Polymer nanocomposites on the base of metal carboxylates

• Autorzy: Pomogailo A. D. , Rozenberg A. S. , Dzhardimalieva G. I.
• Języki publikacji: EN

Abstrakty

EN

The thermal transformation of unsaturated metal carboxylates (metal acrylates and maleates) are the complex process including dehydration, solid phase polymeriza-tion, and decarboxylation of metalcarboxylate groups of the polymer formed which proceed sequentially at varied temperature ranges. The thermolysis resulted in the synthesis of metal nanoparticles with narrow size distribution (the mean particle diameter of 5-10 nm) in the polymer matrix formed in situ.

Słowa kluczowe

EN

polymer nanocomposites; thermal transformation; polymer matrix

• Wydawca: Politechnika Gdańska
• Czasopismo: Advances in Materials Science
• Rocznik: 2001
• Tom: Vol. 1, nr 1(1)
• Strony: 19--27
• Opis fizyczny: Bibliogr. 10 poz., 2 rys., 3 tab.

Twórcy

autor

Pomogailo A. D.

• Institute of Problems of Chemical Physics, Russian Academy of Sciences Chernogolovka, Russia

autor

Rozenberg A. S.

• Institute of Problems of Chemical Physics, Russian Academy of Sciences Chernogolovka, Russia

autor

Dzhardimalieva G. I.

• Institute of Problems of Chemical Physics, Russian Academy of Sciences Chernogolovka, Russia

Bibliografia

• 1. Pomogailo A.D., Rozenberg A. S., Uflyand I.E.: Nanoscale metal particles in polymers. Khimiya, Moscow, Russia, 2001.
• 2. Rozenberg A. S., Dzhardimalieva G.I., Pomogailo A.D.: Polymer Composites of Nano-sized Particles Isolated in Matrix. Polym. Adv. Technol. 9 (1998) 527-535.
• 3. Dzhardimalieva G.I., Pomogailo A.D., Ponomare V.I., Atovmyan L.O., Shulga Yu.M., Starikov A.G.: Synthesis and reactivity of metal-containing monomers. 7. Synthesis and investigation of transition metal acrylates. Bull. Acad. Sci. USSR, Div. Chem. Sci. 37 (1988) 1352-1355 (Engl. Transl.).
• 4. Porollo N.P., Aliev Z.A., Dzhardimalieva G.I., IvlevaI.N., Uflyand I.E., Pomogailo A.D., Ovanesyan N.S.: Synthesis and reactivity of metal-containing monomers. 47. Synthesis and structure of salts of unsaturated dicarboxylic acids. Russ. Chem. Bull. 46 (1997) 362-370 (Engl. Transl.).
• 5. Nakamoto K.: Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley and Sons, New York, USA., 1987.
• 6. Rozenberg A. S., Alexandrova E.I., Ivleva N. P., Dzhardimalieva G.I., Raevskii A.V., Kolesova O.I., Uflyand I.E., Pomogailo A.D.: Reactivity of metal-containing monomers. 48. Thermal transformations of cobalt(II) maleate. Russ. Chem. Bull. 47 (1998) 259–264 (Engl. Trans.).
• 7. Shuvaev A.T., Rozenberg A.S., Dzhardimalieva G.I., Ivleva N. P., Vlasenko V.G., Nedoseikina T.I., Lyubeznova T.A., Uflyand I.E., Pomogailo A.D.: Synthesis and reactivity of metal-containing monomers. 50. Evolution of short-range surrounding of Fe atoms during thermal transformation of [Fe3O(OOCCH=CHCOOH)6]OH⋅3H2O. Russ. Chem. Bull. 47 (1998) 1460–1465 (Engl. Trans.).
• 8. Granowski A., Wojtczak Z.: The thermal decompositions of some transtion metal acrylates and polyacrylates. J. Therm. Anal. 26 (1983) 233–239.
• 9. Wojtezak, Z.: J. Therm. Anal. 1990, 36, 2357–2362.
• 10. Porai-Koshits .: In Kristallokhimiya, Itogi nauki i tekhniki [Crystallochemistry, Advances in Science and Technology], VINITI, Moscow, 15 (1981) 13-45.