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Sialon ceramics appear to be an attractive engineering material because of their excellent mechanical and thermal properties. Carbothermal production can be the most economical route for the production of the relevant sialon powders if some problems of multiphase composition are overcome. Thermodynamic calculations of the equilibrium composition in the Si-O-N-C and Al-O-N-C systems have been performed in order to predict the most suitable parameters for carbothermal reduction and nitridation. The kinetic parameters influencing the process are reviewed. Special attention is paid to the type of phases occuerring during several stages of the reduction. A new model of chemical reactions in the SiO2-Al2O3-C-N2 system has been proposed.
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Rocznik
Tom
Strony
423--439
Opis fizyczny
8 rys., bibliogr. 51 poz.
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autor
- Silesian University of Technology, Department of Materials Science, ul. Krasińskiego 8, skr. poczt. 221, 40-019 Katowice, Poland (Katedra Nauki o Materiałach, Politechnika Śląska), lizer@polsl.katowice.pl
Bibliografia
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Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPG1-0011-0064