Ion exchange in lichen surrounding

• Autorzy: Kłos A. , Rajfur M. , Wacławek M. , Wacławek W.

Warianty tytułu

PL

Wymiana jonowa w układzie porost-otoczenie przyrodnicze

• Konferencja: Środkowo-europejska Konferencja ECOpole '07 (18-20.10.2007 ; Duszniki Zdrój, Polska)
• Języki publikacji: EN

Abstrakty

EN

Results of the research on heterophase equilibria (aqueous solution-the lichen cationactive layer) of exchange of copper ion for the cations naturally found in the environment (H+, Na+, K+, Mg2+ and Ca2+) have been presented, assessing in this way the influence of above-mentioned cations on sorption of heavy metals by lichens. Such processes occur in the lichen natural environment and they influence the reliability of heavy metals determination by measuring the metals accumulation in lichens. Kinetics and equilibria of (he ion exchange have been investigated through analysis of changes in parameters of different solutions, including deionized water and various solutions being in contact with lichens. The reliability of different lichen monitoring methods and the role of cationactive layer as a buffer zone have been discussed. The research has shown that heavy metals sorption is significantly influenced by the type and concentration of cations present in precipitation with which lichens are in contact. These cations originate, among others, from the substratum that lichens grow on and dust accumulated on their surface. Measurements of changes in conductivity and pH value of solutions which lichens were submerged in constituted an important part of the research. On the basis of these measurements, the reasons behind changes in conductivity of deionized water that lichens were dipped in were discussed. Hypogymnia physodes lichens were used in the study.

PL

Przedstawiono wyniki badań równowag heterofazowych (roztwór wodny - kationoaktywna warstwa porostów) wymiany kationów naturalnie występujących w środowisku: H+, Na+, K+, Mg2+ i Ca2+ i jonów miedzi, co pozwala na ocenę wpływu tych kationów na sorpcję metali ciężkich przez porosty. Takie zależności występują w naturalnym środowisku porostów i są jednym z czynników wpływających na miarodajność oceny zanieczyszczenia środowiska na podstawie badań rodzaju i stężenia metali ciężkich zasorbowanych przez porosty. Kinetykę i równowagi procesów wymiany jonowej badano poprzez pomiary zmian parametrów różnych roztworów, a także wody zdemineralizowanej, po zanurzeniu w nich porostów. Uzyskane wyniki wskazują na rolę warstwy kationoaktywnej jako czynnika buforującego. Wykazano, że duży wpływ na sorpcję metali ciężkich ma rodzaj i stężenie kationów zawartych w opadach, z którymi porosty mają kontakt. Kationy te pochodzą m.in. z podłoża, na którym rosną porosty oraz z pyłów nagromadzonych na ich powierzchni. Ważnym elementem badań były pomiary zmian konduktywności i pH roztworów, w których zanurzano porosty. Na ich podstawie zinterpretowano przyczyny zmian konduktywności wody zdemineralizowanej po zanurzeniu w niej porostów. Badania prowadzono dla porostów Hypogymnia physodes.

Słowa kluczowe

EN

lichens; lichenoindication; heavy metals; ion exchange

PL

porosty; lichenoindykacja; metale ciężkie; wymiana jonowa

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Chemia i Inżynieria Ekologiczna
• Rocznik: 2007
• Tom: Vol. 14, nr 7
• Strony: 645--667
• Opis fizyczny: Bibliogr. 42 poz., rys., tab.

Twórcy

autor

Kłos A.

autor

Rajfur M.

autor

Wacławek M.

autor

Wacławek W.

• Chair of Biotechnology and Molecular Biology, Opole University, uL Kard. B. Kominka 4, 45-032 Opole,

Bibliografia

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