Deqing W., Ziyuan S., Yingli T., Microstructure and oxidation of hot-dip aluminized titanium at high temperature, Applied Surface Science 250 (2005), pp. 238–246.
  • 12. Liu Z. , Wang G., Improvement of oxidation resistance of γ-TiAl At 800 and 900◦C in air by TiAl2 coatings, Materials Science and Engineering A 397 (2005), pp. 50–57.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPG8-0018-0024
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