Oxidative desulfurization of synthetic diesel using vanadium based catalysts

• Autorzy: Fabiś G. , Czajkowska S.
• Języki publikacji: EN

Abstrakty

EN

Oxidative desulfurization (ODS) of synthetic diesel was carried out at mild conditions (at atmospheric pressure and temperature of 80 °C) in the presence of V1O5/AI2O3 and V-MCM-41 catalysts, using hydrogen peroxide (H1O2) or rm-butyl hydroperoxide (TBPH) as an oxidant. Obtained results show that removal of benzothiophenic compounds is more effective in the presence of TBHP. Moreover, it has been observed that conversion of sulfur compounds is not a function of textural properties of the catalysts.

Słowa kluczowe

EN

catalytic oxidation; vanadium; mesoporous molecular sieves; supported catalysts

PL

utlenianie katalityczne; wanad; mezoporowate sita molekularne; katalizatory na nośniku

• Wydawca: Centrum Materiałów Polimerowych i Węglowych PAN
• Czasopismo: Polish Journal of Applied Chemistry
• Rocznik: 2011
• Tom: Vol. 55, nr 3-4
• Strony: 151--157
• Opis fizyczny: Bibliogr. 17 poz., rys., tab.

Twórcy

autor

Fabiś G.

autor

Czajkowska S.

• Centre of Polymer and Carbon Materials, Polish Academy of Sciences. M. Curie- Skłodowskiej 34, 41-819 Zabrze. Poland;,

Bibliografia

• 1.Knudsen, K.G., Cooper, B.H., Appl. Catal. A., 1999,189,205.
• 2. Kim, J.H., Ma, X., Zhou, A., Song, Ch., Catal. Today, 2006, 111, 74.
• 3. Mei, H., Mei, B.W., Yen, T.F., Fuel, 2003, 82, 405.
• 4. Babich, I.V., Mouljin, J.A., Fuel, 2003, 82, 607.
• 5. Collins, F.M., Lucy, A.R., Sharp, Ch., J. Mol. Catal. A, 1997,117, 397.
• 6. Hulea, V., Fajula, F., Bousquet, J., J. Catal., 2001, 198, 179.
• 7. Shiraishi, Y., Naito, T., Hirai, T., Ind. Eng. Chem. Res., 2003, 40, 6034.
• 8. Ishihara, A., Wang, D., Dumeignil, F., Amano, H., Qian, E.W., Kabe, T., Appl. Catal. A, 2005, 79, 279.
• 9. Cacro, L. C., Hernandez, E., Pedraza, F., Murietta, F., Catal. Today, 2005,107-108. 564.
• 10. Zapata, B., Pedraza, F., Valenzuela, M.A., Catal Today, 2005, 106, 219.
• 11. Chica, A., Corma, A.,. Domine, M.E, J. Catal., 2006, 242, 299.
• 12. Ma, X., Zhou, A., Song, Ch., Catal Today, 2007,123, 276.
• 13. Cui, S., Ma, F., Wang, Y., React. Kinet. Catal. Lett., 2007, 92(1), 155.
• 14. Gonzalez-Garcia, O., Cedeno-Caero, L., Catal. Today, 2009.148,42.
• 15. Fabis, G., Sarbak. Z., Przem. Chem., 2009. 88, 83.
• 16. Fabis, G., Lewandowski, M., Sarbak, Z., Czajkowska, S., Pol. J. of Appl. Chem., 2010, LIV, no. 1-4, 41. 17.
• 17. Gucbilmez, Y., Dogu, T., Balci S., Catal. Today, 2005, 100, 473