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Processes of the formation of the Fe (Mn)-bearing intermetallic phases in the Al-Fe-(Mn)-Si alloys

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In the present work the intermetallic phases in an Al corner of the Al-Fe- (Mn)-Si diagram were analysed in the area of the co-existence of the ternary α-AlFe (Mn) Si and quaternary α-Al(FeMn) Si compounds. The microstructure of the alloys, chemical composition of the phase constituents and thermal effects during continuous slow cooling were examined using microscopic observation, X-ray microanalysis and differential scanning calorimeter. The phase components present in the alloy AlSi2.5(Fe+Mn)12 (where Mn = 0.03, 0.25, 1.8, 3.0% mass.) were identified on the base of their chemical composition. The successive progress of the peritectic trans-formation L+Al3Fe (Mn, Si) - α-Al. +α-Al (FeMn) Si was shown as the Mn content in an alloy increased until the primary precipitation process of the quaternary α-Al (FeMn) Si phase started. The chemical composition of the phase components was estimated during the progress of the phase transformation. The content of Si in the primary Al3Fe phase was evaluated to be in the range 0.9-2.0% mass. Simultaneously, the Mn presence (0.5-8.5% mass. increasing with an increase in the Mn content in the alloy) was stated in this primary phase. A limit of the Mn concentration in the alloy promoting the process of the primary precipitation of the α-Al (FeMn) Si phase was established as 2.5% mass. This Mn effect was enhanced by 1.3% Cr addition into quaternary alloy. The temperature and the sequence of the phase transformations during slow cooling (5K/min) of the examined alloys were identified. The temperature range of the primary precipitation of the binary, ternary and quaternary intermetallic phases, influenced by the Mn content in the alloy, was estimated.
Rocznik
Strony
81--91
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
  • Foundary Research Institute, Kraków, Poland
autor
  • Foundary Research Institute, Kraków, Poland
  • Rzeszów University of Technology, Rzeszów, Poland
autor
  • Rzeszów University of Technology, Rzeszów, Poland
Bibliografia
  • 1. Mondolfo L.F.: Aluminium alloys: structure and properties, Butterworths, 1976.
  • 2. Petzow G., Effenberg G.: Ternary alloys, A comprehensive compendium of evaluated constitutional data and phase diagrams, ASM International, USA, 1992
  • 3. Rivlin V.G., Raynor G.V.: A critical evaluation of constitution of aluminium silicon system, International Metals Review, (1981), No.3, pp.133-152
  • 4. Cooper M.: The crystal structure of the ternary alloy α-(AlFeSi), Acta Cryst., 23 (1967), pp. 1106-117
  • 5. Munson D.: A clarification of the phases occurring in aluminium -rich aluminium-iron-silicon alloys, with particular reference the temary phase a-AlFeSi, Journal of the Institute of Metals, 95 (1967), pp. 217-219.
  • 6. Cooper m., Robinson K.: The crystal structure of the ternary alloy α-(AlMnSi). Acta Cryst. 20 (1966), pp. 614-617
  • 7. Robinson K.: The structure of β-(AlMnSi)- Mn3SiAl9, Acta Cryst., 5 (1952), pp. 9007-403
  • 8. Robinson K,. Black P.J.: An X-ray examination of α-(AlFeSi) ternary compounds, Phil Mag., 44 (1953), pp. 1392-1397
  • 9. Phragmen G.: On the phases oceurring in alloys of aluminium with copper, magnesium, manganese iron and silicon , J. Inst of Metals, 77 (1950), p. 489.
  • 10. Sun C.Y., Mondolfo L.F.: A clarification of the phases occurring in aluminium -rich aluminium-iron silicon alloys, Journal of the Institute of Metals , 95 (1967), p.384
  • 11. Wang L., Apelian D., Makhlouf M.M.: Iron-bearing compounds in Al-Si die-casting alloys: morphology and conditions under which they form, AFS Trans., 146 (1999), pp. 231-238
  • 12. Zakharov A.M., Gulcyn I.T., Arnold A.A., Macenko J.A.: Issledowanie systemy Al-Si-Mn w intervale koncentracji 10-14%Si, 0-4%Mn., Izv. VUZ., Cnetn. Met., (1988), No.2, pp.90-94
  • 13. ZakharoY A.M., Gulcyn I.T., Arnold A.A., Macenko J.A.: Secenia izotermiceskich tetraedrov sistemy Al-Si-Fe-Mn, pri 10-14%Si, (do 3%Fe i 4%Mn). lzv. VUZ., Cvetn. Met., (1989), No.4, pp.78-81
  • 14. Zakharov A.M., Gulcyn I.T., Arnold A.A., Macenko J.A.: Fazovyje ravnovesia v systemie Al-Si-Fe-Mn w intervale koncentracji 10-14%Si, 0-3%Fe i 0-4%Mn. lzv. VUZ., Cvetn. Met., (1988), No.4, pp.89-94
  • 15. Furrer P. : Gefugeanderung bei der Warmbehandlung von Al-Mn-Strangussen, Z. Metallkde, 70 (1979), pp. 699-706
  • 16. Iglessis J., Frantz C., Gantois M.: La croissance par propagation de plans de macle des composes eutectiques dans le systeme Al-Fe-Si, Mem. Scie. Rev. Met., 77 (1978), pp.93-100
  • 17. Gustafsson G., Thorvaldsson T., Dunlop G.L.: The influence of Fe and Cr on the microstructure of cast Al-Si-Mg alloys. Met Trans. A, 17A, (1986), pp.45-52
  • 18. Stefaniay V., Griger A., Turmezey T: Intermetallic phases in the aluminium -side comer of the AlFeSi alloy system, Journal of Materials Science, 22 (1987), pp. 539-546
  • 19. Warmuzek M.: Identyfikacja składników strukturalnych w stopach Al-Zn-Si i Al-Zn-Si-Cu, Prace I.Od.,42(1992), pp.215-227
  • 20. Warmuzek M., Lech Z., Sęk-Sas G.: Mikrostrukturalny aspekt obecności metali przejściowych (Fe, Mn, Cr) w stopach Al-Si. Międzynarodowa Konferencja Naukowo-Techniczna, Odlewnictwo Metali Nieżelaznych: Nauka-Technologie, 6-8 czerwca 2002, Lucień
  • 21. Ghomashi R.M.: Intermetallic compounds in an Al-Si alloy used in high pressure die casting, Z. Metalik., 78 (1987), pp. 784-787
  • 22. Narayanan A. L., Samuel F.H., Gruzleski J.E.: Crystallization behaviour of iron-containing intermetallic compounds in 319aluminium alloy. Met and Mat. Trans A, 25A (1994), pp.1761-1773
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPG5-0015-0041
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